ChemicalBook > CAS DataBase List > 9-Azabicyclo[3.3.1]nonane N-oxyl

9-Azabicyclo[3.3.1]nonane N-oxyl

Product Name
9-Azabicyclo[3.3.1]nonane N-oxyl
CAS No.
31785-68-9
Chemical Name
9-Azabicyclo[3.3.1]nonane N-oxyl
Synonyms
ABNO;NPPN;9-azabicyclo[3.3.1]nonan-9-ol;9-Azabicyclo[3.3.1]non-9-yloxy;9-AZABICYCLO[3.3.1]NONANE N-OX;9-Azabicyclo[3.3.1]nonane N-oxyl;9-hydroxy-9-azabicyclo[3.3.1]nonane;9-Azabicyclo[3.3.1]nonane N-oxyl 95%;9-azabiscyclo[3.3.1]nonylalkane-N-oxy;9-Azabicyclo[3.3.1]nonane N-oxyl
CBNumber
CB82730770
Molecular Formula
C8H14NO*
Formula Weight
140.20286
MOL File
31785-68-9.mol
More
Less

9-Azabicyclo[3.3.1]nonane N-oxyl Property

Melting point:
65-70°C
storage temp. 
2-8°C
form 
solid
Appearance
Brown to reddish brown Solid
BRN 
1681761
InChI
InChI=1S/C8H14NO/c10-9-7-3-1-4-8(9)6-2-5-7/h7-8H,1-6H2
InChIKey
SZAKAAGHPLUEPM-UHFFFAOYSA-N
SMILES
C12N([O])C(CCC1)CCC2 |^1:2|
More
Less

Safety

Hazard Codes 
Xn
Risk Statements 
22-41-52/53
Safety Statements 
26-39-61
WGK Germany 
3
Storage Class
11 - Combustible Solids
Hazard Classifications
Acute Tox. 4 Oral
Eye Dam. 1
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
763284
Product name
9-Azabicyclo[3.3.1]nonane N-oxyl
Purity
95%
Packaging
50mg
Price
$123
Updated
2026/03/19
Sigma-Aldrich
Product number
763284
Product name
9-Azabicyclo[3.3.1]nonane N-oxyl
Purity
95%
Packaging
1g
Price
$456
Updated
2026/03/19
Sigma-Aldrich
Product number
763284
Product name
9-Azabicyclo[3.3.1]nonane N-oxyl
Purity
95%
Packaging
250mg
Price
$264
Updated
2026/03/19
TRC
Product number
A965460
Product name
9-Azabicyclo[3.3.1]nonane N-oxyl
Packaging
100mg
Price
$125
Updated
2021/12/16
Biosynth Carbosynth
Product number
FA59534
Product name
9-Azabicyclo[3.3.1]nonane N-oxyl
Packaging
250mg
Price
$115
Updated
2021/12/16
More
Less

9-Azabicyclo[3.3.1]nonane N-oxyl Chemical Properties,Usage,Production

Uses

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) may be employed for the aerobic oxidation of alcohols.

General Description

9-Azabicyclo[3.3.1]nonane N-oxyl (ABNO) belongs to a sterically unhindered and stable class of nitroxyl radicals. It efficiently catalyzes the oxidation of alcohols to afford the corresponding carbonyl compounds. ABNO along with (MeObpy)CuI(OTf) (MeObpy =4,4′-dimethoxy-2,2′-bipyridine) comprises a catalytic system. This catalytic system is useful for the aerobic oxidation of all categories of alcohols.

reaction suitability

reagent type: ligand

Synthesis

1. 9-Benzyl-9-azabicyclononan-3-one is reduced to 9-benzyl-9-azabicyclononane in a continuous reactor at 215C with KOH/hydrazine hydrate/ethanol.
2. The product from step 1 is hydrogenated in methanol with Pd/C to remove the benzyl group, yielding 9-azabicyclononane.
3. The product from step 2 is oxidized with urea peroxide catalyzed by sodium tungstate to give the N-oxyl radical.

9-Azabicyclo[3.3.1]nonane N-oxyl Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

9-Azabicyclo[3.3.1]nonane N-oxyl Suppliers

China 76 Germany 1 India 1 United Kingdom 1 United States 3 Global 82
Suzhou Lakestar Pharmatech Co., Ltd.
Tel
0512-63970158-603 18018108880
Fax
0512-63971078
Email
info@lakestarpharma.com
Country
China
ProdList
403
Advantage
59
HuBei VernalBay Biopharmaceutical Co., Ltd.
Tel
17371337933 17371337933
Email
3495784513@qq.com
Country
China
ProdList
20
Advantage
58
Beijing Ouhe Technology Co., Ltd
Tel
13552068683 13522913783
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
11778
Advantage
60
Sphinx Scientific Laboratory (Tianjin) Co., Ltd.
Tel
022-66211289-843 13672102692
Fax
QQ：2377893365
Email
contact@sphinxpharm.com
Country
China
ProdList
361
Advantage
62
T&W GROUP
Tel
021-61551611 13296011611
Fax
＋86 21-50676805
Email
contact@trustwe.com
Country
China
ProdList
9895
Advantage
58
Nanjing Norris-Pharm Technology Co., Ltd
Tel
18652989687
Fax
+86-25-52131256
Email
sales@norris-pharm.com
Country
China
ProdList
8878
Advantage
55
Suzhou Sino Rare Chemical Co., Ltd.
Tel
0512-62857507
Fax
+86-512-62857507
Email
sales@sinorarechem.com
Country
China
ProdList
997
Advantage
58
Bide Pharmatech Ltd.
Tel
400-400-164-7117 18317119277
Fax
+86-21-61629029
Email
product02@bidepharm.com
Country
China
ProdList
40000
Advantage
60
Quality Control Solutions Ltd.
Tel
0755-66853366 13670046396
Fax
0755-28363542
Email
orders@qcsrm.com
Country
China
ProdList
18422
Advantage
56
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51395
Advantage
80

31785-68-9, 9-Azabicyclo[3.3.1]nonane N-oxylRelated Search:


  • NPPN
  • 9-Azabicyclo[3.3.1]nonane N-oxyl
  • ABNO
  • 9-Azabicyclo[3.3.1]nonane N-oxyl 95%
  • exe-3-methylamino-9-boc -9-azabicyclo[3.3.1]nonane
  • 9-AZABICYCLO[3.3.1]NONANE N-OX
  • 9-Azabicyclo[3.3.1]non-9-yloxy
  • 9-azabicyclo[3.3.1]nonan-9-ol
  • 9-hydroxy-9-azabicyclo[3.3.1]nonane
  • 9-Azabicyclo[3.3.1]nonane <i>N</i>-oxyl
  • 9-azabiscyclo[3.3.1]nonylalkane-N-oxy
  • 31785-68-9