2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3
- Product Name
- 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3
- CAS No.
- 1269004-46-7
- Chemical Name
- 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3
- Synonyms
- PM189;DPP26-2B;2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[;2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3;2,5-bis(2-ethylhexyl)-1,4-bis[5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl]pyrrolo[3,4-c]pyrrole-3,6-dione;2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H )-dione;Pyrrolo[3,4-c]pyrrole-1,4-dione, 2,5-bis(2-ethylhexyl)-2,5-dihydro-3,6-bis[5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)-2-thienyl]-;2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)-2,5-dihydropyrrolo[3,4-c]pyrrole-1,4-dione
- CBNumber
- CB82682437
- Molecular Formula
- C42H62B2N2O6S2
- Formula Weight
- 776.7
- MOL File
- 1269004-46-7.mol
2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Property
- Melting point:
- 242-244 °C
- Boiling point:
- 857.8±65.0 °C(Predicted)
- Density
- 1.16±0.1 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
- pka
- -4.78±0.60(Predicted)
- Appearance
- Pink to red Solid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- A138819
- Product name
- 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
- Purity
- 95+%
- Packaging
- 50mg
- Price
- $95
- Updated
- 2021/12/16
- Product number
- A138819
- Product name
- 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
- Purity
- 95+%
- Packaging
- 100mg
- Price
- $142
- Updated
- 2021/12/16
- Product number
- A138819
- Product name
- 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
- Purity
- 95+%
- Packaging
- 250mg
- Price
- $210
- Updated
- 2021/12/16
- Product number
- CD41002118
- Product name
- 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
- Purity
- 95+%
- Packaging
- 1g
- Price
- $500
- Updated
- 2021/12/16
- Product number
- A138819
- Product name
- 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione
- Purity
- 95+%
- Packaging
- 1g
- Price
- $525
- Updated
- 2021/12/16
2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Chemical Properties,Usage,Production
Synthesis
1000623-95-9
73183-34-3
1269004-46-7
To a 100 mL flask under nitrogen protection was added 3,6-bis(5-bromo-2-thienyl)-2,5-bis(2-ethylhexyl)-2,5-dihydropyrrolo[3,4-C]pyrrole-1,4-dione (3.70 g, 5.4 mmol), bis(pinacolato)diboron (3.00 g, 11.8 mmol), potassium acetate (2.59 g, 26.4 mmol), [1,1'-bis(diphenylphosphino)ferrocene]palladium(II) dichloride dichloromethane adduct (0.09 g, 0.1 mmol), 1,1'-bis(diphenylphosphino)ferrocene (0.06 g, 0.1 mmol) and anhydrous 1,4-dioxane (300 mL). The mixture was heated with stirring at 120 °C for 15 hours. After completion of the reaction, the reaction solution was filtered through diatomaceous earth and the filtrate was concentrated by rotary evaporator. Chloroform (200 mL) was added to the residue and heated with stirring at 80 °C, followed by the addition of acetonitrile (400 mL), and this operation was repeated 5 times. The mixture was stirred and cooled to room temperature and stirring was continued for 1 hour. The solid product was collected by filtration, washed twice with acetonitrile (100 mL) and dried under reduced pressure to afford 2,5-bis(2-ethylhexyl)-3,6-bis(5-boronic acid pinacol ester thienyl)- pyrrolo[pyrrolidin]dione (Compound 14) in a yield of 2.25 g (0.24 mmol) in 53.4%.
References
[1] Patent: JP6140482, 2017, B2. Location in patent: Paragraph 0210
2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 manufacturers
- Product
- 2,5-Bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3,4-c ]pyrrole-1,4(2H ,5H )-dione 1269004-46-7
- Price
- US $3.00-9.00/kg
- Min. Order
- 1kg
- Purity
- 99%min
- Supply Ability
- 50kg
- Release date
- 2025-08-01
- Product
- 2,5-bis(2-ethylhexyl)-3,6-bis(5-(4,4,5,5-tetraMethyl-1,3,2-dioxaborolan-2-yl)thiophen-2-yl)pyrrolo[3 1269004-46-7
- Price
- US $1.00/g
- Min. Order
- 1g
- Purity
- 99%
- Supply Ability
- 200kg
- Release date
- 2020-01-14