5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine

Reaction

Product Name: 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
CAS No.: 942939-38-0
Chemical Name: 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
Synonyms: f]azepine;Reaxys ID: 21143615;5-(11bS)-Dinaphtho[2;5-(11bS)-Dinaphtho[2,1-d;2]dioxaphosphepin-4-yl-5H-dibenz[b;3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine;(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a'']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%
CBNumber: CB82750837
Molecular Formula: C34H22NO2P
Formula Weight: 507.53
MOL File: 942939-38-0.mol

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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Property

Melting point:: 246 °C
Boiling point:: 711.5±63.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: -2.70±0.20(Predicted)
form: solid
color: yellow
Sensitive: air sensitive, moisture sensitive

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 744646
Product name: (S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
Purity: ≥95% (elemental analysis)
Packaging: 100mg
Price: $110
Updated: 2024/03/01

Sigma-Aldrich

Product number: 744646
Product name: (S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
Purity: ≥95% (elemental analysis)
Packaging: 500mg
Price: $350
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1227
Product name: (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
Packaging: 100mg
Price: $90
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1227
Product name: (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
Packaging: 500mg
Price: $354
Updated: 2024/03/01

Ambeed

Product number: A857931
Product name: (S)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
Purity: 98%99%ee
Packaging: 5g
Price: $990
Updated: 2021/12/16

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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Chemical Properties,Usage,Production

Reaction

The ligand is used in the stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis.
The ligand used in the direct, enantioselective iridium-catalyzed amination and (thio-) etherification of racemic allylic alcohols.
The ligand used in an asymmetric, rhodium-catalyzed, intramolecular hydroacylation reaction.

Uses

Phosphorous precursor for ligand synthesis

5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Preparation Products And Raw materials

Raw materials

Preparation Products

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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Suppliers

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942939-38-0, 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepineRelated Search:

Reaxys ID: 21143615

(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a

3,4-a']dinaphthalen-4-yl)-dibenzo[b,f]azepine >=95% (elemental analysis)

3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine

3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%

(S)-(+)-(3,5-DIOXA-4-PHOSPHACYCLOHEPTA[2,1-A;3,4-A']DINAPHTHALEN-4-YL)-5H-DIBENZ[B,F]AZEPINE,MIN.97%

3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%

(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%

3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine

1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine

5-(11bS)-Dinaphtho[2,1-d

(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine

5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine

5-(11bS)-5H-Dibenz[b,f]azepine-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl

5H-Dibenz[b,f]azepine, 5-(11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-

2]dioxaphosphepin-4-yl-5H-dibenz[b

5-(11bS)-Dinaphtho[2

f]azepine

5-((11bS)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-5H-dibenzo[b,f]azepine

3,4-a'']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine

5-(11bS)-Dinaphtho[2,1-d:1’,2’-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine

5-(11bS)-5H-Dibenz[b,f]azepine-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl

942939-38-0

C34H22NO2P

Chiral Phosphine

CPN