AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER
- Product Name
- AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER
- CAS No.
- 477585-43-6
- Chemical Name
- AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER
- Synonyms
- (2S, 2R)-GLY-4-PYRANOYL-OME;methyl aminotetrahydropyr...;methyl 2-amino-2-(oxan-4-yl)acetate;Methyl aMinotetrahydropyran-4-ylacetate;METHYL AMINO-(4-TETRAHYDROPYRANYL) ACETATE;METHYL AMINO(TETRAHYDRO-2H-PYRAN-4-YL)ACETATE;methyl 2-amino-2-tetrahydropyran-4-yl-acetate;AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER;2H-Pyran-4-acetic acid, a-aMinotetrahydro-, Methyl ester;2H-Pyran-4-acetic acid, α-aminotetrahydro-, methyl ester
- CBNumber
- CB8303842
- Molecular Formula
- C8H15NO3
- Formula Weight
- 173.21
- MOL File
- 477585-43-6.mol
AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER Property
- storage temp.
- 2-8°C(protect from light)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H350May cause cancer
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P201Obtain special instructions before use.
P202Do not handle until all safety precautions have been read and understood.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313IF exposed or concerned: Get medical advice/attention.
P391Collect spillage. Hazardous to the aquatic environment
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M224423
- Product name
- MethylAminotetrahydropyran-4-ylacetate
- Packaging
- 50mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- M224423
- Product name
- MethylAminotetrahydropyran-4-ylacetate
- Packaging
- 100mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- FA51096
- Product name
- Amino-(tetrahydropyran-4-yl)acetic acid methyl ester hydrochloride
- Packaging
- 50mg
- Price
- $67.5
- Updated
- 2021/12/16
- Product number
- FA51096
- Product name
- Amino-(tetrahydropyran-4-yl)acetic acid methyl ester hydrochloride
- Packaging
- 100mg
- Price
- $108
- Updated
- 2021/12/16
- Product number
- FA51096
- Product name
- Amino-(tetrahydropyran-4-yl)acetic acid methyl ester hydrochloride
- Packaging
- 250mg
- Price
- $135
- Updated
- 2021/12/16
AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER Chemical Properties,Usage,Production
Synthesis
477584-90-0
477585-43-6
The general procedure for the synthesis of methyl 2-amino-2-(tetrahydro-2H-pyran-4-yl)acetate from methyl 2-(benzyloxycarbonylamino)-2-(tetrahydro-2H-pyran-4-yl)acetate was as follows: a mixture of methyl N-Cbz-dehydropyranosylglycinate (5.2 g, 17 mmol), 5% Pd/C catalyst (500 mg), methanol (75 mL) and tetrahydrofuran ( A mixture of methanol (75 mL) and tetrahydrofuran (25 mL) was placed under hydrogen atmosphere for 24 hours. Upon completion of the reaction, the mixture was filtered through diatomaceous earth and the diatomaceous earth was washed with methanol. The filtrate was concentrated under reduced pressure to give methyl 2-amino-2-(tetrahydro-2H-pyran-4-yl)acetate in quantitative yield as a colorless oil, which can be used directly in the next step of the reaction.
References
[1] Patent: WO2006/69063, 2006, A1. Location in patent: Page/Page column 80
[2] Patent: WO2010/21934, 2010, A2. Location in patent: Page/Page column 40-41
[3] Patent: WO2007/106192, 2007, A2. Location in patent: Page/Page column 50
[4] Patent: WO2008/134679, 2008, A1. Location in patent: Page/Page column 74
[5] Patent: WO2013/131408, 2013, A1. Location in patent: Page/Page column 110; 111
AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER Preparation Products And Raw materials
Raw materials
Preparation Products
AMINO-(TETRAHYDRO-PYRAN-4-YL)-ACETIC ACID METHYL ESTER Suppliers
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