Reaction
ChemicalBook > CAS DataBase List > (S) QuinoxP(R)

(S) QuinoxP(R)

Reaction
Product Name
(S) QuinoxP(R)
CAS No.
1107608-80-9
Chemical Name
(S) QuinoxP(R)
Synonyms
QuinoxP;(S) QuinoxP;(S,S)-QuinoxP*;(S) QuinoxP(R);3-bis((S)-tert-butyl(methyl)phosphino)quinoxaline;(S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline;(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline;2,3-bis((S)-tert-butyl(methyl)phosphaneyl)quinoxaline;2,3-Bis[(S)-(1,1-dimethylethyl)methylphosphino]quinoxaline;Quinoxaline, 2,3-bis[(S)-(1,1-dimethylethyl)methylphosphino]-
CBNumber
CB82102711
Molecular Formula
C18H28N2P2
Formula Weight
334.38
MOL File
1107608-80-9.mol
More
Less

(S) QuinoxP(R) Property

Melting point:
100-105 °C
alpha 
+54.3° (c 1.0, CHCl3)
Boiling point:
447.6±45.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
pka
-0.54±0.59(Predicted)
color 
orange
optical activity
[α]22/D +55°, c = 1 in chloroform
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
22-36/37/38
Safety Statements 
26
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
HS Code 
2933.99.8290
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P273Avoid release to the environment.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
694215
Product name
(S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Packaging
100mg
Price
$89.8
Updated
2024/03/01
TCI Chemical
Product number
B5302
Product name
(S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Purity
>98.0%(HPLC)
Packaging
100mg
Price
$213
Updated
2024/03/01
Strem Chemicals
Product number
15-0127
Product name
(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP*
Packaging
100mg
Price
$116
Updated
2024/03/01
Strem Chemicals
Product number
15-0127
Product name
(S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (S,S)-QuinoxP*
Packaging
500mg
Price
$458
Updated
2024/03/01
TRC
Product number
B400220
Product name
(S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
Packaging
100mg
Price
$250
Updated
2021/12/16
More
Less

(S) QuinoxP(R) Chemical Properties,Usage,Production

Reaction

  1. Ligand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and α-enamides.
  2. Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to α,β-unsaturated carbonyl compounds.
  3. Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction
  4. Ligand for the palladium-catalyzed asymmetric allylic alkylation and amination of racemic substrates.
  5. Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones.
  6. Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes.
  7. Ligand for the silver-catalyzed asymmetric nitroso aldol reaction.

Uses

(S,S)-(+)-2,3-Bis(tert-butylmethylphosphino)quinoxaline is a useful reagent for organic synthesis of chiral tetraphenylenes, fused lactones and other useful intermediates.

(S) QuinoxP(R) Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(S) QuinoxP(R) Suppliers

