ChemicalBook > CAS DataBase List > ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE

ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE

Product Name
ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE
CAS No.
13537-82-1
Chemical Name
ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE
Synonyms
Ai3-18159;NSC 84213;Einecs 236-910-1;2-Carbethoxy-5-methylcyclohexanone;ethyl 4-methyl-2-oxocyclohexanecarboxylate;ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE;ETHYL 4-METHYL-2-OXO-1-CYCLOHEXANECARBOXYLATE;ethyl4-?methyl-?2-?oxocyclohexane-?1-?carboxylate;4-Methyl-2-oxocyclohexanecarboxylic acid ethyl ester;2-Oxo-4-methylcyclohexanecarboxylic acid ethyl ester
CBNumber
CB8195522
Molecular Formula
C10H16O3
Formula Weight
184.23
MOL File
13537-82-1.mol
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ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE Property

Melting point:
53-54 °C
Boiling point:
128-132 °C/32 mmHg (lit.)
Density 
1.045 g/mL at 25 °C (lit.)
vapor pressure 
28Pa at 25℃
refractive index 
n20/D 1.473(lit.)
Flash point:
>230 °F
pka
12.09±0.40(Predicted)
Water Solubility 
2.56g/L at 20℃
LogP
4.36 at 30℃
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Safety

WGK Germany 
3
HS Code 
2918300090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
E35702
Product name
Ethyl 4-methyl-2-cyclohexanone-1-carboxylate
Packaging
5g
Price
$395
Updated
2023/06/20
Matrix Scientific
Product number
180402
Product name
Ethyl 4-methyl-2-cyclohexanone-1-carboxylate
Packaging
500mg
Price
$100
Updated
2021/12/16
AK Scientific
Product number
3386AL
Product name
Ethyl 4-methyl-2-cyclohexanone-1-carboxylate
Packaging
1g
Price
$107
Updated
2021/12/16
Matrix Scientific
Product number
180402
Product name
Ethyl 4-methyl-2-cyclohexanone-1-carboxylate
Packaging
1g
Price
$120
Updated
2021/12/16
Apolloscientific
Product number
OR946697
Product name
Ethyl 4-methyl-2-cyclohexanone-1-carboxylate
Purity
95%
Packaging
1g
Price
$167
Updated
2021/12/16
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ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE Chemical Properties,Usage,Production

Uses

Reactant involved in:• ;Hydroxylation / oxidative chlorination with hydrogen peroxide1• ;Heterocyclization2• ;Cyclization of generated dianions followed by dehydrogenation3• ;Palladium-catalyzed isomerization4• ;Regioselective cyclizations5• ;Vinylogous Michael reactions6

Uses

2-Carbethoxy-5-methylcyclohexanone is a useful chemical reagent in organic synthesis. It is reported that 2-Carbethoxy-5-methylcyclohexanone is used in the synthesis of optically active α-methylene γ-butyrolactones and (+)-mintlactone.

Uses

Reactant involved in:

  • Hydroxylation / oxidative chlorination with hydrogen peroxide
  • Heterocyclization
  • Cyclization of generated dianions followed by dehydrogenation
  • Palladium-catalyzed isomerization
  • Regioselective cyclizations
  • Vinylogous Michael reactions

Flammability and Explosibility

Not classified

ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE Preparation Products And Raw materials

Raw materials

Preparation Products

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ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
91

13537-82-1, ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATERelated Search:


  • NSC 84213
  • ETHYL 4-METHYL-2-OXO-1-CYCLOHEXANECARBOXYLATE
  • ETHYL 4-METHYL-2-CYCLOHEXANONE-1-CARBOXYLATE
  • 2-Oxo-4-methylcyclohexanecarboxylic acid ethyl ester
  • 4-Methyl-2-oxocyclohexanecarboxylic acid ethyl ester
  • Ai3-18159
  • Cyclohexanecarboxylic acid, 4-methyl-2-oxo-, ethyl ester
  • Einecs 236-910-1
  • ethyl 4-methyl-2-oxocyclohexanecarboxylate
  • ethyl4-?methyl-?2-?oxocyclohexane-?1-?carboxylate
  • 2-Carbethoxy-5-methylcyclohexanone
  • 13537-82-1
  • CH3C6H8OCO2C2H5
  • Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Esters
  • Organic Building Blocks
  • Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Chemical Synthesis
  • Esters
  • Organic Building Blocks