Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)

Reaction

Product Name: Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)
CAS No.: 1419179-26-2
Chemical Name: Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)
Synonyms: Jamison Catalyst;Trans-Bis(dicycL;chlorobis(dicyclohexylphenyl)(2-methylphenyl)nickel;Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II);(II)Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II);Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II), 99%;trans-Bis(dicyclohexylphenylphosphine)(2-methylphenyl)nickel(II) chloride;(2,1,3-Benzothiadiazole)- κ N1) carbonyl chloride [(1E) -2- (1-styryl) vinyl] bis (triphenylphosphine) ruthenium (II)
CBNumber: CB82710037
Molecular Formula: C43H59ClNiP2-2
Formula Weight: 732.022482
MOL File: 1419179-26-2.mol

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Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Property

Melting point:: 150°C(dec.)(lit.)
form: Powder
color: yellow

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Safety

HS Code: 2931.90.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H350May cause cancer

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P272Contaminated work clothing should not be allowed out of the workplace.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P285In case of inadequate ventilation wear respiratory protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P341IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.

P314Get medical advice/attention if you feel unwell.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

P363Wash contaminated clothing before reuse.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 901116
Product name: trans-Bis(dicyclohexylphenylphosphine)(2-methylphenyl)nickel(II) chloride
Packaging: 100mg
Price: $80
Updated: 2023/01/07

TCI Chemical

Product number: C3325
Product name: Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II)
Packaging: 100mg
Price: $70
Updated: 2024/03/01

TCI Chemical

Product number: C3325
Product name: Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II)
Packaging: 500mg
Price: $237
Updated: 2024/03/01

Strem Chemicals

Product number: 28-0150
Product name: Chlorobis(dicyclohexylphenylphosphino)(2-methylphenyl)nickel(II), 99%
Packaging: 100mg
Price: $68
Updated: 2024/03/01

Strem Chemicals

Product number: 28-0150
Product name: Chlorobis(dicyclohexylphenylphosphino)(2-methylphenyl)nickel(II), 99%
Packaging: 500mg
Price: $274
Updated: 2024/03/01

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Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Chemical Properties,Usage,Production

Reaction

An air-stable nickel precatalyst for the Internally-selective benzylation of terminal alkenes.

Uses

Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(II) (CAS# 1419179-26-2) is a pre-catalyst for Heck-type benzylation of terminal alkenes. The catalytically active Chlorobis[dicyclohexyl(phenyl)phosphino](o-tolyl)nickel(0) complex is unstable in air.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II) Suppliers

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1419179-26-2, Chlorobis(dicyclohexylphenylphosphino)(2-Methylphenyl)nickel(II)Related Search:

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