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(+)-ALPHA-LONGIPINENE

Product Name
(+)-ALPHA-LONGIPINENE
CAS No.
5989-08-2
Chemical Name
(+)-ALPHA-LONGIPINENE
Synonyms
(+)-α-longipinene;Longipinene (>80%);(+)-alfa-Longipinene;(+)-alfa-Longipinene;(+)-ALPHA-LONGIPINENE;(+)-ALPHA-LONGIPINENE;Phenyl Acetate Impurity 43;97.0% (sum of enantiomers, GC);2,6,6,9-Tetramethyl-tricyclo[5.4.0.0(2,8)]undec-9-ene;(+)-alpha-Longipinene >=99.0% (sum of enantiomers, GC)
CBNumber
CB8252513
Molecular Formula
C15H24
Formula Weight
204.35
MOL File
5989-08-2.mol
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(+)-ALPHA-LONGIPINENE Property

Boiling point:
244-246 °C(lit.)
Density 
0.915 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.493
Flash point:
92℃
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Dichloromethane (Slightly), Methanol (Slightly)
form 
Oil
color 
Colourless
optical activity
[α]20/D +25±1°, neat
Stability:
Light Sensitive
LogP
6.398 (est)
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Safety

Safety Statements 
23-24/25
RIDADR 
NA 1993 / PGIII
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
62638
Product name
(+)-α-Longipinene
Purity
≥97.0% (sum of enantiomers, GC)
Packaging
250mg
Price
$396
Updated
2023/06/20
Usbiological
Product number
453881
Product name
Longipinene
Packaging
5mg
Price
$305
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HBL0000014
Product name
(+)-ALPHA-LONGIPINENE
Purity
95.00%
Packaging
250MG
Price
$879.25
Updated
2021/12/16
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(+)-ALPHA-LONGIPINENE Chemical Properties,Usage,Production

Uses

(+)-α-Longipinene can be used as a starting material for the synthesis of new terpenoids, (+)-(5S)-5,12-dihydroxy-α-longipinene, (-)-(5R)-5,12-dihydroxy-α-longipinene, and (+)-12-hydroxy-α-longipinen-5-one by oxidation reaction using Aspergillus niger as a biocatalyst. It can be oxidized using lead tetraacetate into tertiary alcohol, longi-cis-verbenol, longi-trans-verbenol, longi-cis-β-crysanthenol, longiverbenone, longi-trans- β -crysanthenol, 2 β,3 β -dihydroxylongipinane, 4 α,8-dihydroxy- α -Iongipinene, and 4 β,8-dihydroxy- α -longipinene.

Definition

ChEBI: A bridged compound and sesquiterpene that is tricyclo[5.4.0.02,8]undecane that is substituted by methyl groups at the 2, 6, 6, and 9 positions and has a double bond between positions 9 and 10.

(+)-ALPHA-LONGIPINENE Preparation Products And Raw materials

Raw materials

Preparation Products

5989-08-2, (+)-ALPHA-LONGIPINENERelated Search:


  • Tricyclo[5.4.0.0(2,8)]undec-9-ene, 2,6,6,9-tetramethyl-
  • Tricyclo[5.4.0.0(2,8)]undec-9-ene, 3,3,7,9-tetramethyl-
  • (+)-alpha-Longipinene >=99.0% (sum of enantiomers, GC)
  • (1R,2S,7R,8R)-2,6,6,9-TETRAMETHYL-TRICYCLO[5.4.0.0(2.8)]UNDEC-9-ENE
  • (+)-ALPHA-LONGIPINENE
  • (+)-α-longipinene
  • 2,6,6,9-Tetramethyl-tricyclo[5.4.0.0(2,8)]undec-9-ene
  • (+)-alfa-Longipinene
  • Tricyclo[5.4.0.02,8]undec-9-ene, 2,6,6,9-tetramethyl-, (1R,2S,7R,8R)-
  • Longipinene (>80%)
  • α-longipineneQ: What is α-longipinene Q: What is the CAS Number of α-longipinene
  • (+)-ALPHA-LONGIPINENE
  • 97.0% (sum of enantiomers, GC)
  • (+)-alfa-Longipinene
  • Phenyl Acetate Impurity 43
  • 5989-08-2
  • Complex Molecules
  • Asymmetric Synthesis
  • Chiral Building Blocks