N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE
- Product Name
- N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE
- CAS No.
- 38257-52-2
- Chemical Name
- N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE
- Synonyms
- 4-ITPA;4-iodotriphenylaMine;N-(4-Iodophenyl)diphenylamine;(4-Iodo-phenyl)-diphenyl-amine;4-Iodo-N,N-diphenylaminobenzene;4-Iodo-N,N-diphenyl-benzenaMine;4-(N,N-diphenylamino)iodobenzene;BenzenaMine, 4-iodo-N,N-diphenyl-;N-(4-IODOPHENYL)-N-PHENYLBENZEMINE;N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE
- CBNumber
- CB82455668
- Molecular Formula
- C18H14IN
- Formula Weight
- 371.22
- MOL File
- 38257-52-2.mol
N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE Property
- Melting point:
- 107.1-107.9℃ (hexane )
- Boiling point:
- 434.1±28.0 °C(Predicted)
- Density
- 1.529±0.06 g/cm3 (20 ºC 760 Torr)
- storage temp.
- 2-8°C(protect from light)
- form
- powder to crystal
- pka
- -3.71±0.30(Predicted)
- color
- White to Light yellow to Light orange
- λmax
- 307nm(lit.)
Safety
- HS Code
- 2921.49.5000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- I0951
- Product name
- 4-Iodotriphenylamine
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $37
- Updated
- 2025/07/31
- Product number
- I0951
- Product name
- 4-Iodotriphenylamine
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $103
- Updated
- 2024/03/01
- Product number
- 4935AB
- Product name
- 4-Iodo-N,N-diphenylaniline
- Packaging
- 5g
- Price
- $263
- Updated
- 2021/12/16
- Product number
- 098162
- Product name
- 4-Iodo-N,N-diphenylaniline
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $303
- Updated
- 2021/12/16
- Product number
- HCH0361301
- Product name
- 4-IODO-N,N-DIPHENYLANILINE
- Purity
- 95.00%
- Packaging
- 5MG
- Price
- $505.69
- Updated
- 2021/12/16
N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE Chemical Properties,Usage,Production
Synthesis
624-38-4
122-39-4
38257-52-2
GENERAL STEPS: 1,4-Diiodobenzene (396 mg, 1.2 mmol), diphenylamine (169 mg, 1 mmol), cuprous iodide (CuI, 19 mg, 0.1 mmol), phenanthroline (28.2 mg, 0.12 mmol) and potassium hydroxide (224 mg) were added to anhydrous toluene (20 mL) under nitrogen protection. The reaction mixture was heated to 120 °C and the reaction was stirred at this temperature for about 12 hours. Upon completion of the reaction, water (30 mL) was added to quench the reaction. The reaction mixture was extracted three times with dichloromethane (CH2Cl2, 30 mL), the organic phases were combined and dried overnight with anhydrous magnesium sulfate. The organic solvent was removed by evaporation under reduced pressure to give the crude product. The crude product was purified by silica gel column chromatography with petroleum ether as eluent to afford N-(4-iodophenyl)-N-phenylaniline (315.4 mg, 85%) as white powder. Melting point >300°C; 1H NMR (300 MHz, CDCl3): δ 7.58 (d, 2H), 7.28 (m, 4H), 7.08 (m, 6H), 6.83 (d, 2H); MS (ESI): m/z, calculated value for C18H14IN: 371.21, measured value: 372.02 [M + H]+.
References
[1] Tetrahedron, 2014, vol. 70, # 10, p. 1903 - 1909
[2] Journal of Molecular Structure, 2014, vol. 1056-1057, # 1, p. 339 - 346
[3] Journal of Polymer Science, Part A: Polymer Chemistry, 2011, vol. 49, # 2, p. 392 - 402
[4] Journal of the American Chemical Society, 2006, vol. 128, # 11, p. 3789 - 3799
[5] Angewandte Chemie - International Edition, 2013, vol. 52, # 48, p. 12696 - 12700
N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE Preparation Products And Raw materials
Raw materials
Preparation Products
N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE Suppliers
- Tel
- 320-37350700
- Fax
- +32 (0)37350701
- sales@tcieurope.eu
- Country
- Europe
- ProdList
- 23671
- Advantage
- 75
View Lastest Price from N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE manufacturers
- Product
- n-(4-iodophenyl)-n-phenylbenzenamine 38257-52-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 150KG /month
- Release date
- 2021-11-19
- Product
- N-(4-IODOPHENYL)-N-PHENYLBENZENAMINE 38257-52-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-08-16
- Product
- 4-Iodo-N,N-diphenylaniline 38257-52-2
- Price
- US $200.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%, 99.5% Sublimated
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-30