ChemicalBook > CAS DataBase List > 1-(1-Methyl-1H-iMidazol-5-yl)ethanone

1-(1-Methyl-1H-iMidazol-5-yl)ethanone

Product Name
1-(1-Methyl-1H-iMidazol-5-yl)ethanone
CAS No.
20970-50-7
Chemical Name
1-(1-Methyl-1H-iMidazol-5-yl)ethanone
Synonyms
5-Acetyl-1-methylimidazole;1-(3-methylimidazol-4-yl)ethanone;1-(1-Methyl-1H-iMidazol-5-yl)ethanone;Ethanone, 1-(1-methyl-1H-imidazol-5-yl)-
CBNumber
CB82677338
Molecular Formula
C6H8N2O
Formula Weight
124.14
MOL File
20970-50-7.mol
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1-(1-Methyl-1H-iMidazol-5-yl)ethanone Property

storage temp. 
Sealed in dry,Room Temperature
Appearance
White to yellow Solid
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Safety

HS Code 
2933998090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
4596AQ
Product name
1-(3-methylimidazol-4-yl)ethanone
Packaging
100mg
Price
$245.6
Updated
2021/12/16
AK Scientific
Product number
4596AQ
Product name
1-(3-methylimidazol-4-yl)ethanone
Packaging
250mg
Price
$377.6
Updated
2021/12/16
AK Scientific
Product number
4596AQ
Product name
1-(3-methylimidazol-4-yl)ethanone
Packaging
1g
Price
$706.4
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CHM0371342
Product name
1-(1-METHYL-1H-IMIDAZOL-5-YL)ETHANONE
Purity
95.00%
Packaging
5MG
Price
$504.86
Updated
2021/12/16
Abosyn
Product number
61-10383
Product name
1-(1-Methyl-1H-imidazol-5-yl)ethanone
Purity
95-98%
Packaging
1g
Price
$522
Updated
2021/12/16
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1-(1-Methyl-1H-iMidazol-5-yl)ethanone Chemical Properties,Usage,Production

Synthesis

592554-79-5

75-16-1

20970-50-7

General procedure for the synthesis of 1-(1-methyl-1H-imidazol-5-yl)ethanone from the compound (CAS: 592554-79-5) and methylmagnesium bromide: First, the crude product (882) (14.2 mmol) was dissolved in tetrahydrofuran (THF) (100 mL). Methylmagnesium bromide (3 M solution in ether) (22.2 mL) was slowly added under cooling conditions in an ice bath, the titration was controlled to be completed within 10 min and the reaction was carried out under nitrogen (N2) protection. Subsequently, the reaction mixture was warmed up to 40 °C and stirred continuously for 4 h or until the reaction was complete. After completion of the reaction, it was again cooled in an ice bath and the reaction was quenched by slow addition of saturated ammonium chloride (NH4Cl) solution. Initial extraction was carried out with ethyl acetate followed by three extractions with dichloromethane (CH2Cl2). The organic phases were combined, dried with anhydrous magnesium sulfate, filtered and the solvent evaporated. Finally, the product was stored under vacuum to afford crystalline 1-(1-methyl-1H-imidazol-5-yl)ethanone (883) (1.78 g, 74% yield).

References

[1] Patent: US2004/122018, 2004, A1. Location in patent: Page 349

1-(1-Methyl-1H-iMidazol-5-yl)ethanone Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(1-Methyl-1H-iMidazol-5-yl)ethanone Suppliers

Nanjing Norris-Pharm Technology Co., Ltd
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18652989687
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China
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China
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4677
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Shanghai ChuangYan Chemical Technology Co., Ltd.
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China
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Aikon International Limited
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Shanghai Lanle Bird Industrial Co., Ltd.
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20970-50-7, 1-(1-Methyl-1H-iMidazol-5-yl)ethanoneRelated Search:


  • 1-(1-Methyl-1H-iMidazol-5-yl)ethanone
  • Ethanone, 1-(1-methyl-1H-imidazol-5-yl)-
  • 1-(3-methylimidazol-4-yl)ethanone
  • 5-Acetyl-1-methylimidazole
  • 20970-50-7