ChemicalBook > CAS DataBase List > 2-Methyl-2-(3-nitrophenyl)propanenitrile

2-Methyl-2-(3-nitrophenyl)propanenitrile

Product Name
2-Methyl-2-(3-nitrophenyl)propanenitrile
CAS No.
915394-28-4
Chemical Name
2-Methyl-2-(3-nitrophenyl)propanenitrile
Synonyms
2-Methyl-2-(3-nitrophenyl)propanenitrile;Benzeneacetonitrile, α,α-dimethyl-3-nitro-
CBNumber
CB82662411
Molecular Formula
C10H10N2O2
Formula Weight
190.2
MOL File
915394-28-4.mol
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2-Methyl-2-(3-nitrophenyl)propanenitrile Property

Boiling point:
307.4±17.0 °C(Predicted)
Density 
1.178±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
Appearance
White to light yellow Solid
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Safety

HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

TRC
Product number
M350735
Product name
2-Methyl-2-(3-nitrophenyl)propanenitrile
Packaging
500mg
Price
$65
Updated
2021/12/16
AK Scientific
Product number
Z5342
Product name
2-Methyl-2-(3-nitrophenyl)propanenitrile
Packaging
1g
Price
$127
Updated
2021/12/16
Apolloscientific
Product number
OR916221
Product name
2-Methyl-2-(3-nitrophenyl)propanenitrile
Purity
95%
Packaging
1g
Price
$174
Updated
2021/12/16
Matrix Scientific
Product number
119669
Product name
2-Methyl-2-(3-nitrophenyl)propanenitrile
Purity
95+%
Packaging
1g
Price
$270
Updated
2021/12/16
AK Scientific
Product number
Z5342
Product name
2-Methyl-2-(3-nitrophenyl)propanenitrile
Packaging
5g
Price
$339
Updated
2021/12/16
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2-Methyl-2-(3-nitrophenyl)propanenitrile Chemical Properties,Usage,Production

Synthesis

621-50-1

74-88-4

915394-28-4

Anhydrous tetrahydrofuran solution (30 mL) of 2-(3-nitrophenyl)acetonitrile (4.2 g, 25.9 mmol) was added slowly and dropwise to an anhydrous tetrahydrofuran (30 mL) suspension of 50% sodium hydride (6.84 g, 171 mmol) cooled in an ice bath. After dropwise addition, stirring was continued for 30 min, followed by slow addition of iodomethane (12.63 mL, 202 mmol). The reaction mixture was gradually warmed to room temperature and stirred overnight. After completion of the reaction, the reaction was quenched with ice water. The reaction mixture was extracted with ethyl acetate, the organic layer was separated, washed with water and dried over anhydrous sodium sulfate. The crude product was obtained by filtration and concentration. The crude product was purified by silica gel column chromatography using ethyl acetate/hexane (5:95) as eluent to afford 2-methyl-2-(3-nitrophenyl)propionitrile (2.1 g).1H NMR (400 MHz, CDCl3) δ 8.33-8.32 (m, 1H), 8.24-8.21 (m, 1H), 7.92-7.89 (m, 1H), 7.63 (t, J = 8.00 Hz, 1H), 1.82 (s, 6H).GCMS: 190.11 [M+].

References

[1] Patent: WO2006/123145, 2006, A1. Location in patent: Page/Page column 49
[2] Bioorganic and Medicinal Chemistry Letters, 2018, vol. 28, # 4, p. 577 - 583
[3] Patent: EP2876107, 2015, A1. Location in patent: Paragraph 0085
[4] Patent: US2015/191450, 2015, A1. Location in patent: Paragraph 0176-0178
[5] Patent: WO2013/136249, 2013, A1. Location in patent: Page/Page column 49-50

2-Methyl-2-(3-nitrophenyl)propanenitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Methyl-2-(3-nitrophenyl)propanenitrile Suppliers

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915394-28-4, 2-Methyl-2-(3-nitrophenyl)propanenitrileRelated Search:


  • 2-Methyl-2-(3-nitrophenyl)propanenitrile
  • Benzeneacetonitrile, α,α-dimethyl-3-nitro-
  • 915394-28-4