1,3-BENZOXAZOL-6-AMINE

Product Name: 1,3-BENZOXAZOL-6-AMINE
CAS No.: 177492-52-3
Chemical Name: 1,3-BENZOXAZOL-6-AMINE
Synonyms: benzo[d]oxazol-6-amine;6-BenzoxazolaMine;6-AMINO-BENZOXAZOLE;Benzooxazol-6-ylamine;6-Aminobenzoxazole,95%;1,3-BENZOXAZOL-6-AMINE;6-Amino-1,3-benzoxazole
CBNumber: CB8280376
Molecular Formula: C7H6N2O
Formula Weight: 134.14
MOL File: 177492-52-3.mol

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1,3-BENZOXAZOL-6-AMINE Property

Melting point:: 88 °C
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: Solid
color: Orange to brown
Water Solubility: Slightly soluble in water.
Sensitive: Air Sensitive

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22-36/37/38-36-22
Safety Statements: 22-26-36/37/39
RIDADR: 2811
HazardClass: IRRITANT
HS Code: 2934999090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CDS013806
Product name: 1,3-benzoxazol-6-amine
Purity: Aldrich<SUP>CPR</SUP>
Packaging: 250 mg
Price: $107
Updated: 2025/07/31

TRC

Product number: B130008
Product name: 6-Benzoxazolamine
Packaging: 500mg
Price: $110
Updated: 2021/12/16

Matrix Scientific

Product number: 043883
Product name: 1,3-Benzoxazol-6-amine
Purity: 97%
Packaging: 5g
Price: $119
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB139721
Product name: Benzo[d]oxazol-6-amine
Packaging: 500mg
Price: $130
Updated: 2021/12/16

SynQuest Laboratories

Product number: 4H30-1-5N
Product name: 6-Amino-1,3-benzoxazole
Packaging: 1g
Price: $168
Updated: 2021/12/16

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1,3-BENZOXAZOL-6-AMINE Chemical Properties,Usage,Production

Uses

6-Aminobenzoxazole is used as pharmaceutical intermediate.

Definition

ChEBI: 6-Amino-benzoxazole is a benzoxazole.

Synthesis

17200-30-5

177492-52-3

GENERAL METHOD: 6-nitro-1,3-benzoxazole (6.13 mmol) was dissolved in ethanol (30 mL) and 10% Pd/C catalyst was added (the amount of catalyst was 20% of the mass of 6-nitro-1,3-benzoxazole). The mixture was placed in a Parr hydrogenation unit and the hydrogenation reaction was carried out at 50 psi H?(g) pressure overnight. Upon completion of the reaction, the catalyst was removed by filtration and the filtrate was concentrated under vacuum to remove the solvent. The crude product was purified by fast column chromatography using a 30%-40% ethyl acetate/hexane gradient elution to give pure 6-aminobenzoxazole.

References

[1] ACS Catalysis, 2015, vol. 5, # 3, p. 1526 - 1529
[2] Molecules, 2014, vol. 19, # 1, p. 925 - 939
[3] Collection of Czechoslovak Chemical Communications, 1996, vol. 61, # 2, p. 268 - 275
[4] Collection of Czechoslovak Chemical Communications, 1996, vol. 61, # 3, p. 371 - 380
[5] Chemical Communications, 2011, vol. 47, # 39, p. 10972 - 10974

1,3-BENZOXAZOL-6-AMINE Preparation Products And Raw materials

Raw materials

Preparation Products

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1,3-BENZOXAZOL-6-AMINE Suppliers

Belgium 1 China 84 Germany 2 India 3 United Kingdom 3 United States 13 Global 106

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
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Alfa Aesar

Tel: 400-6106006
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Wuhan Chemwish Technology Co., Ltd

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Capot Chemical Co., Ltd

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Shanghai Hanhong Scientific Co.,Ltd.

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Shanghai Ennopharm Co., Ltd.

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Chiba Pharmaceutical Science and technology Co, Ltd.

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Thermo Fisher Scientific

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Shanghai Topbiochem Technology Co., Ltd

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View Lastest Price from 1,3-BENZOXAZOL-6-AMINE manufacturers

Career Henan Chemical Co

Product: 1,3-BENZOXAZOL-6-AMINE 177492-52-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2019-12-30

177492-52-3, 1,3-BENZOXAZOL-6-AMINERelated Search:

2-(4-AMINOPHENYL)-6-AMINOBENZOXAZOLE 2-Methyl-6-nitrobenzoxazole 6-NITRO BENZOXAZOLINONE 5-CHLORO-6-BENZOXAZOLAMINE 2-(2-NAPHTHYL)-1,3-BENZOXAZOL-5-AMINE 2-Methyl-5-chloro-6-benzoxazolamine 1,3-BENZOXAZOL-2-AMINE 6-Amino-2-methylbenzoxazole Benzoxazole Oxazole N-METHYL-N'-(2-METHYL-1,3-BENZOXAZOL-6-YL)THIOUREA 6-Amino-2-(3-aminophenyl)benzoxazole OTAVA-BB 1315014 2-(4-METHOXY-PHENYL)-BENZOOXAZOLE-6-YLAMINE OTAVA-BB 1315037 6-NITRO-1,3-BENZOXAZOLE 2-Phenyl-benzooxazol-6-ylamine 5-CHLORO-2-METHYL-6-NITRO-1,3-BENZOXAZOLE

6-AMINO-BENZOXAZOLE

Benzooxazol-6-ylamine

benzo[d]oxazol-6-amine

6-Amino-1,3-benzoxazole

6-BenzoxazolaMine

1,3-BENZOXAZOL-6-AMINE

6-Aminobenzoxazole,95%

177492-52-3