ChemicalBook > CAS DataBase List > 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3

2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3

Product Name
2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3
CAS No.
1269004-46-7
Chemical Name
2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3
Synonyms
PM189;DPP26-2B;2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[;2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3;2,5-bis(2-ethylhexyl)-1,4-bis[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-dione;2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H )-dione;Pyrrolo[3,4-c]pyrrole-1,4-dione, 2,5-bis(2-ethylhexyl)-2,5-dihydro-3,6-bis[5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-2-thienyl]-;2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione
CBNumber
CB82682437
Molecular Formula
C42H62B2N2O6S2
Formula Weight
776.7
MOL File
1269004-46-7.mol
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2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Property

Melting point:
242-244 °C
Boiling point:
857.8±65.0 °C(Predicted)
Density 
1.16±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
pka
-4.78±0.60(Predicted)
Appearance
Pink to red Solid
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Ambeed
Product number
A138819
Product name
2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
Purity
95+%
Packaging
50mg
Price
$95
Updated
2021/12/16
Ambeed
Product number
A138819
Product name
2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
Purity
95+%
Packaging
100mg
Price
$142
Updated
2021/12/16
Ambeed
Product number
A138819
Product name
2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
Purity
95+%
Packaging
250mg
Price
$210
Updated
2021/12/16
Crysdot
Product number
CD41002118
Product name
2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
Purity
95+%
Packaging
1g
Price
$500
Updated
2021/12/16
Ambeed
Product number
A138819
Product name
2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
Purity
95+%
Packaging
1g
Price
$525
Updated
2021/12/16
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2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Chemical Properties,Usage,Production

Synthesis

1000623-95-9

73183-34-3

1269004-46-7

To a 100 mL flask under nitrogen protection was added 3,6-bis(5-bromo-2-thienyl)-2,5-bis(2-ethylhexyl)-2,5-dihydropyrrolo[3,4-C]pyrrole-1,4-dione (3.70 g, 5.4 mmol), bis(pinacolato)diboron (3.00 g, 11.8 mmol), potassium acetate (2.59 g, 26.4 mmol), [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride dichloromethane adduct (0.09 g, 0.1 mmol), 1,1'-bis(diphenylphosphino)ferrocene (0.06 g, 0.1 mmol) and anhydrous 1,4-dioxane (300 mL). The mixture was heated with stirring at 120 °C for 15 hours. After completion of the reaction, the reaction solution was filtered through diatomaceous earth and the filtrate was concentrated by rotary evaporator. Chloroform (200 mL) was added to the residue and heated with stirring at 80 °C, followed by the addition of acetonitrile (400 mL), and this operation was repeated 5 times. The mixture was stirred and cooled to room temperature and stirring was continued for 1 hour. The solid product was collected by filtration, washed twice with acetonitrile (100 mL) and dried under reduced pressure to afford 2,5-bis(2-ethylhexyl)-3,6-bis(5-boronic acid pinacol ester thienyl)- pyrrolo[pyrrolidin]dione (Compound 14) in a yield of 2.25 g (0.24 mmol) in 53.4%.

References

[1] Patent: JP6140482, 2017, B2. Location in patent: Paragraph 0210

2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Preparation Products And Raw materials

Raw materials

Preparation Products

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2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Suppliers

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View Lastest Price from 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H )-dione 1269004-46-7
Price
US $3.00-9.00/kg
Min. Order
1kg
Purity
99%min
Supply Ability
50kg
Release date
2025-08-01
Career Henan Chemical Co
Product
2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 1269004-46-7
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
200kg
Release date
2020-01-14

1269004-46-7, 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3Related Search:


  • 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3
  • 2,5-bis(2-ethylhexyl)-1,4-bis[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-dione
  • 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[
  • 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione
  • 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H )-dione
  • Pyrrolo[3,4-c]pyrrole-1,4-dione, 2,5-bis(2-ethylhexyl)-2,5-dihydro-3,6-bis[5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-2-thienyl]-
  • PM189
  • DPP26-2B
  • 1269004-46-7
  • Diketopyrrolopyrrole