ChemicalBook > CAS DataBase List > 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
Reaction- Product Name
- 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
- CAS No.
- 942939-38-0
- Chemical Name
- 5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine
- Synonyms
- f]azepine;Reaxys ID: 21143615;5-(11bS)-Dinaphtho[2;5-(11bS)-Dinaphtho[2,1-d;2]dioxaphosphepin-4-yl-5H-dibenz[b;3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine;(S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a'']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine,min.97%
- CBNumber
- CB82750837
- Molecular Formula
- C34H22NO2P
- Formula Weight
- 507.53
- MOL File
- 942939-38-0.mol
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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Property
- Melting point:
- 246 °C
- Boiling point:
- 711.5±63.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- -2.70±0.20(Predicted)
- form
- solid
- color
- yellow
- Sensitive
- air sensitive, moisture sensitive
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Safety
- WGK Germany
- 3
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 744646
- Product name
- (S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
- Purity
- ≥95% (elemental analysis)
- Packaging
- 100mg
- Price
- $110
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 744646
- Product name
- (S)-(+)-N-(3,5-Dioxa-4-phosphacyclohepta[2,1-a,3,4-a′]dinaphthalen-4-yl)-dibenzo[b,f]azepine
- Purity
- ≥95% (elemental analysis)
- Packaging
- 500mg
- Price
- $350
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1227
- Product name
- (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
- Packaging
- 100mg
- Price
- $90
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1227
- Product name
- (S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine, min. 97%
- Packaging
- 500mg
- Price
- $354
- Updated
- 2024/03/01
Ambeed
- Product number
- A857931
- Product name
- (S)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-5H-dibenz[b,f]azepine
- Purity
- 98%99%ee
- Packaging
- 5g
- Price
- $990
- Updated
- 2021/12/16
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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Chemical Properties,Usage,Production
Reaction
- The ligand is used in the stereodivergent α-allylation of linear aldehydes with dual iridium and amine catalysis.
- The ligand used in the direct, enantioselective iridium-catalyzed amination and (thio-) etherification of racemic allylic alcohols.
- The ligand used in an asymmetric, rhodium-catalyzed, intramolecular hydroacylation reaction.
Uses
Phosphorous precursor for ligand synthesis
5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Preparation Products And Raw materials
Raw materials
Preparation Products
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5-(11bS)-Dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl-5H-dibenz[b,f]azepine Suppliers
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