ChemicalBook > CAS DataBase List > (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID

(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID

Product Name
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID
CAS No.
603122-82-3
Chemical Name
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID
Synonyms
METHYL 4-B;AKOS BRN-0545;oro-4-(methoxycarbonyL;METHYL 4-BORONO-2-CHLOROBENZOATE;3-CHLORO-4-(METHOXYCARBONYL)PHENYLBORONIC ACID;(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID;Benzoic acid, 4-borono-2-chloro-, 1-methyl ester;(4-(Methoxycarbonyl)-3-chlorophenyl)boronic acid;3-Chloro-4-(methoxycarbonyl)benzeneboronic acid 97%;(3-Chloro-4-(methoxycarbonyl)phenyl)boronic acid, 99.8%
CBNumber
CB8182568
Molecular Formula
C8H8BClO4
Formula Weight
214.41
MOL File
603122-82-3.mol
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(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Property

Melting point:
174-178
storage temp. 
Inert atmosphere,2-8°C
solubility 
soluble in Methanol
form 
powder to crystal
color 
White to Almost white
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Safety

Hazard Codes 
Xi
Hazard Note 
Irritant
HS Code 
2931900090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical
Product number
C3279
Product name
3-Chloro-4-(methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1G
Price
$106
Updated
2026/03/19
TCI Chemical
Product number
C3279
Product name
3-Chloro-4-(methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5G
Price
$319
Updated
2026/03/19
TRC
Product number
C427823
Product name
3-Chloro-4-methoxycarbonylphenylboronicacid
Packaging
1g
Price
$75
Updated
2021/12/16
Apolloscientific
Product number
OR1933
Product name
3-Chloro-4-(methoxycarbonyl)benzeneboronicacid
Purity
96%
Packaging
1g
Price
$27
Updated
2021/12/16
SynQuest Laboratories
Product number
6660-5-X9
Product name
3-Chloro-4-(methoxycarbonyl)benzeneboronic acid
Purity
96%
Packaging
1g
Price
$29
Updated
2021/12/16
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(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Chemical Properties,Usage,Production

Uses

3-Chloro-4-methoxycarbonylphenylboronic acid

Synthesis

To a solution of methyl 2-chloro-4-bromobenzoate (31.4 mmol) in dioxane (154 mL) was added pinacol ester of bis(boronic acid) (8.6 g, 31.4 mmol), PdCl2(PPh3)2 (0.42 mmol), and KOAc (94.2 mmol), and the mixture was stirred for 2-6 hr at 100 C under nitrogen. The mixture was diluted with EtOAc and water. The organic layer was separated, washed with brine, dried over MgSO4 and evaporated. The residue was purified by silica gel column chromatography (hexane/EtOAc 5/1) to give 3-chloro-4-methoxycarbonylphenylboronic acid pinacol ester. To a suspension of the above product (29.4 mmol) in acetone (175 mL) and water (175 mL) was added NH4OAc (66.2 mmol) and NaIO4 (14.2 g, 66.4 mmol) and the mixture was stirred for 15 hours at room temperature. The solvent was evaporated and the residue was diluted with EtOAc. The organic layer was separated, washed with water and brine, dried over MgSO4 and evaporated under reduced pressure to give the title compound as a white solid.

(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Preparation Products And Raw materials

Raw materials

Preparation Products

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(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Suppliers

J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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4006356688 18621169109
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86-21-61259102
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market03@meryer.com
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China
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400-6106006
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021-67582001/03/05
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saleschina@alfa-asia.com
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China
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Energy Chemical
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Wuhan Chemwish Technology Co., Ltd
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86-027-87531808
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sales@chemwish.com
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Jia Xing Isenchem Co.,Ltd
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isenchem@163.com
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T&W GROUP
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Shanghai Topbiochem Technology Co., Ltd
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021-58170097
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China
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View Lastest Price from (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID manufacturers

Hebei Zhanyao Biotechnology Co. Ltd
Product
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID 603122-82-3
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2021-10-19
Career Henan Chemical Co
Product
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID 603122-82-3
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-26

603122-82-3, (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACIDRelated Search:


  • (4-(Methoxycarbonyl)-3-chlorophenyl)boronic acid
  • 3-Chloro-4-(methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
  • AKOS BRN-0545
  • (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID
  • 3-CHLORO-4-(METHOXYCARBONYL)PHENYLBORONIC ACID
  • METHYL 4-BORONO-2-CHLOROBENZOATE
  • 3-Chloro-4-(methoxycarbonyl)benzeneboronic acid 97%
  • (3-Chloro-4-(methoxycarbonyl)phenyl)boronic acid, 99.8%
  • METHYL 4-B
  • oro-4-(methoxycarbonyL
  • Benzoic acid, 4-borono-2-chloro-, 1-methyl ester
  • (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID ISO 9001:2015 REACH
  • 603122-82-3
  • C8H8BClO4
  • blocks
  • BoronicAcids
  • Carboxes