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1-pinacolato-2-(1,8)diamo-naphthalenylborane

Product Name
1-pinacolato-2-(1,8)diamo-naphthalenylborane
CAS No.
1214264-88-6
Chemical Name
1-pinacolato-2-(1,8)diamo-naphthalenylborane
Synonyms
(Pin)B-B(Dan);2-(4,4,5,5-Tetra;1-Phenaol-2- (1,8) Diaminonaphthylborane;1-pinacolato-2-(1,8)diamo-naphthalenylborane;1-ol-2-(1,8)naphthalenediaminebiboronic acidester;2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-...;1H-Naphtho[1,8-de][1,3,2]diazaborinine-2(3H)-boronic Acid Pinacol Ester;2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-naphtho[1,8-de][1,3,2]diazaborinane;3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,4-diaza-3-boratricyclo-[7.3.1.0^{5,13}]trideca-1(13);1H-Naphtho[1,8-de]-1,3,2-diazaborine, 2,3-dihydro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
CBNumber
CB83122626
Molecular Formula
C16H20B2N2O2
Formula Weight
293.96
MOL File
1214264-88-6.mol
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1-pinacolato-2-(1,8)diamo-naphthalenylborane Property

Melting point:
186.7-187.4 °C
Boiling point:
384.1±25.0 °C(Predicted)
Density 
1.14±0.1 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
pka
-0.85±0.20(Predicted)
color 
Off-white
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P302+P350IF ON SKIN: Gently wash with plenty of soap and water.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
T3556
Product name
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
Purity
min. 98.0 %
Packaging
1G
Price
$30
Updated
2026/04/30
TCI Chemical
Product number
T3556
Product name
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
Purity
min. 98.0 %
Packaging
5G
Price
$90
Updated
2026/04/30
TRC
Product number
T889643
Product name
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
Packaging
500mg
Price
$130
Updated
2021/12/16
SynQuest Laboratories
Product number
8H60-1-AR
Product name
2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
Packaging
1g
Price
$148
Updated
2021/12/16
Matrix Scientific
Product number
102827
Product name
3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,4-diaza-3-boratricyclo-[7.3.1.0{5,13}]trideca-1(13),5,7,9,11- pentaene
Purity
>95%
Packaging
1g
Price
$166
Updated
2021/12/16
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1-pinacolato-2-(1,8)diamo-naphthalenylborane Chemical Properties,Usage,Production

Synthesis

479-27-6

73183-34-3

1214264-88-6

General Steps: EXAMPLE: A 50 mL reaction flask was placed on a magnetic stirrer and pinacol ester of bisboronic acid (1.0 mmol, 1.0 eq.), 1,8-diaminonaphthalene (1.0 mmol, 1.0 eq.), and sodium methanol (1.0 mmol, 1.0 eq.) were added sequentially. After purging the reaction system with nitrogen three times under nitrogen protection, 10 mL of methanol was added as solvent. The reaction mixture was heated to 70 °C and stirred continuously for 4 hours. After completion of the reaction, the solvent methanol was removed by rotary evaporator. The crude product was purified by column chromatography to afford the target product 1-pinacol-2-(1,8)naphthalenediamine biboronate in 90% yield.

References

[1] Patent: CN106946916, 2017, A. Location in patent: Paragraph 0012
[2] Chemical Communications, 2014, vol. 50, # 61, p. 8299 - 8302

1-pinacolato-2-(1,8)diamo-naphthalenylborane Preparation Products And Raw materials

Raw materials

Preparation Products

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1-pinacolato-2-(1,8)diamo-naphthalenylborane Suppliers

Energy Chemical
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021-021-58432009 400-005-6266
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021-58436166
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sales8178@energy-chemical.com
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China
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Changzhou Chemscaler Pharmtech Co., Ltd.
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0519-81096292 15312577869
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chemscaler@yahoo.com.cn
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China
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China
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Shanghai ShiXian Chemical Technology Co., Ltd.
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13764359345
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China
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Chengdu Aslee Biopharmaceuticals, Inc
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Suzhou Future Chemical Technology Co., Ltd.
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13921981169
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China
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Amadis Chemical Company Limited
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0086-571-89925065
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sales@amadischem.com
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China
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Amatek Scientific Co. Ltd.
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China
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LinkChem Technology Co., Ltd.
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021-58950110 13124863828
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021-20922272
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sales@linkchem.cn
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Aikon International Limited
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025-66061636 19370895928
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(3)02557626880
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View Lastest Price from 1-pinacolato-2-(1,8)diamo-naphthalenylborane manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Product
1-pinacolato-2-(1,8)diamo-naphthalenylborane 1214264-88-6
Price
US $3.00-9.00/KG
Min. Order
0.1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2025-07-02
Career Henan Chemical Co
Product
1-pinacolato-2-(1,8)diamo-naphthalenylborane 1214264-88-6
Price
US $3.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2020-01-08

1214264-88-6, 1-pinacolato-2-(1,8)diamo-naphthalenylboraneRelated Search:


  • 1-pinacolato-2-(1,8)diamo-naphthalenylborane
  • 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine
  • 3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,4-diaza-3-boratricyclo-[7.3.1.0^{5,13}]trideca-1(13)
  • 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-naphtho[1,8-de][1,3,2]diazaborinane
  • (Pin)B-B(Dan)
  • 2-(4,4,5,5-Tetra
  • 1H-Naphtho[1,8-de][1,3,2]diazaborinine-2(3H)-boronic Acid Pinacol Ester
  • 1H-Naphtho[1,8-de]-1,3,2-diazaborine, 2,3-dihydro-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-
  • 2-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-...
  • 3-(Tetramethyl-1,3,2-dioxaborolan-2-yl)-2,4-diaza-3-boratricyclo-[7.3.1.0 {5,13}]trideca-1(13),5,7,9,11- pentaene
  • 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,4-diaza-3-boratricyclo[7.3.1.0?13]trideca-1(13),5,7,9,11-pentaene
  • 1-Phenaol-2- (1,8) Diaminonaphthylborane
  • 3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,4-diaza-3-boratricyclo[7.3.1.0,5,13]trideca-1(13),5,7,9,11-pentaene
  • 1-ol-2-(1,8)naphthalenediaminebiboronic acidester
  • 1214264-88-6
  • C16H20B2N2O2