ChemicalBook > CAS DataBase List > (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE

(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE

Product Name
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
CAS No.
102308-32-7
Chemical Name
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
Synonyms
tert-butyl (S)-4-formyl-2,2-dimethyloxazolidine-3-carboxylate;(s)-(-)-3-boc-2,2-dimethyloxazolidine-4-carboxaldehyde;tert-butyl (4S)-4-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate;GARNER'S ALDEHYDE;S-Garner'saldehyde;(S)-Garner aldehyde;(-)-Garner aldehyde;1,1-DiMethylethyl1,1-DiMethylethyl;(-)-n-boc-n,o-isopropylidene-l-serinal;(S)-2,2-diMethyloxazolidine-4-carbaldehyde
CBNumber
CB8196796
Molecular Formula
C11H19NO4
Formula Weight
229.27
MOL File
102308-32-7.mol
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(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE Property

Boiling point:
83-88 °C1 mm Hg(lit.)
alpha 
D -91.7° (c = 1.34 in CHCl3)
Density 
1.06 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.445(lit.)
Flash point:
226 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Methanol (Slightly)
pka
-3.26±0.60(Predicted)
form 
Oil
color 
Clear colorless to yellow
optical activity
[α]20/D 90°, c = 1 in chloroform
Water Solubility 
Slightly soluble in water.
Sensitive 
Air Sensitive
BRN 
3591324
CAS DataBase Reference
102308-32-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
432741
Product name
(S)-(?)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde
Purity
95%
Packaging
1g
Price
$118.2
Updated
2024/03/01
TCI Chemical
Product number
B1759
Product name
(S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine
Purity
>95.0%(GC)
Packaging
1g
Price
$146
Updated
2024/03/01
TCI Chemical
Product number
B1759
Product name
(S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine
Purity
>95.0%(GC)
Packaging
5g
Price
$483
Updated
2024/03/01
TRC
Product number
B689730
Product name
(4S)-4-Formyl-2,2-dimethyl-3-oxazolidinecarboxylicAcid1,1-DimethylethylEster
Packaging
5G
Price
$495
Updated
2021/12/16
TRC
Product number
B689730
Product name
(4S)-4-Formyl-2,2-dimethyl-3-oxazolidinecarboxylicAcid1,1-DimethylethylEster
Packaging
250mg
Price
$90
Updated
2021/12/16
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(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellow oil

Uses

Widely utilized in the asymmetric synthesis of natural products.

Uses

Chiral, non-racemic synthon for asymmetric synthesis of amino sugars and other nitrogen-containing targets.

(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE Suppliers

Americas 1 Belgium 2 Canada 3 China 144 Europe 1 France 4 Germany 5 India 10 Italy 1 Japan 1 Switzerland 1 The Netherlands 1 United Kingdom 8 United States 33 Global 215
ProtEra Srl
Tel
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Fax
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Email
info@proterasrl.com
Country
Italy
ProdList
7
Advantage
60
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View Lastest Price from (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE manufacturers

Career Henan Chemical Co
Product
(S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE 102308-32-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200kg
Release date
2019-12-26

102308-32-7, (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINERelated Search:

4-METHOXYCINNAMALDEHYDE NAPHTHALENE-2,3-DICARBOXALDEHYDE (S)-3-(TERT-BUTOXYCARBONYL)-2,2-DIMETHYLOXAZOLIDINE-4-CARBOXYLIC ACID 3-OXAZOLIDINECARBOXYLIC ACID (S)-3-BOC-4-(METHOXYMETHYLCARBAMOYL)-2,2-DIMETHYLOXAZOLIDINE (S)-(-)-3-TERT-BUTOXYCARBONYL-4-METHOXYCARBONYL-2,2-DIMETHYL-1,3-OXAZOLIDINE ethyl (hydroxymethyl)-carbamate (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE 1,1-DIMETHYLETHYL-(R,S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE

