2-Furanacrolein Property

Melting point:

49-55 °C(lit.)

Boiling point:

143 °C37 mm Hg(lit.)

Density 

1.1483 (rough estimate)

refractive index 

1.5286 (estimate)

FEMA 

2494 | 3-(2-FURYL)ACROLEIN

Flash point:

211 °F

storage temp. 

2-8°C

form 

powder to crystal

color 

White to Light yellow to Dark green

Odor

at 1.00 % in dipropylene glycol. green grassy fruity spicy vanilla nutty woody cinnamon

Odor Type

spicy

Water Solubility 

insoluble

Sensitive 

Air Sensitive

JECFA Number

1497

BRN 

107570

LogP

1.74

CAS DataBase Reference

623-30-3(CAS DataBase Reference)

NIST Chemistry Reference

2-Propenal, 3-(2-furanyl)-(623-30-3)

EPA Substance Registry System

2-Propenal, 3-(2-furanyl)- (623-30-3)

Safety

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-27-28-36/37/39-45-24/25

RIDADR 

UN 1759 8/PG 2

WGK Germany 

3

RTECS 

LT8528500

TSCA 

Yes

HazardClass 

8

PackingGroup 

III

HS Code 

29321900

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

P405Store locked up.

P501Dispose of contents/container to..…

2-Furanacrolein Chemical Properties,Usage,Production

Chemical Properties

Colorless to light yellow liqui

Chemical Properties

3(2-Furyl)acrolein has a cooked spicy-herb odor and taste.

Occurrence

Reported found in ground and roasted coffee and rum

Definition

ChEBI: 3-(2-Furanyl)-2-propenal is a heteroarene.

Synthesis Reference(s)

The Journal of Organic Chemistry, 58, p. 2517, 1993 DOI: 10.1021/jo00061a027

General Description

Light brown powder. Cinnamon odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Furanacrolein is an aldehyde. May become involved in exothermic self-condensation or polymerization reactions that are often catalyzed by acid. May generate flammable and/or toxic gases with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation.

Fire Hazard

Flash point data are not available for 2-Furanacrolein, but 2-Furanacrolein is probably combustible.