LITHIUM DIETHYLAMIDE
- Product Name
- LITHIUM DIETHYLAMIDE
- CAS No.
- 816-43-3
- Chemical Name
- LITHIUM DIETHYLAMIDE
- Synonyms
- Diethyllithioamine;Diethylaminolithium;N-Lithiodiethylamine;LITHIUM DIETHYLAMIDE;(Diethylamino)lithium;LITHIUM DIETHYLAMIDE, 95+%;Lithiumdiethylamideoffwhitepowder;Ethanamine, N-ethyl-, lithium salt
- CBNumber
- CB8437479
- Molecular Formula
- C4H12LiN
- Formula Weight
- 81.09
- MOL File
- 816-43-3.mol
LITHIUM DIETHYLAMIDE Property
- solubility
- sol THF, Et2O, Et2O-hexane mixtures, Et2O-benzene mixtures; insol hydrocarbon solvents
- pka
- pKa = 31.7
- form
- solid
- color
- off-white to light-orange
- Sensitive
- moisture sensitive
Safety
- Hazard Codes
- F,C
- Risk Statements
- 17-34
- Safety Statements
- 16-26-27-36/37/39-45
- RIDADR
- UN 3393 4.2/PG 1
- WGK Germany
- 3
- HazardClass
- 4.2
- PackingGroup
- I
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H250Catches fire spontaneously if exposed to air
H261In contact with water releases flammable gas
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P231+P232Handle under inert gas. Protect from moisture.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378In case of fire: Use … for extinction.
N-Bromosuccinimide Price
- Product number
- 296074
- Product name
- Lithium diethylamide
- Purity
- ≥95%
- Packaging
- 50g
- Price
- $394.8
- Updated
- 2024/03/01
- Product number
- 296074
- Product name
- Lithium diethylamide
- Purity
- ≥95%
- Packaging
- 10g
- Price
- $175
- Updated
- 2023/06/20
- Product number
- 93-0317
- Product name
- Lithium diethylamide, 95+%
- Packaging
- 5g
- Price
- $60
- Updated
- 2024/03/01
- Product number
- 93-0317
- Product name
- Lithium diethylamide, 95+%
- Packaging
- 25g
- Price
- $238
- Updated
- 2024/03/01
- Product number
- ING0008209
- Product name
- LITHIUM DIETHYLAMIDE
- Purity
- 95.00%
- Packaging
- 10G
- Price
- $1158.54
- Updated
- 2021/12/16
LITHIUM DIETHYLAMIDE Chemical Properties,Usage,Production
Uses
Lithium Diethylamide is used as a strong base; nitrogen nucleophile.
Synthesis Reference(s)
1.Normant, H.; Cuvigny, T.; Reisdorf, D. CR(C) 1969, 268, 521.
2. Gaudemar-Bardone, F.; Gaudemar, M. S 1979, 463.
Synthesis
Lithium Diethylamide is synthesized by treating diethylamine with Phenyllithium or n-Butyllithium or, alternatively, by treating diethylamine with Lithium metal in the presence of Hexamethylphosphoric Triamide or an electron acceptor.1,2
LITHIUM DIETHYLAMIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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