ChemicalBook > CAS DataBase List > (S) QuinoxP(R)
(S) QuinoxP(R)
Reaction- Product Name
- (S) QuinoxP(R)
- CAS No.
- 1107608-80-9
- Chemical Name
- (S) QuinoxP(R)
- Synonyms
- QuinoxP;(S) QuinoxP;(S,S)-QuinoxP*;(S) QuinoxP(R);3-bis((S)-tert-butyl(methyl)phosphino)quinoxaline;(S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline;(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline;2,3-bis((S)-tert-butyl(methyl)phosphaneyl)quinoxaline;2,3-Bis[(S)-(1,1-dimethylethyl)methylphosphino]quinoxaline;Quinoxaline, 2,3-bis[(S)-(1,1-dimethylethyl)methylphosphino]-
- CBNumber
- CB82102711
- Molecular Formula
- C18H28N2P2
- Formula Weight
- 334.38
- MOL File
- 1107608-80-9.mol
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(S) QuinoxP(R) Property
- Melting point:
- 100-105 °C
- alpha
- +54.3° (c 1.0, CHCl3)
- Boiling point:
- 447.6±45.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- -0.54±0.59(Predicted)
- color
- orange
- optical activity
- [α]22/D +55°, c = 1 in chloroform
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Safety
- Hazard Codes
- Xn
- Risk Statements
- 22-36/37/38
- Safety Statements
- 26
- RIDADR
- UN 2811 6.1/PG 3
- WGK Germany
- 3
- HS Code
- 2933.99.8290
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
H413May cause long lasting harmful effects to aquatic life
- Precautionary statements
-
P273Avoid release to the environment.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 694215
- Product name
- (S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
- Packaging
- 100mg
- Price
- $89.8
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B5302
- Product name
- (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
- Purity
- >98.0%(HPLC)
- Packaging
- 100mg
- Price
- $213
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0127
- Product name
- (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP*
- Packaging
- 100mg
- Price
- $116
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0127
- Product name
- (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP*
- Packaging
- 500mg
- Price
- $458
- Updated
- 2024/03/01
TRC
- Product number
- B400220
- Product name
- (S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
- Packaging
- 100mg
- Price
- $250
- Updated
- 2021/12/16
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(S) QuinoxP(R) Chemical Properties,Usage,Production
Reaction
- Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides.
- Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.
- Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction
- Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates.
- Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones.
- Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes.
- Ligand for the silver-catalyzed asymmetric nitroso aldol reaction.
Uses
(S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is a useful reagent for organic synthesis of chiral tetraphenylenes, fused lactones and other useful intermediates.
(S) QuinoxP(R) Preparation Products And Raw materials
Raw materials
Preparation Products
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(S) QuinoxP(R) Suppliers
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