  • (4S)-3-(tert-Butoxycarbonyl)-2,2-dimethyl-1,3-oxazolidine-4-carbaldehyde
  • (S)-Garner aldehyde
  • 1,1-DIMETHYLETHYL-(S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINE CARBOXYLATE
  • (S)-4-FORMYL-2,2-DIMETHYL-OXAZOLIDINE-3-CARBOXYLIC ACID TERT-BUTYL ESTER
  • (S)-(-)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
  • (S)-3-BOC-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
  • (S)-(-)-3-TERT-BUTOXYCARBONYL-4-FORMYL-2,2-DIMETHYL-1,3-OXAZOLIDINE
  • TERT-BUTYL (S)-(-)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
  • TERT-BUTYL (S)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE
  • (S)-N-BOC-2,2-DIMETHYLOXAZOLINDINE-4-CARBOXALDEHYDE
  • GARNER'S ALDEHYDE
  • (S)-(-)-3-tert-Butoxycarbonyl-4-formyl-2,2-dimethyl
  • (S)-4-Formyl-2,2-dimethyl-oxazolidine-3-carboxylictert-butylester
  • (-)-n-boc-n,o-isopropylidene-l-serinal
  • (s)-(-)-3-boc-2,2-dimethyloxazolidine-4-carboxaldehyde
  • (s)-(-)-3-tert-butoxycarbonyl-4-formyl- 2,2-
  • (S)-tert-butyl 4-formyl-2,2-dimethyloxazolidine-3-carboxylate
  • Garners aldehyde, (-)-N-Boc-N,O-isopropylidene-L-serinal, tert-Butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate
  • (4S)-2,2-Dimethyl-3-(tert-butoxycarbonyl)oxazolidine-4-carbaldehyde
  • (4S)-2,2-Dimethyl-4α-formyl-3-oxazolidinecarboxylic acid tert-butyl ester
  • 1,1-dimethylethyl-(S)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate, 95 %
  • tert-butyl (4S)-4-formyl-2,2-dimethyl-1,3-oxazolidine-3-carboxylate
  • (4S)-2,2-Dimethyl-1,3-oxazolidine-4-carboxaldehyde, N-BOC protected
  • 1,1-DiMethylethyl1,1-DiMethylethyl
  • S-Garner'saldehyde
  • tert-Butyl (4S)-2,2-dimethyl-4-formyl-1,3-oxazolidine-3-carboxylate
  • 1,1-Dimethylethyl-(S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidine carboxylate mainly (S)
  • (4S)-4-Formyl-2,2-dimethyl-3-oxazolidinecarboxylic acid 1,1-dimethylethyl ester
  • tert-Butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazolidinecarboxylate,95%
  • (S)-2,2-diMethyloxazolidine-4-carbaldehyde
  • tert-Butyl (4S)-2,2-dimethyl-4-formyl-1,3-oxazolidine-3-carboxylate, (4S)-3-(tert-Butoxycarbonyl)-2,2-dimethyl-4-formyl-1,3-oxazolidine
  • (S)-(-)-3-Boc-2,2-diMethyloxazolidine-4-carboxaldehyde, 95%, 95%
  • (S)-(-)-3-Boc-2,2-dimethyloxazolidine-4-carboxaldehyde 95%
  • tert-Butyl (4S)-4-formyl-2,2-dimethyl-oxazolidine-3-carboxylate
  • (<i>S</i>)-(-)-3-(<i>tert</i>-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine
  • tert-butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazol
  • (4S)-2,2-Dimethyl-1,3-oxazolidine-4-carboxaldehyde, N-BOC protected 97%
  • (4S)-4-formyl-2,2-dimethyl-oxazolidine-3-carboxylic acid tert-butyl ester
  • (S)-(-)-3-(tert-Butoxycarbonyl)-4-formyl-2,2-dimethyl-1,3-oxazolidine &gt
  • 3-Oxazolidinecarboxylic acid, 4-formyl-2,2-dimethyl-, 1,1-dimethylethyl ester, (4S)-
  • tert-butyl (S)-4-formyl-2,2-dimethyloxazolidine-3-carboxylate
  • (S)-N-Boc-4-formyl-2,2-dimethyloxazolidine
  • (-)-Garner aldehyde
  • N-Boc-4(S)-2,2-dimethyl-1,3-oxazolidine-4-carbaldehyde
  • 102308-32-7
  • ALDEHYDE
  • Asymmetric Synthesis
  • Chiral Auxiliaries
  • Chiral Building Blocks
  • Glycidyl Compounds, etc. (Chiral)
  • Oxazolidinone Derivatives
  • Chiral Building Blocks
  • Glycidyl Compounds, etc. (Chiral)
  • Synthetic Organic Chemistry
  • pharmacetical