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Benzonitrile, 2-amino-3-hydroxy-

Product Name
Benzonitrile, 2-amino-3-hydroxy-
CAS No.
211172-52-0
Chemical Name
Benzonitrile, 2-amino-3-hydroxy-
Synonyms
2-AMino-3-hydroxy-benzonitrile;Benzonitrile, 2-amino-3-hydroxy-
CBNumber
CB81872013
Molecular Formula
C7H6N2O
Formula Weight
134.14
MOL File
211172-52-0.mol
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Benzonitrile, 2-amino-3-hydroxy- Property

Boiling point:
301.5±37.0 °C(Predicted)
Density 
1.33±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
8.37±0.10(Predicted)
Appearance
Light brown to brown Solid
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Safety

RIDADR 
UN3439
HazardClass 
6.1
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC
Product number
A636198
Product name
2-Amino-3-hydroxybenzonitrile
Packaging
50mg
Price
$130
Updated
2021/12/16
TRC
Product number
A636198
Product name
2-Amino-3-hydroxybenzonitrile
Packaging
100mg
Price
$200
Updated
2021/12/16
Oakwood
Product number
244064
Product name
2-Amino-3-hydroxybenzonitrile
Purity
95+%
Packaging
100mg
Price
$120
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0387977
Product name
2-AMINO-3-HYDROXYBENZONITRILE
Purity
95.00%
Packaging
5MG
Price
$503.59
Updated
2021/12/16
AK Scientific
Product number
0783AB
Product name
2-Amino-3-hydroxybenzonitrile
Packaging
1g
Price
$984
Updated
2021/12/16
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Benzonitrile, 2-amino-3-hydroxy- Chemical Properties,Usage,Production

Synthesis

129298-23-3

211172-52-0

B. 3-Hydroxy-2-nitrobenzonitrile (1.31 g) was mixed with 10% Pd/C (131 mg) in a solvent mixture of ethanol (9 mL) and ethyl acetate (18 mL), and the reaction was stirred overnight under hydrogen atmosphere. Upon completion of the reaction, the catalyst was removed by filtration through diatomaceous earth and the filtrate was subsequently concentrated. The resulting residue was purified by column chromatography (eluent: hexane/ethyl acetate, 6/4) to give 2-amino-3-hydroxybenzonitrile (398 mg, 37% yield).

References

[1] Journal of Medicinal Chemistry, 2004, vol. 47, # 6, p. 1319 - 1321
[2] Patent: WO2008/110793, 2008, A1. Location in patent: Page/Page column 106-107
[3] Patent: US5840764, 1998, A
[4] Patent: WO2011/106986, 2011, A1. Location in patent: Page/Page column 122; 123

Benzonitrile, 2-amino-3-hydroxy- Preparation Products And Raw materials

Raw materials

Preparation Products

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Benzonitrile, 2-amino-3-hydroxy- Suppliers

Beijing Eternalchem Co,. Ltd.
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