ChemicalBook > CAS DataBase List > 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE

1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE

Product Name: 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE
CAS No.: 106854-77-7
Chemical Name: 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE
Synonyms: UKRORGSYN-BB BBV-081072;4-(Trifluoroethoxy)bromobenzene;4-(2,2,2-Trifluoroethoxy)bromobenzene;1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE;4-bromo-1-(2,2,2-trifluoroethoxy)benzene;Benzene, 1-bromo-4-(2,2,2-trifluoroethoxy)-
CBNumber: CB8242828
Molecular Formula: C8H6BrF3O
Formula Weight: 255.03
MOL File: 106854-77-7.mol

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1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Property

Boiling point:: 212.8±40.0 °C(Predicted)
Density: 1.569±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
Appearance: White to off-white Solid
InChI: InChI=1S/C8H6BrF3O/c9-6-1-3-7(4-2-6)13-5-8(10,11)12/h1-4H,5H2
InChIKey: SMDIDUHBHCDCRQ-UHFFFAOYSA-N
SMILES: C1(Br)=CC=C(OCC(F)(F)F)C=C1

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Safety

HS Code: 2909309090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: B695128
Product name: 1-Bromo-4-(2,2,2-trifluoroethoxy)benzene
Packaging: 250mg
Price: $55
Updated: 2021/12/16

AK Scientific

Product number: Z3856
Product name: 1-Bromo-4-(2,2,2-trifluoroethoxy)benzene
Packaging: 1g
Price: $85
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2607-B-84
Product name: 1-Bromo-4-(2,2,2-trifluoroethoxy)benzene
Packaging: 5G
Price: $85
Updated: 2021/12/16

Apolloscientific

Product number: PC500829
Product name: 4-(2,2,2-Trifluoroethoxy)bromobenzene
Packaging: 5g
Price: $152
Updated: 2021/12/16

Apolloscientific

Product number: PC500829
Product name: 4-(2,2,2-Trifluoroethoxy)bromobenzene
Packaging: 25g
Price: $446
Updated: 2021/12/16

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1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Chemical Properties,Usage,Production

Synthesis

106-41-2

6226-25-1

106854-77-7

General procedure for the synthesis of 1-bromo-4-(2,2,2-trifluoroethoxy)benzene from 4-bromophenol and 2,2,2-trifluoroethyl trifluoromethanesulfonate: first, 4-bromophenol (9.57 g, 55 mmol) was dissolved in acetone (200 mL), followed by the addition of potassium carbonate (22.89 g, 166 mmol) and 2,2,2-trifluoroethyl trifluoromethanesulfonate ester (16.0 g, 69 mmol). The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, the mixture was filtered to remove the insoluble salt and then concentrated under reduced pressure at 300 mbar at 30 °C to remove the acetone. The final product was 1-bromo-4-(2,2,2-trifluoroethoxy)benzene as a waxy solid (more than 100% yield, as a small amount of acetone remained in the product).

References

[1] Patent: WO2005/822, 2005, A1. Location in patent: Page/Page column 44
[2] Patent: US2016/332999, 2016, A1. Location in patent: Paragraph 0576; 0577

1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE Suppliers

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106854-77-7, 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENERelated Search:

5-bromo-2-(2,2,2-trifluoroethoxy)aniline RARECHEM AL BO 0707 1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE 2-Adamantyl-4-bromo-1-(2,2,2-trifluoroethoxy)benzene 2,6-BIS(2,2,2-TRIFLUOROETHOXY)-3-BROMOBENZONITRILE 2-(4-BROMO-PHENOXY)-3,3,3-TRIFLUORO-PROPYLAMINE RARECHEM AL BW 0738

1-BROMO-4-(2,2,2-TRIFLUOROETHOXY)BENZENE

UKRORGSYN-BB BBV-081072

4-(2,2,2-Trifluoroethoxy)bromobenzene

Benzene, 1-bromo-4-(2,2,2-trifluoroethoxy)-

4-bromo-1-(2,2,2-trifluoroethoxy)benzene

4-(Trifluoroethoxy)bromobenzene

106854-77-7

106854777