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Bis(tert-butyldioxyisopropyl)benzene

Product Name
Bis(tert-butyldioxyisopropyl)benzene
CAS No.
25155-25-3
Chemical Name
Bis(tert-butyldioxyisopropyl)benzene
Synonyms
BIS(TERT-BUTYLPEROXYISOPROPYL)BENZENE;di-(2-tert-butylperoxyisopropyl)benzene;Bis(t-butylperoxy isopropyl)benzene (BIPB);- BIPB;vul-cup;vul-cupr;VAROX VC-R;Luperox? F;Luperox(R);Perkadox 14
CBNumber
CB8422097
Molecular Formula
C20H34O4
Formula Weight
338.48
MOL File
25155-25-3.mol
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Bis(tert-butyldioxyisopropyl)benzene Property

Melting point:
44-48 °C(lit.)
Boiling point:
434.61°C (rough estimate)
Density 
1.63 g/mL at 25 °C(lit.)
vapor pressure 
0Pa at 20℃
refractive index 
1.6000 (estimate)
Flash point:
>230 °F
Water Solubility 
<0.1 g/100 mL at 21 ºC
InChI
InChI=1S/C20H34O4/c1-17(2,3)21-23-19(7,8)15-11-13-16(14-12-15)20(9,10)24-22-18(4,5)6/h11-14H,1-10H3
InChIKey
GWQOYRSARAWVTC-UHFFFAOYSA-N
SMILES
C1(=CC=C(C(C)(C)OOC(C)(C)C)C=C1)C(C)(C)OOC(C)(C)C
LogP
7.3 at 20℃
CAS DataBase Reference
25155-25-3(CAS DataBase Reference)
EPA Substance Registry System
(Phenylenediisopropylidene)bis(tert-butylperoxide) (25155-25-3)
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Safety

Hazard Codes 
O,Xn
Risk Statements 
8-36/37-20-7-53
Safety Statements 
17-36-26-36/37/39-3/7-14
RIDADR 
UN 3106 5.2
WGK Germany 
1
RTECS 
SD8431900
TSCA 
TSCA listed
HazardClass 
5.2
PackingGroup 
II
Toxicity
skn-rbt 100%/24H MLD HERBU* PRC-304
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Biosynth Carbosynth
Product number
FB149645
Product name
1,4-Bis(tert-butylperoxydiisopropyl)benzene
Packaging
500mg
Price
$70
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB149645
Product name
1,4-Bis(tert-butylperoxydiisopropyl)benzene
Packaging
1g
Price
$124
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB149645
Product name
1,4-Bis(tert-butylperoxydiisopropyl)benzene
Packaging
2g
Price
$216
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB149645
Product name
1,4-Bis(tert-butylperoxydiisopropyl)benzene
Packaging
5G
Price
$431
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB149645
Product name
1,4-Bis(tert-butylperoxydiisopropyl)benzene
Packaging
10g
Price
$750
Updated
2021/12/16
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Bis(tert-butyldioxyisopropyl)benzene Chemical Properties,Usage,Production

Description

Bis(tert-butyldioxyisopropyl)benzene (BIPB 40) is a bifunctional peroxide formulation used for crosslinking natural and synthetic rubbers, as well as thermoplastic polyolefins. it is a generalpurpose dilkyl peroxide, 40% ctve ingredient on CaCO3 in granule form for ease of dispersion in an elastomer compound and to control dusting.

Uses

α'',α''-Bis(tert-butylperoxy)diisopropylbenzene (Technical Grade) acts as a crosslinker agent in the synthesis of polymers.

Application

Bis(tert-butyldioxyisopropyl)benzene,also known as BIBP, could used as a hyperoxide crosslinking agent and a chlorinated polyethylene crosslinking agent.

General Description

White crystalline solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Bis(tert-butyldioxyisopropyl)benzene may polymerize and/or decompose if heated.

Fire Hazard

Flash point data for Bis(tert-butyldioxyisopropyl)benzene are not available, however, Bis(tert-butyldioxyisopropyl)benzene is probably combustible.

Safety Profile

A skin irritant. When heated todecomposition it emits acrid smoke and irritating fumes.

Synthesis

A production method of Bis(tert-butyldioxyisopropyl)benzene, comprising the following steps: adding reactant A: 1kg of tert-butylhydrogen peroxide in low concentration to the reaction kettle, and then adding 2g of sodium carbonate and 150g of sodium sulfate respectively to the reactant A for stirring in order to purify it, and then after about 15mins of static standing, delamination, and draining off of the bottom aqueous phase, and the concentration of the purified reactant A is between 68%, then Add reactant B: 0.5kg of diisopropylbenzyl alcohol, and then add 90g of strong oxidizing catalyst C, 500g of sulfuric acid with a concentration of 65% for the reaction, the reaction time is about 1.0h, atmospheric pressure, the temperature is controlled between 50 , after the reaction is over, 500g of deionized water is added, the temperature of the water is between 25 , stirring for about 15min, after static, stratification and draining of the water phase in the lower part of the reactor, the upper oil phase is the crude diisopropylbenzyl alcohol, which is the oil phase of the crude diisopropylbenzoic alcohol. The upper oil phase is the crude di(tert-butylperoxyisopropyl)benzene product, the content of about 80%; the crude product with 20% sodium hydroxide solution, 60 hot water to be washed to get the refined product, the content of more than 92%.

Bis(tert-butyldioxyisopropyl)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(tert-butyldioxyisopropyl)benzene Suppliers

Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006356688 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Shandong Xiya Chemical Co., Ltd
Tel
13355009207 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18729
Advantage
57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
Advantage
57
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17770
Advantage
75
Shanghai T&W Pharmaceutical Co., Ltd.
Tel
+86 21 61551611
Fax
+86 21 50676805
Country
China
ProdList
9891
Advantage
58
Shanghai Hekang Biotechnology Co., Ltd.
Tel
18939837085
Fax
2880152141(QQ)
Email
youchemicals@gmail.com
Country
China
ProdList
1839
Advantage
55
HUBEI RISON CHEMICAL CO.,LTD
Tel
027 83642615 13995607107
Fax
027 83660699
Email
market@risonchem.com
Country
China
ProdList
279
Advantage
58
Wuhan Silworld Chemical Co.,Ltd
Tel
027-85613400 18707177243
Fax
027-85613419
Email
info@silworldchemical.com
Country
China
ProdList
294
Advantage
58
Guangzhou Kafen Biotech Co.,Ltd
Tel
18029243487 2355327168
Fax
020-31121510
Email
gy@yccreate.com
Country
China
ProdList
4749
Advantage
55
Shanghai Orgchem Co.,Ltd.
Tel
+86-21-5877 1921
Fax
+86-21-5877 1925
Email
info@chemofchina.com
Country
China
ProdList
9653
Advantage
55
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View Lastest Price from Bis(tert-butyldioxyisopropyl)benzene manufacturers

Taizhou Suze Chemical Materials Co.,Ltd.
Product
bis(tert-butyldioxyisopropyl)benzene 25155-25-3
Price
US $0.00/kg
Min. Order
1kg
Purity
96%
Supply Ability
24 tons
Release date
2023-03-22
Zhuozhou Wenxi import and Export Co., Ltd
Product
FARIDA BIPB 25155-25-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
FARIDA BIPB 25155-25-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-08

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