Sphinx Scientific Laboratory(Tianjin) Co.,Ltd
Tel
022-66211289-860 18222589728
Email
contact@sphinxpharm.com
Country
China
ProdList
187
Advantage
58
ChemicalRIM Co., Ltd
Tel
17828056498
Email
chemicalRIM@gmail.com
Country
China
ProdList
41
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44700
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12458
Advantage
60
Sphinx Scientific Laboratory (Tianjin) Co., Ltd.
Tel
022-66211289-843 13672102692
Fax
QQ:2377893365
Email
contact@sphinxpharm.com
Country
China
ProdList
361
Advantage
62
T&W GROUP
Tel
021-61551611 13296011611
Fax
+86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9900
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 15221909166
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
41438
Advantage
60
ChemStrong Scientific Co.,Ltd
Tel
0755-0755-66853366 13670046396
Fax
0755-28363542
Email
sales@chem-strong.com
Country
China
ProdList
17993
Advantage
56
Shanghai Xingui Biotechnology Co., Ltd.
Tel
17501653713 17501653715
Email
xingui2022@126.com
Country
China
ProdList
10033
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51471
Advantage
80
Tongling HengYou Biotechnology Co., Ltd.
Tel
021-50426030 13856289449
Fax
021-50426030
Email
2630597085@qq.com
Country
China
ProdList
1889
Advantage
55
ATK CHEMICAL COMPANY LIMITED
Tel
3429815786 13301662590
Fax
+86-21-51619052
Email
sales@atkchemical.com
Country
China
ProdList
10006
Advantage
55
parabiochem
Tel
025-83453382-8005
Fax
025-83453382
Email
sale@parabiochem.com
Country
China
ProdList
9604
Advantage
55
Cangzhou Enke Pharma-tech Co., Ltd.
Tel
0317-5296180 15533709196
Fax
0317-5106596
Email
sale@enkepharma.com
Country
China
ProdList
1647
Advantage
55
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2654
Advantage
58
JinJin Le Chemical Co., Ltd
Tel
10106090
Email
jjlchem2@163.com
Country
China
ProdList
9986
Advantage
58
Aikon International Limited
Tel
025-58851090 13611564524
Fax
(6)02557626880
Email
lwan@aikonchem.com
Country
China
ProdList
15952
Advantage
58
SHANGHAI FDC-CHEMICAL CO.,LTD
Tel
021-61469567 18521078705
Fax
021-61161605
Email
sales@fdc-chemical.com
Country
China
ProdList
19971
Advantage
58
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901
Email
420970979@qq.com
Country
China
ProdList
5751
Advantage
58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 13028896684
Email
sales@rrkchem.com
Country
China
ProdList
55896
Advantage
58
TCI Chemicals
Tel
021-67121386, 800-988-0390
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
5391
Advantage
58
WinWin Chemical CO., Limited
Tel
+86-0577-64498589 +8615325081899
Fax
0086-577-56994596
Email
sales@win-winchemical.com
Country
China
ProdList
14145
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25363
Advantage
58
Jinan ponder chemical co. LTD
Tel
0531-0000
Email
thinklifescience@163.com
Country
China
ProdList
19690
Advantage
58
Shanghai Jiegu Biotechnology Co., Ltd.
Tel
021-51698675
Email
jiejiegroup@126.com
Country
China
ProdList
4130
Advantage
58
Zhengzhou Alpha Chemical Co. LTD
Tel
0371-0371-53732842 13383863444
Fax
QQ:3002612166
Email
3002612166@qq.com
Country
China
ProdList
10008
Advantage
58
Hubei Shishun Biotechnology Co. Ltd
Tel
027-59223025 15107168801
Fax
027-59223025
Email
1718480011@qq.com
Country
China
ProdList
9981
Advantage
58
Hubei Baidu Chemical Co., Ltd
Tel
027-59106051 13627137652
Fax
027-59223020
Email
1438180055@qq.com
Country
China
ProdList
9994
Advantage
58
Hubei Guangao Biotechnology Co., Ltd
Tel
027-027-59223056 18162699093
Fax
027-59223056
Email
1208480011@qq.com
Country
China
ProdList
9951
Advantage
58
Tianmen Hengchang Chemical Co., Ltd
Tel
027-59322316 15172518801
Fax
027-59322316
Email
1208480077@qq.com
Country
China
ProdList
9941
Advantage
58
Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840
Email
psaitong@jm-bio.com
Country
China
ProdList
29778
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
39997
Advantage
58
JinOu Biomedical (Nanjing) Co., Ltd.
Tel
13000000000
Fax
jinoupharma@163
Email
jinoupharma@163.com
Country
China
ProdList
11732
Advantage
58
Shanghai Maclean Biochemical Technology Co., LTD
Tel
021-50706066 15221275939
Email
shenlinxing@macklin.cn
Country
China
ProdList
29803
Advantage
58
Suzhou origin Specialty Chemicals Co., Ltd
Tel
17701559125
Email
jiaoshangjun@origsc.com
Country
China
ProdList
1786
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
18621169109
Email
market03@meryer.com
Country
China
ProdList
27996
Advantage
58
Hubei Chenghai Chemical Co., Ltd
Tel
18327245847 18327245847
Email
1400838877@qq.com
Country
China
ProdList
9990
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50751
Advantage
58
Shanghai Tengjun Biotechnology Co. LTD
Tel
19821570922
Email
angela@labgogo.com
Country
China
ProdList
9901
Advantage
58
Shanghai Jieshikai Biotechnology Co. , Ltd.
Tel
021-57520305 15001810326
Email
guojianing@jskchem.com
Country
China
ProdList
49242
Advantage
58
Accela ChemBio Co.,Ltd.
Tel
021-50795510 4000665055
Email
SY06@accelachem.com
Country
China
ProdList
10334
Advantage
58
Shanghai Jiahua Herong Biotechnology Co., Ltd
Tel
13296077563 13296077563
Email
hr@bettersyn.com
Country
China
ProdList
9937
Advantage
58
Soochow Chirally Material Science and Technology Co.,Ltd
Tel
0512-66834346 17751187418
Email
szkrl2022@126.com
Country
China
ProdList
453
Advantage
58
shanghai yayu biomedical co.,ltd
Tel
021-54370211 18051886391
Email
3007215920@qq.com
Country
China
ProdList
2991
Advantage
58
Henan Vcommend Consultrading Co., Ltd.
Tel
13393721940
Email
sales@vcommend.com
Country
China
ProdList
9886
Advantage
58
Guangdong Shengke Biochemical Technology Co., Ltd.
Tel
189-25112307 18925113981
Email
3809205144@qq.com
Country
China
ProdList
10000
Advantage
58
Shanghai Aladdin Biochemical Technology Co.,Ltd.
Tel
+86-18521732826
Email
market@aladdin-e.com
Country
China
ProdList
48467
Advantage
58
Nantong Hanfang Biotechnology Co. , Ltd.
Tel
3674309880
Email
hanfangpharma@126.com
Country
China
ProdList
30968
Advantage
58
Leshan Bangsheng New Materials Co., Ltd
Tel
0833-2599138 19162614312
Email
lsbangsheng@126.com
Country
China
ProdList
556
Advantage
58

1107608-80-9, (S) QuinoxP(R)Related Search:


  • (S) QuinoxP
  • QuinoxP
  • (S,S)-QuinoxP*
  • 2,3-Bis[(S)-(1,1-dimethylethyl)methylphosphino]quinoxaline
  • (S,S)-(+)-2,3-Bis(t-butylmethylphosphino)quinoxaline
  • (S,S)-(+)-2,3-Bis(t-butylMethylphosphino)quinoxaline (S,S)-QuinoxP*
  • (S) QuinoxP(R)
  • (S,S)-2,3-Bis(tert-butylmethylphosphino)quinoxaline
  • 3-bis((S)-tert-butyl(methyl)phosphino)quinoxaline
  • Quinoxaline, 2,3-bis[(S)-(1,1-dimethylethyl)methylphosphino]-
  • 2,3-bis((S)-tert-butyl(methyl)phosphaneyl)quinoxaline
  • 1107608-80-9
  • Chiral Phosphine