2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene
- Product Name
- 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene
- CAS No.
- 67061-69-2
- Chemical Name
- 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene
- Synonyms
- M8806;TTT-2Br;2,6-DibroMo-dithieno[3,2-b;26-dibromobisthieno[32-b23-d]thiophene;2,6-dibromodithieno[2,3-a:2',3'-d]thiophene;2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene;2,6-Dibromodithieno[3,2-b:2’,3’-d]thiophene;2,6-Dibromobisthieno[3,2-b:2',3'-d]thiophene;Dithieno[3,2-b:2',3'-d]thiophene, 2,6-dibromo-;2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene>
- CBNumber
- CB82446147
- Molecular Formula
- C8H2Br2S3
- Formula Weight
- 354.1
- MOL File
- 67061-69-2.mol
2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene Property
- Melting point:
- 171℃ (chloroform methanol )
- Boiling point:
- 447.9±40.0 °C(Predicted)
- Density
- 2.234±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C
- solubility
- soluble in Toluene
- form
- powder to crystal
- color
- White to Light yellow to Green
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313IF eye irritation persists: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 731137
- Product name
- 2,6-Dibromodithieno[3,2-b:2′,3′-d]thiophene
- Purity
- >97%
- Packaging
- 500mg
- Price
- $172.9
- Updated
- 2025/07/31
- Product number
- D3799
- Product name
- 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $370
- Updated
- 2025/07/31
- Product number
- D3799
- Product name
- 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene
- Purity
- >98.0%(GC)
- Packaging
- 200mg
- Price
- $107
- Updated
- 2025/07/31
- Product number
- D448878
- Product name
- 2,6-Dibromodithieno[3,2-b:2'',3''-d]thiophene
- Packaging
- 25mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FD62227
- Product name
- 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene
- Packaging
- 50mg
- Price
- $53
- Updated
- 2021/12/16
2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene Chemical Properties,Usage,Production
Chemical Properties
White to yellow to tan solid
Synthesis
3593-75-7
67061-69-2
General procedure for the synthesis of 2,5-dibromodithieno[3,2-B:2',3'-D]thiophene using dithieno[3,2-B:2',3'-D]thiophene as starting material: at 0 °C, N-bromosuccinimide (5.87 g, 33 mmol) was slowly added to dithieno[3,2-B:2',3'-D]thiophene (Aldrich, 2.94 g, 2.94 g, 2.94 g, 1.5 mmol) dissolved in an anhydrous DMF (60 mL). 15 mmol) was dissolved in a solution of anhydrous DMF (60 mL). The reaction mixture was gradually warmed to room temperature and stirred overnight. Subsequently, the reaction solution was poured into water and the precipitate precipitated was collected. The precipitate was washed with methanol and recrystallized in a chloroform/methanol solvent mixture to finally obtain off-white crystals of 2,5-dibromodithieno[3,2-B:2',3'-D]thiophene (yield: 5.14 g, 97%).1H NMR (500 MHz, CDCl3): δ 7.28 (s, 2H).
References
[1] Journal of Materials Chemistry, 2012, vol. 22, # 33, p. 16810 - 16816
[2] Patent: US2013/207081, 2013, A1. Location in patent: Paragraph 0081; 0082; 0083
[3] Angewandte Chemie - International Edition, 2015, vol. 54, # 9, p. 2734 - 2738
[4] Angew. Chem., 2015, vol. 127, # 9, p. 2772 - 2776,5
[5] Patent: CN105646528, 2016, A. Location in patent: Paragraph 0069; 0070
2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene manufacturers
- Product
- 2,6-Dibromobisthieno[3,2-b:2',3'-d]thiophene 67061-69-2
- Price
- US $1.10-9.90/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 100kg
- Release date
- 2025-08-18
- Product
- 2,6-Dibromodithieno[3,2-b:2',3'-d]thiophene 67061-69-2
- Price
- US $6.68/KG
- Min. Order
- 1KG
- Purity
- 97%-99%
- Supply Ability
- 1kg-1000kg
- Release date
- 2020-01-09