4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene

Product Name: 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene
CAS No.: 335013-18-8
Chemical Name: 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene
Synonyms: 4-Bromo-2-(trifluoromethyl)benzyl bromide 95%;4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene;Benzene, 4-bromo-1-(bromomethyl)-2-(trifluoromethyl)-;4-bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene, 95%min
CBNumber: CB82609902
Molecular Formula: C8H5Br2F3
Formula Weight: 317.93
MOL File: 335013-18-8.mol

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4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene Property

Boiling point:: 239.4±35.0 °C(Predicted)
Density: 1.885±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: liquid
color: Colorless

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Safety

HS Code: 2902900000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B680928
Product name: 4-Bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene
Packaging: 50mg
Price: $45
Updated: 2021/12/16

TRC

Product number: B680928
Product name: 4-Bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene
Packaging: 100mg
Price: $60
Updated: 2021/12/16

Oakwood

Product number: 232932
Product name: 4-Bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene
Purity: 98%
Packaging: 1g
Price: $70
Updated: 2021/12/16

SynQuest Laboratories

Product number: 1800-B-58
Product name: 4-Bromo-2-(trifluoromethyl)benzyl bromide
Packaging: 1g
Price: $77
Updated: 2021/12/16

Matrix Scientific

Product number: 096869
Product name: 4-Bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene
Purity: 95+%
Packaging: 1g
Price: $165
Updated: 2021/12/16

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4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene Chemical Properties,Usage,Production

Synthesis

86845-27-4

335013-18-8

General procedure for the synthesis of 4-bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene from 5-bromo-2-methyltrifluorotoluene: 5-bromo-2-methyltrifluorotoluene (25 g, 104.59 mmol), N-bromosuccinimide (18.62 g, 104.59 mmol) and benzoyl peroxide (1.27 g, 5.23 mmol) were reacted in a A mixture in carbon tetrachloride (35 mL) was heated and reacted at 90 °C for 4 hours. Upon completion of the reaction, the mixture was cooled to 0 °C and filtered through a glass sand core funnel and the solids were washed with dichloromethane. The filtrates were combined and concentrated and subsequently purified by fast column chromatography (eluent: hexane/ethyl acetate, 0% to 5% ethyl acetate gradient) to give a clear oily product, which was crystallized after standing (33.26 g, 100% yield). The structure of the product was confirmed by 1H NMR (400 MHz, CDCl3): δ 4.57 (s, 2H), 7.46 (d, J = 8.3 Hz, 1H), 7.67 (d, J = 8.3 Hz, 1H), 7.78 (s, 1H).

References

[1] Patent: WO2006/18725, 2006, A1. Location in patent: Page/Page column 208
[2] Journal of Labelled Compounds and Radiopharmaceuticals, 2015, vol. 58, # 5, p. 188 - 195
[3] Patent: WO2008/148867, 2008, A2. Location in patent: Page/Page column 37
[4] Patent: WO2009/23964, 2009, A1. Location in patent: Page/Page column 24
[5] Patent: WO2006/46593, 2006, A1. Location in patent: Page/Page column 235

4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene Suppliers

China 51 India 1 United Kingdom 1 United States 6 Global 59

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View Lastest Price from 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene manufacturers

Career Henan Chemical Co

Product: 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene 335013-18-8
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kg
Release date: 2018-12-25

335013-18-8, 4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzeneRelated Search:

4-broMo-1-(broMoMethyl)-2-(trifluoroMethyl)benzene

4-Bromo-2-(trifluoromethyl)benzyl bromide 95%

Benzene, 4-bromo-1-(bromomethyl)-2-(trifluoromethyl)-

4-bromo-1-(bromomethyl)-2-(trifluoromethyl)benzene, 95%min

335013-18-8