Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)
Reaction- Product Name
- Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)
- CAS No.
- 1419179-26-2
- Chemical Name
- Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)
- Synonyms
- Jamison Catalyst;Trans-Bis(dicycL;chlorobis(dicyclohexylphenyl)(2-methylphenyl)nickel;Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II);(II)Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II);Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II), 99%;trans-Bis(dicyclohexylphenylphosphine)(2-methylphenyl)nickel(II) chloride;(2,1,3-Benzothiadiazole)- κ N1) carbonyl chloride [(1E) -2- (1-styryl) vinyl] bis (triphenylphosphine) ruthenium (II)
- CBNumber
- CB82710037
- Molecular Formula
- C43H59ClNiP2-2
- Formula Weight
- 732.022482
- MOL File
- 1419179-26-2.mol
Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Property
- Melting point:
- 150°C(dec.)(lit.)
- form
- Powder
- color
- yellow
Safety
- HS Code
- 2931.90.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H317May cause an allergic skin reaction
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H350May cause cancer
H372Causes damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P272Contaminated work clothing should not be allowed out of the workplace.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P285In case of inadequate ventilation wear respiratory protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P314Get medical advice/attention if you feel unwell.
P321Specific treatment (see … on this label).
P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.
P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P363Wash contaminated clothing before reuse.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 901116
- Product name
- trans-Bis(dicyclohexylphenylphosphine)(2-methylphenyl)nickel(II) chloride
- Packaging
- 100mg
- Price
- $80
- Updated
- 2023/01/07
- Product number
- C3325
- Product name
- Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II)
- Packaging
- 100mg
- Price
- $70
- Updated
- 2024/03/01
- Product number
- C3325
- Product name
- Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II)
- Packaging
- 500mg
- Price
- $237
- Updated
- 2024/03/01
- Product number
- 28-0150
- Product name
- Chlorobis(dicyclohexylphenylphosphino)(2-methylphenyl)nickel(II), 99%
- Packaging
- 100mg
- Price
- $68
- Updated
- 2024/03/01
- Product number
- 28-0150
- Product name
- Chlorobis(dicyclohexylphenylphosphino)(2-methylphenyl)nickel(II), 99%
- Packaging
- 500mg
- Price
- $274
- Updated
- 2024/03/01
Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Chemical Properties,Usage,Production
Reaction
An air-stable nickel precatalyst for the Internally-selective benzylation of terminal alkenes.
Uses
Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II) (CAS# 1419179-26-2) is a pre-catalyst for Heck-type benzylation of terminal alkenes. The catalytically active Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(0) complex is unstable in air.
Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Preparation Products And Raw materials
Raw materials
Preparation Products
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