DifluoroiodoMethyl phenyl sulfone
- Product Name
- DifluoroiodoMethyl phenyl sulfone
- CAS No.
- 802919-90-0
- Chemical Name
- DifluoroiodoMethyl phenyl sulfone
- Synonyms
- DifluoroiodoMethyl phenyl sulfone;(difluoroiodomethylsulfonyl)benzene;Benzene, [(difluoroiodomethyl)sulfonyl]-
- CBNumber
- CB82709840
- Molecular Formula
- C7H5F2IO2S
- Formula Weight
- 318.08
- MOL File
- 802919-90-0.mol
DifluoroiodoMethyl phenyl sulfone Property
- Boiling point:
- 312.4±42.0 °C(Predicted)
- Density
- 1.975±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
Safety
- Safety Statements
- 24/25
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- 8573AJ
- Product name
- Difluoroiodomethylphenylsulfone
- Packaging
- 250mg
- Price
- $162
- Updated
- 2021/12/16
- Product number
- JK1711633
- Product name
- Difluoroiodomethylphenylsulfone
- Purity
- 98%
- Packaging
- 250mg
- Price
- $72
- Updated
- 2021/12/16
- Product number
- 8573AJ
- Product name
- Difluoroiodomethylphenylsulfone
- Packaging
- 1g
- Price
- $358
- Updated
- 2021/12/16
- Product number
- PC911469
- Product name
- [(Difluoroiodomethyl)sulfonyl]benzene
- Purity
- 98%
- Packaging
- 1g
- Price
- $475
- Updated
- 2021/12/16
- Product number
- A264821
- Product name
- ((Difluoroiodomethyl)sulfonyl)benzene
- Purity
- 98%
- Packaging
- 5g
- Price
- $890
- Updated
- 2021/12/16
DifluoroiodoMethyl phenyl sulfone Chemical Properties,Usage,Production
Description
A visible light-catalysed direct and regioselective (phenylsulfonyl) difluoromethylation of imidazo[1,2-A]pyridines and benzo[d]-imidazo[2,1-b]thiazoles was carried out by DifluoroiodoMethyl phenyl sulfone under mild conditions. This synthetic methodology enables the introduction of a CF2SO2Ph group in an efficient and regioselective reaction through C-H bond functionalization with a broad substrate scope in good to excellent yields.
Uses
Iododifluoromethyl phenyl sulfone can be used for the difluoromethylation of alkenes and alkynes initiated by triethylborane/air or arenediazonium salt/titanium chloride in moderate to good yields.
Reactions
(1) Difluoromethylation of terminal alkenes and alkynes.
References
[1] GUO-JIE YIN; W. F; Mei Zhu. Visible-light mediated regioselective (phenylsulfonyl)difluoromethylation of fused imidazoles with iododifluoromethyl phenyl sulfone[J]. Heterocyclic Communications, 2017. DOI:10.1515/hc-2017-0101.
[2] YA LI. Radical (Phenylsulfonyl)difluoromethylation with Iododifluoromethyl Phenyl Sulfone[J]. The Journal of Organic Chemistry, 2007. DOI:10.1021/jo070618s.
DifluoroiodoMethyl phenyl sulfone Preparation Products And Raw materials
Raw materials
Preparation Products
DifluoroiodoMethyl phenyl sulfone Suppliers
- Tel
- +1-833-552-7181
- sales@aladdinsci.com
- Country
- United States
- ProdList
- 52927
- Advantage
- 58