Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]-

Product Name: Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]-
CAS No.: 37885-07-7
Chemical Name: Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]-
Synonyms: 2'-Amino-4'-(trifluoromethyl)acetophenone;1-[2-aMino-4-(trifluoroMethyl)phenyl]-Ethanone;Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]-;1-[2-amino-4-(trifluoromethyl)phenyl]ethan-1-one;1-[2-Amino-4-(trifluoromethyl)phenyl]ethan-1-one, 2-Acetyl-5-(trifluoromethyl)aniline, 4-Acetyl-3-aminobenzotrifluoride
CBNumber: CB82077389
Molecular Formula: C9H8F3NO
Formula Weight: 203.16
MOL File: 37885-07-7.mol

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Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]- Property

Boiling point:: 274℃
Density: 1.296
Flash point:: 120℃
storage temp.: 2-8°C(protect from light)
pka: 1.08±0.10(Predicted)
Appearance: Light yellow to yellow Solid
InChI: InChI=1S/C9H8F3NO/c1-5(14)7-3-2-6(4-8(7)13)9(10,11)12/h2-4H,13H2,1H3
InChIKey: ALHLVWOGPMHZHJ-UHFFFAOYSA-N
SMILES: C(=O)(C1=CC=C(C(F)(F)F)C=C1N)C

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Safety

HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: A630483
Product name: 1-(2-Amino-4-(trifluoromethyl)phenyl)ethanone
Packaging: 500mg
Price: $175
Updated: 2021/12/16

TRC

Product number: A630483
Product name: 1-(2-Amino-4-(trifluoromethyl)phenyl)ethanone
Packaging: 50mg
Price: $45
Updated: 2021/12/16

AK Scientific

Product number: W5870
Product name: 1-(2-Amino-4-(trifluoromethyl)phenyl)ethanone
Packaging: 1g
Price: $419
Updated: 2021/12/16

Crysdot

Product number: CD12077288
Product name: 1-(2-Amino-4-(trifluoromethyl)phenyl)ethanone
Purity: 98%
Packaging: 25g
Price: $456
Updated: 2021/12/16

Alichem

Product number: 37885077
Product name: 1-(2-Amino-4-(trifluoromethyl)phenyl)ethanone
Packaging: 5g
Price: $935
Updated: 2021/12/16

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Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]- Chemical Properties,Usage,Production

Synthesis

128403-22-5

37885-07-7

c) To a mixture of 1-(2-nitro-4-trifluoromethylphenyl)ethanone (1.44 g, 6.18 mmol) in EtOH (30 mL) and H2O (15 mL) was added iron powder (1.72 g, 30.88 mmol) and NH4Cl (165 mg, 3.09 mmol) and the reaction mixture was stirred vigorously at 90 °C for 30 min. The reaction mixture was filtered while hot and the residue was washed with EtOAc and additional H2O was added. The phases were separated and the organic phase was washed sequentially with water and brine, dried over MgSO4 and concentrated under reduced pressure to remove the solvent. The residue was filtered through a silica gel pad (eluent: EtOAc/PE=1:1) to afford 1-(2-amino-4-trifluoromethylphenyl)ethanone (1.20 g, 96%) as a yellow solid.

References

[1] Patent: US2006/63841, 2006, A1. Location in patent: Page/Page column 37; 10/12
[2] Tetrahedron Letters, 1990, vol. 31, # 8, p. 1093 - 1096
[3] Patent: US2007/238700, 2007, A1. Location in patent: Page/Page column 35

Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]- Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]- Suppliers

China 35 India 1 United Kingdom 1 United States 3 Global 40

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37885-07-7, Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]-Related Search:

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1-[2-Amino-4-(trifluoromethyl)phenyl]ethan-1-one, 2-Acetyl-5-(trifluoromethyl)aniline, 4-Acetyl-3-aminobenzotrifluoride

Ethanone,1-[2-amino-4-(trifluoromethyl)phenyl]-

1-[2-aMino-4-(trifluoroMethyl)phenyl]-Ethanone

1-[2-amino-4-(trifluoromethyl)phenyl]ethan-1-one

2'-Amino-4'-(trifluoromethyl)acetophenone

37885-07-7