Linoleoyl Chloride
- Product Name
- Linoleoyl Chloride
- CAS No.
- 7459-33-8
- Chemical Name
- Linoleoyl Chloride
- Synonyms
- (9Z,12Z)-octadeca-9,12-dienoyl chloride;LINOLEOYL CHLORIDE;Linoleoyl Choride;LinoleoylChloride>Linoleic acid chloride;Linoleoyl chloride, pract.;(z,z)-12-octadecadienoylchloride;9(Z),12(Z)-Octadecadienoyl chloride;DELTA 9-12 CIS OCTADECADIENOYL CHLORIDE;9,12-Octadecadienoyl chloride, (9Z,12Z)-
- CBNumber
- CB8242000
- Molecular Formula
- C18H31ClO
- Formula Weight
- 298.89
- MOL File
- 7459-33-8.mol
Linoleoyl Chloride Property
- Boiling point:
- 150-152 °C (0.5 mmHg)
- Density
- 0.93
- refractive index
- 1.47-1.49
- storage temp.
- Refrigerator
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- clear liquid
- color
- Colorless to Light orange to Yellow
- Stability:
- Moisture Sensitive
- EPA Substance Registry System
- 9,12-Octadecadienoyl chloride, (9Z,12Z)- (7459-33-8)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 28A-26-45-36/37/39-27
- RIDADR
- UN 3265 8/PG 2
- TSCA
- TSCA listed
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 29130000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P390Absorb spillage to prevent material damage.
P405Store locked up.
P406Store in corrosive resistant/… container with a resistant inner liner.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- L0113
- Product name
- Linoleoyl Chloride
- Purity
- >97.0%(GC)(T)
- Packaging
- 1g
- Price
- $162
- Updated
- 2026/03/19
- Product number
- L467670
- Product name
- Linoleoyl Chloride
- Packaging
- 10g
- Price
- $970
- Updated
- 2021/12/16
- Product number
- 164765
- Product name
- Linoleoyl Chloride
- Packaging
- 1g
- Price
- $396
- Updated
- 2021/12/16
- Product number
- 41195
- Product name
- Linoleoyl Chloride
- Packaging
- 1g
- Price
- $605
- Updated
- 2021/12/16
- Product number
- LIP0000614
- Product name
- LINOLEOYL CHLORIDE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $698.42
- Updated
- 2021/12/16
Linoleoyl Chloride Chemical Properties,Usage,Production
Chemical Properties
dark brown liquid or oil
Uses
Linoleoyl chloride is a volatile compound found in the leaves of white cedar. It is used in the production of antimicrobial agents.
Preparation
A solution of linoleoyl chloride prepared from linoleic acid (2 mmol) and oxalyl chloride (3 mmol) in dichloromethane (5 mL), as described above, was added dropwise to a stirred solution of 3 (1 mmol) in pyridine (5 mL) at room temperature. The reaction mixture was stirred for 1 h at room temperature and then processed as already described. The crude product was subjected to SiO₂ column chromatography by elution with n-hexane/ethyl acetate (20:1, vol/vol) to yield OLP (6) as a colorless oil (0.70 g, 82%). ¹H NMR (CDCl₃, δ): 0.86–0.90 (m by three overlapping triplets, 9H, –CH₃), 1.25–1.62 (m, 64H, –CH₂–), 2.01–2.07 (m, 8H, –C=C–CH₂–), 2.31 (t, J = 6.4 Hz, 6H, –OCO–CH₂–), 2.77 (t, J = 5.5 Hz, 2H, –C=C–CH₂–C=C–), 4.14 (dd, J = 12.2 and 6.3 Hz, 2H, 1- and 3-H), 4.28 (dd, J = 12.2 and 4.4 Hz, 2H, 1- and 3-H), 5.27 (m, 1H, 2-H), and 5.34 ppm (m, 6H, –CH=CH–). ¹³C NMR (CDCl₃, δ): 62.07 (glyceryl C1 and C3), 68.86 (glyceryl C2), 87.11 (–CH–OOH–), 127.86, 128.05, 129.69, 129.97, 129.99, 130.21 (–C=C–), 172.82, and 173.25 ppm (–COO–).
References
[1] Hui, S.-P., Murai, T., Yoshimura, T., Chiba, H., & Kurosawa, T. (2003). Simple chemical syntheses of TAG monohydroperoxides. Lipids, 38 12, 1287–1292. https://doi.org/10.1007/s11745-003-1191-9
[2] Awl, R. A., Frankel, E. N., & Weisleder, D. (1989). Synthesis and characterization of triacylglycerols containing linoleate and linolenate†. Lipids, 24 10, 866–872. https://doi.org/10.1007/BF02535761
Linoleoyl Chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Linoleoyl Chloride manufacturers
- Product
- LINOLEOYL CHLORIDE 7459-33-8
- Price
- US $0.10/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000 tons
- Release date
- 2024-08-13