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METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE

Product Name
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
CAS No.
110556-33-7
Chemical Name
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
Synonyms
Sacubitril Impurity 128;METHYL (R)-(+)-3-BROMOISOBUTYRATE;(+)-methyl (r)-β-bromoisobutyrate;methyl 3-bromo-2-methylpropionate;(+)-METHYL (R)-BETA-BROMOISOBUTYRATE;(R)-Methyl 3-bromo-2-methylpropanoate;Methyl (R)-(+)-3-Bromoisobutyrate >Methyl (R)-3-Bromo-2-methylpropanoate;methyl (2R)-3-bromo-2-methylpropanoate;Methyl (R)-(+)-3-Bromoisobutyrate
CBNumber
CB8409964
Molecular Formula
C5H9BrO2
Formula Weight
181.03
MOL File
110556-33-7.mol
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METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Property

Boiling point:
85 °C37 mm Hg(lit.)
Density 
1.422 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.455
Flash point:
165 °F
storage temp. 
Sealed in dry,Room Temperature
form 
liquid
Appearance
Colorless to light yellow Liquid
optical activity
[α]20/D +16°, neat
BRN 
1720833
InChI
InChI=1S/C5H9BrO2/c1-4(3-6)5(7)8-2/h4H,3H2,1-2H3/t4-/m0/s1
InChIKey
FKWNAVCXZSQYTA-BYPYZUCNSA-N
SMILES
C(OC)(=O)[C@@H](C)CBr
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
2915907098
Storage Class
10 - Combustible liquids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
325090
Product name
Methyl (R)-(+)-3-bromo-2-methylpropionate
Purity
97%
Packaging
1g
Price
$55
Updated
2023/06/20
Sigma-Aldrich
Product number
325090
Product name
Methyl (R)-(+)-3-bromo-2-methylpropionate
Purity
97%
Packaging
5g
Price
$261
Updated
2023/06/20
TRC
Product number
M296688
Product name
(R)-Methyl3-Bromo-2-methylpropanoate
Packaging
50mg
Price
$60
Updated
2021/12/16
AK Scientific
Product number
4140AL
Product name
(R)-(+)-3-Bromoisobutyricacidmethylester
Packaging
1g
Price
$104
Updated
2021/12/16
Apolloscientific
Product number
OR938686
Product name
(R)-(+)-3-Bromoisobutyric acid methyl ester
Packaging
1g
Price
$169
Updated
2021/12/16
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METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Chemical Properties,Usage,Production

Uses

Methyl (R)-(+)-3-bromo-2-methylpropionate can be used as a reactant to prepare:

  • (S)-3-(6-Methoxy-pyridin-3-yl)-2-methylpropionic acid methylester by reacting with 5-bromo-2-methoxy pyridine via nucleophilic displacement reaction.
  • Decahydroisoquinoline derivative (NVP-ACQ090) as a potent antagonist of somatostatin sst3 receptor.

It can also be used as a reference compound in the enantioselective alkylation reaction of hydrophobic vitamin B12 derivatives.

METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE Suppliers

Shanghai PharmaPartner Co., Ltd.
Tel
19983777532
Fax
-
Email
pharmabridge@163.com
Country
China
ProdList
500
Advantage
55
Shanghai Science-Scale Pharmaceutical Technology Co., Ltd.?
Tel
15021108835/19916339073 19116339073
Email
738553248@qq.com
Country
China
ProdList
280
Advantage
58
J & K SCIENTIFIC LTD.
Tel
18210857532; 18210857532
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44801
Advantage
61
Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696
Email
info@hanhongsci.com
Country
China
ProdList
42934
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64
Shanghai Sphchem Co., Ltd.
Tel
021-56491756 13512199871
Email
2819742715@qq.com
Country
China
ProdList
3997
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55
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12335
Advantage
58
9ding chemical ( Shanghai) Limited
Tel
4009209199
Fax
86-021-52271987
Email
sales@9dingchem.com
Country
China
ProdList
22514
Advantage
55
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View Lastest Price from METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE manufacturers

Honest Joy Holdings Limited
Product
(R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester 110556-33-7
Price
US $0.00/KG
Min. Order
1KG
Purity
97.9%
Supply Ability
100 tons
Release date
2022-01-14
Career Henan Chemical Co
Product
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE 110556-33-7
Price
US $20.00/KG
Min. Order
10KG
Purity
98%
Supply Ability
100kg
Release date
2018-08-02

110556-33-7, METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATERelated Search:


  • (R)-(+)-3-Bromoisobutyric Acid Methyl Ester (R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester Methyl (R)-(+)-3-Bromo-2-methylpropionate
  • Methyl (R)-(+)-3-bromo-2-methylpropionate 97%
  • (R)-Methyl 3-bromo-2-methylpropanoate
  • Methyl (<i>R</i>)-(+)-3-Bromoisobutyrate
  • (+)-METHYL (R)-3-BROMO-2-METHYLPROPIONATE
  • METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
  • METHYL (R)-(+)-3-BROMOISOBUTYRATE
  • (+)-METHYL (R)-BETA-BROMOISOBUTYRATE
  • (R)-(+)-3-BROMO-2-METHYLPROPIONIC ACID METHYL ESTER
  • (R)-(+)-3-BROMOISOBUTYRIC ACID METHYL ESTER
  • METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONAT E, 97% (99% EE/GLC)
  • (+)-methyl (r)-β-bromoisobutyrate
  • methyl 3-bromo-2-methylpropionate
  • (R)-2-Methyl-3-bromopropionic acid methyl ester
  • (R)-3-Bromo-2-methylpropanoic acid methyl ester
  • methyl (2R)-3-bromo-2-methylpropanoate
  • Methyl (R)-(+)-3-Bromoisobutyrate &gt
  • Propanoic acid, 3-bromo-2-methyl-, methyl ester, (2R)-
  • (+)-methyl (R)-3-bromo-2-methyl propionate
  • Methyl (R)-3-Bromo-2-methylpropanoate
  • Methyl (<i>R</i>)-(+)-3-bromo-2-methylpropionate
  • Sacubitril Impurity 128
  • 110556-33-7
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Organic Building Blocks
  • Esters
  • Carboxylic Acids (Chiral)
  • Chiral Building Blocks
  • Synthetic Organic Chemistry