ChemicalBook > CAS DataBase List > 1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate

1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate

Product Name
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate
CAS No.
135540-11-3
Chemical Name
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate
Synonyms
PYCLU;PyCIU;N,N,N,N-bis(;N,N,N,N-bis(tetramethylene)*chloroformamidinium;1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium;1-(Chloro-1-pyrrolidinylmethylene)pyrrolidiniumhe;CHLORO-DIPYRROLIDINOCARBENIUM HEXAFLUOROPHOSPHATE;chloro-n,n,n’,n’-bis(tetramethylene)formamidiniumpf6;PYCLU CHLORODIPYRROLIDINOCARBENIUM HEXAFLUOROPHOSPHATE;Chlorodipyrrolidinocarbenium hexafluorophosphate(PyCIU)
CBNumber
CB8376460
Molecular Formula
C9H16ClF6N2P
Formula Weight
332.66
MOL File
135540-11-3.mol
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1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate Property

Melting point:
153-156 °C
storage temp. 
2-8°C
solubility 
almost transparency in Acetonitrile
form 
Powder or Solid
color 
White to off-white
Sensitive 
Moisture & Light Sensitive
BRN 
7898575
InChI
InChI=1S/C9H16ClN2.F6P/c10-9(11-5-1-2-6-11)12-7-3-4-8-12;1-7(2,3,4,5)6/h1-8H2;/q+1;-1
InChIKey
NHEGCUSBUWGOQM-UHFFFAOYSA-N
SMILES
[P+5]([F-])([F-])([F-])([F-])([F-])[F-].C(=[N+]1/CCCC/1)(/N1CCCC1)\Cl
CAS DataBase Reference
135540-11-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37
WGK Germany 
3
8-10-21
Hazard Note 
Irritant
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
23955
Product name
Chlorodipyrrolidinocarbenium hexafluorophosphate
Purity
≥97.5% (CHN)
Packaging
5G
Price
$139
Updated
2025/07/31
TCI Chemical
Product number
C1379
Product name
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium Hexafluorophosphate
Purity
>97.0%(T)
Packaging
5g
Price
$47
Updated
2025/07/31
TCI Chemical
Product number
C1379
Product name
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium Hexafluorophosphate
Purity
>97.0%(T)
Packaging
25g
Price
$186
Updated
2025/07/31
TRC
Product number
P840663
Product name
PYCIU,ChlorodipyrrolidinocarbeniumHexafluorophosphate
Packaging
500mg
Price
$75
Updated
2021/12/16
Oakwood
Product number
009100
Product name
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate
Packaging
1g
Price
$12
Updated
2021/12/16
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1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate Chemical Properties,Usage,Production

Chemical Properties

White solid

Uses

Reactant for:
Enantioselective desymmetrization of meso-asiridines
Peptide coupling
Reagent for:
Heterocyclization of chloroformamidinium salts
Oxidative insertion for palladium and nickel catalyst synthesis

reaction suitability

reaction type: Coupling Reactions

1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate Preparation Products And Raw materials

Raw materials

Preparation Products

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1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate Suppliers

CMS Chemicals Limited
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View Lastest Price from 1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate 135540-11-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2022-09-26
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate 135540-11-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphate 135540-11-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08

135540-11-3, 1-(Chloro-1-pyrrolidinylmethylene)pyrrolidinium hexafluorophosphateRelated Search:


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  • C9H16N2ClPF6
  • C9H16ClF6N2P
  • C9H16ClN2F6P
  • Condensation & Active Esterification
  • Coupling
  • Phosphonium/Uronium/Formamidinium
  • Synthetic Reagents
  • Biochemistry
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  • Coupling Reactions (Peptide Synthesis)
  • Peptide Synthesis
  • Synthetic Organic Chemistry