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ChemicalBook > CAS DataBase List > (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE

(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE

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Product Name
(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE
CAS No.
914089-00-2
Chemical Name
(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE
Synonyms
amino)(2-dicycL;Taniaphos ligand;phosphinoferrocenyL;(S)-(-)-[(S)-2-DicycL;(SP)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene;(S?)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene;(SP)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene;(SP)-1-Dicyclohexylphosphino-2-[(S)-alpha-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene;(1R)-1-(Dicyclohexylphosphino)-2-[(S)-[2-(dicyclohexylphosphino)phenyl](dimethylamino)methyl]ferrocene;(1Sp)-1-(Dicyclohexylphosphino)-2-[(S)-[2-(dicyclohexylphosphino)phenyl](dimethylamino)methyl]ferrocene
CBNumber
CB8250317
Molecular Formula
C43H63FeNP210*
Formula Weight
711.76
MOL File
914089-00-2.mol
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(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Property

alpha 
-110° ±10° (c 0.5, CHCl3)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange
Stability:
store cold
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Safety

WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Strem Chemicals
Product number
26-0955
Product name
(S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2-dicyclohexylphosphinophenyl)methane, min. 97%
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
26-0955
Product name
(S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2-dicyclohexylphosphinophenyl)methane, min. 97%
Packaging
500mg
Price
$355
Updated
2024/03/01
Strem Chemicals
Product number
26-0955
Product name
(S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2-dicyclohexylphosphinophenyl)methane, min. 97%
Packaging
2g
Price
$1207
Updated
2024/03/01
Strem Chemicals
Product number
26-0955
Product name
(S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2-dicyclohexylphosphinophenyl)methane, min. 97%
Packaging
10g
Price
$4824
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
OGM0002676
Product name
(SP)-1-DICYCLOHEXYLPHOSPHINO-2-[(S)-ALPHA-(DIMETHYLAMINO)-2-(DICYCLOHEXYLPHOSPHINO)BENZYL]FERROCENE
Purity
95.00%
Packaging
5MG
Price
$501.48
Updated
2021/12/16
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(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Chemical Properties,Usage,Production

Reactions

  1. Iron catalyst for olefin cross-coupling
  2. Iron catalyst for regioselective alkylation of diols and polyols.
  3. Ligand for the iridium-catalyzed asymmetric cis hydrogenation of bromobenzothiazepine.

Chemical Properties

Orange powder

General Description

sold in collaboration with Solvias AG

(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Preparation Products And Raw materials

Raw materials

Preparation Products

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(S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE Suppliers

China 27 Germany 1 Switzerland 1 United States 3 Global 32
ABCR GmbH & CO. KG
Tel
--
Fax
--
Email
info@abcr.de
Country
Germany
ProdList
6831
Advantage
75

914089-00-2, (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANERelated Search:

(S)-(-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE (+/-)-N,N-DIMETHYL-1-FERROCENYLETHYLAMINE Dicyclohexylphenylphosphine DI-N-PENTYLPHENYLPHOSPHINE DIBUTYLPHENYLPHOSPHINE N,N-Dimethylaminomethylferrocene (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE

  • (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE
  • (SP)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene
  • Taniaphos SL-T002-2, (1R)-1-(Dicyclohexylphosphino)-2-[(S)-[2-(dicyclohexylphosphino)phenyl](dimethylamino)methyl]ferrocene (acc to CAS)
  • (S)-(+)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2- dicyclohexylphosphinophenyl)methane, min. 97%
  • Taniaphos ligand
  • (S)-(+)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-diMethylaMino)(2-dicyclohexylphosphinophenyl)Methane,Min.97%
  • (S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-diMethylaMino)(2-dicyclohexylphosphinophenyl)Methane
  • (S)-1-Dicyclohexylphosphino-2-[(S)-a-(N,N-dimethylamino)-o-(dicyclohexylphosphinophenyl)methyl]-ferrocene
  • (SP)-1-Dicyclohexylphosphino-2-[(S)-alpha-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene >=97%
  • phosphinoferrocenyL
  • amino)(2-dicycL
  • (S)-(-)-[(S)-2-DicycL
  • (SP)-1-Dicyclohexylphosphino-2-[(S)-alpha-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene
  • (S)-1-Dicyclohexylphosphino-2-[(S)-(N,N-dimethylamino) [2-(dicyclohexylphosphino)phenyl]methyl]ferrocene
  • (S)-(+)-[(R)-2-DICYCLOHEXYLPHOSPHINOFERROCENYL](N,N-DIMETHYLAMINO)(2-DICYCLOHEXYLPHOSPHINOPHENYL)METHANE ISO 9001：2015 REACH
  • (1R)-1-(Dicyclohexylphosphino)-2-[(S)-[2-(dicyclohexylphosphino)phenyl](dimethylamino)methyl]ferrocene
  • (S?)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene
  • (SP)-1-Dicyclohexylphosphino-2-[(S)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene
  • (1Sp)-1-(Dicyclohexylphosphino)-2-[(S)-[2-(dicyclohexylphosphino)phenyl](dimethylamino)methyl]ferrocene
  • (S)-(-)-[(S)-2-Dicyclohexylphosphinoferrocenyl](N,N-dimethylamino)(2-dicyclohexylphosphinophenyl)methane,97%
  • 914089-00-2
  • Chiral Phosphine
  • Ferrocene Series
  • Taniaphos Series