Identification Description Regulatory Status Usage Natural occurrence
ChemicalBook > CAS DataBase List > ALLYL CINNAMATE

ALLYL CINNAMATE

Identification Description Regulatory Status Usage Natural occurrence
Product Name
ALLYL CINNAMATE
CAS No.
1866-31-5
Chemical Name
ALLYL CINNAMATE
Synonyms
Nsc20972;FEMA 2022;Wln: 1U2ov1U1r;ALLYL CINNAMATE;propenylcinnamate;Propenyl cinnamate;allyl (E)-cinnamate;Allyl CinnaMate allyl3-phenylacrylate;ALLYL CINNAMATE, 99+%
CBNumber
CB8304551
Molecular Formula
C12H12O2
Formula Weight
188.22
MOL File
1866-31-5.mol
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ALLYL CINNAMATE Property

Boiling point:
150-152 °C15 mm Hg(lit.)
Density 
1.053 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.566(lit.)
FEMA 
2022 | ALLYL CINNAMATE
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Insoluble in water, soluble in alcohol and oils, almost insoluble in Propylene glycol.
color 
A colourless or pale straw-coloured liquid.
Odor
at 100.00 %. fruity balsamic pineapple spicy cinnamyl plum apricot peach
Odor Type
fruity
JECFA Number
19
LogP
2.93
CAS DataBase Reference
1866-31-5(CAS DataBase Reference)
EPA Substance Registry System
2-Propenoic acid, 3-phenyl-, 2-propenyl ester (1866-31-5)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
Safety Statements 
26-36
WGK Germany 
3
RTECS 
GD8050000
HS Code 
29163100
Toxicity
The acute oral LD50 value in rats was reported as 1.52 g/kg and the acute dermal LD50 value in rabbits as less than 5 g/kg(Levenstein, 1975).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
1133999
Product name
Allyl cinnamate
Purity
United States Pharmacopeia (USP) Reference Standard
Packaging
5x0.5ml
Price
$397
Updated
2022/05/15
TCI Chemical
Product number
C0878
Product name
Allyl Cinnamate (stabilized with TBC)
Purity
>98.0%(GC)
Packaging
25g
Price
$60
Updated
2021/12/16
Sigma-Aldrich
Product number
W202207
Product name
Allyl cinnamate
Purity
≥99%
Packaging
sample
Price
$54.6
Updated
2024/03/01
Sigma-Aldrich
Product number
W202207
Product name
Allyl cinnamate
Purity
≥99%
Packaging
100g
Price
$84
Updated
2024/03/01
Sigma-Aldrich
Product number
W202207
Product name
Allyl cinnamate
Purity
≥99%
Packaging
1kg
Price
$405
Updated
2024/03/01
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ALLYL CINNAMATE Chemical Properties,Usage,Production

Identification

CAS.No.: 
1866-31-5 
FL.No.: 
9.741
FEMA.No.: 
2022
NAS.No.: 
2022
CoE.No.: 
334
EINECS.No.: 
217-477-8 
JECFA.No.: 
19
 
 

Description

A colorless liquid with peachor apricot-like aroma. It is used as a flavoring agent or adjuvant.

Regulatory Status

CoE: n/a
FDA: 21 CFR 172.515
FDA (other): n/a
JECFA: ADI: Acceptable. No safety concern at current levels of intake when used as a flavoring agent (1996).

Usage

Reported uses (ppm): (FEMA, 1994)

Food Category 
Usual 
Max. 
Alcoholic beverages 
0.5
2
Baked goods 
7.68
10.08
Frozen dairy 
2.65
4.65
Gelatins, puddings 
2.28
3.83
Nonalcoholic beverages 
0.92
1.81
Soft candy 
4.38
7.27

Natural occurrence

Not reported found in nature.

Chemical Properties

A colorless liquid with peach- or apricot-like aroma. It is used as a flavoring agent or adjuvant.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Allyl Cinnamate is a synthetic flavoring agent that is a fairly stable, hazy, colorless to light yellow colored liquid of cherry odor. it is used for its cherry note in flavors and has application in baked goods and candies at 1–2 ppm.

Preparation

By esterification of cinnamic acid with allyl alcohol in the presence of concentrated H2SO4.

Production Methods

Allyl cinnamate is produced by the direct esterification of allyl alcohol with cinnamic acid.

Definition

ChEBI: Allyl cinnamate is a cinnamate ester.

Synthesis Reference(s)

Tetrahedron, 48, p. 1219, 1992 DOI: 10.1016/S0040-4020(01)90785-9
Tetrahedron Letters, 36, p. 113, 1995 DOI: 10.1016/0040-4039(94)02179-F

Safety Profile

Moderately toxic by ingestion. Human skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALLYL COMPOUNDS and ESTERS

Metabolism

Many esters, including benzyl cinnamate, are rapidly hydrolysed in vivo. Cinnamic acid is known to conjugate with glycine in the animal body, or it may be converted to benzoic acid(Williams, 1959). In the rabbit, cinnamic acid is almost entirely excreted as hippuric acid, without formation of cinnamoyl glycine(El Masry, Smith & Williams, 1956) . In the dog, Quick(1928) observed a large excretion of glucuronide, probably benzoylglucuronide. Dakin (1909) named B-phenyl-B-oxopropionic acid, cinnamoyl glycine and acetophenone as minor metabolites in the dog.

Solubility in organics

Allyl Cinnamate is soluble in alcohol and oils, almost insoluble in Propylene glycol.

ALLYL CINNAMATE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ALLYL CINNAMATE manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Allyl Cinnamate 1866-31-5
Price
US $99.00-45.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-12-19
Hebei Chuanghai Biotechnology Co,.LTD
Product
Allyl cinnamate 1866-31-5
Price
US $5.70/kg
Min. Order
10kg
Purity
99%
Supply Ability
10000kg
Release date
2024-08-22
JINING XINHE CHEMICAL CO., LTD
Product
ALLYL CINNAMATE 1866-31-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10ton
Release date
2024-07-18

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