(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID
- Product Name
- (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID
- CAS No.
- 603122-82-3
- Chemical Name
- (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID
- Synonyms
- METHYL 4-B;AKOS BRN-0545;oro-4-(methoxycarbonyL;METHYL 4-BORONO-2-CHLOROBENZOATE;3-CHLORO-4-(METHOXYCARBONYL)PHENYLBORONIC ACID;(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID;Benzoic acid, 4-borono-2-chloro-, 1-methyl ester;(4-(Methoxycarbonyl)-3-chlorophenyl)boronic acid;3-Chloro-4-(methoxycarbonyl)benzeneboronic acid 97%;(3-Chloro-4-(methoxycarbonyl)phenyl)boronic acid, 99.8%
- CBNumber
- CB8182568
- Molecular Formula
- C8H8BClO4
- Formula Weight
- 214.41
- MOL File
- 603122-82-3.mol
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Property
- Melting point:
- 174-178
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- soluble in Methanol
- form
- powder to crystal
- color
- White to Almost white
Safety
- Hazard Codes
- Xi
- Hazard Note
- Irritant
- HS Code
- 2931900090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- C3279
- Product name
- 3-Chloro-4-(methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 1G
- Price
- $106
- Updated
- 2026/03/19
- Product number
- C3279
- Product name
- 3-Chloro-4-(methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride)
- Packaging
- 5G
- Price
- $319
- Updated
- 2026/03/19
- Product number
- C427823
- Product name
- 3-Chloro-4-methoxycarbonylphenylboronicacid
- Packaging
- 1g
- Price
- $75
- Updated
- 2021/12/16
- Product number
- OR1933
- Product name
- 3-Chloro-4-(methoxycarbonyl)benzeneboronicacid
- Purity
- 96%
- Packaging
- 1g
- Price
- $27
- Updated
- 2021/12/16
- Product number
- 6660-5-X9
- Product name
- 3-Chloro-4-(methoxycarbonyl)benzeneboronic acid
- Purity
- 96%
- Packaging
- 1g
- Price
- $29
- Updated
- 2021/12/16
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Chemical Properties,Usage,Production
Uses
3-Chloro-4-methoxycarbonylphenylboronic acid
Synthesis
To a solution of methyl 2-chloro-4-bromobenzoate (31.4 mmol) in dioxane (154 mL) was added pinacol ester of bis(boronic acid) (8.6 g, 31.4 mmol), PdCl2(PPh3)2 (0.42 mmol), and KOAc (94.2 mmol), and the mixture was stirred for 2-6 hr at 100 C under nitrogen. The mixture was diluted with EtOAc and water. The organic layer was separated, washed with brine, dried over MgSO4 and evaporated. The residue was purified by silica gel column chromatography (hexane/EtOAc 5/1) to give 3-chloro-4-methoxycarbonylphenylboronic acid pinacol ester. To a suspension of the above product (29.4 mmol) in acetone (175 mL) and water (175 mL) was added NH4OAc (66.2 mmol) and NaIO4 (14.2 g, 66.4 mmol) and the mixture was stirred for 15 hours at room temperature. The solvent was evaporated and the residue was diluted with EtOAc. The organic layer was separated, washed with water and brine, dried over MgSO4 and evaporated under reduced pressure to give the title compound as a white solid.
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Preparation Products And Raw materials
Raw materials
Preparation Products
(3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID Suppliers
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View Lastest Price from (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID manufacturers
- Product
- (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID 603122-82-3
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2021-10-19
- Product
- (3-CHLORO-4-METHOXYCARBONYL)BENZENEBORONIC ACID 603122-82-3
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 1000KGS
- Release date
- 2019-12-26