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RARECHEM AL BI 1318

Product Name
RARECHEM AL BI 1318
CAS No.
59937-01-8
Chemical Name
RARECHEM AL BI 1318
Synonyms
RARECHEM AL BI 1318;ethyl 2-phenylthiazole-4-carboxylate;2-PHENYL-THIAZOLE-4-CARBOXYLIC ACID ETHYL ESTER;4-THIAZOLECARBOXYLIC ACID, 2-PHENYL-, ETHYL ESTER
CBNumber
CB8462594
Molecular Formula
C12H11NO2S
Formula Weight
233.29
MOL File
59937-01-8.mol
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RARECHEM AL BI 1318 Property

Melting point:
47 °C
Boiling point:
365℃
Density 
1.216
Flash point:
175℃
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
pka
0.09±0.10(Predicted)
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Ark Pharm
Product number
P000167550
Product name
Ethyl 2-phenylthiazole-4-carboxylate
Purity
97%
Packaging
1g
Price
$70
Updated
2021/12/16
AK Scientific
Product number
Z3167
Product name
Ethyl2-phenylthiazole-4-carboxylate
Packaging
1g
Price
$171
Updated
2021/12/16
Ark Pharm
Product number
P000167550
Product name
Ethyl 2-phenylthiazole-4-carboxylate
Purity
97%
Packaging
5g
Price
$224
Updated
2021/12/16
Matrix Scientific
Product number
113991
Product name
Ethyl 2-phenyl-1,3-thiazole-4-carboxylate
Purity
97%
Packaging
1g
Price
$260
Updated
2021/12/16
Ark Pharm
Product number
P000167550
Product name
Ethyl 2-phenylthiazole-4-carboxylate
Purity
97%
Packaging
10g
Price
$381
Updated
2021/12/16
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RARECHEM AL BI 1318 Chemical Properties,Usage,Production

Synthesis

70454-09-0

59937-01-8

GENERAL METHOD: 4-carboxythiazoline or 4-carboxyoxazoline (0.5 mmol) was dissolved in anhydrous DMF (1 mL), molecular sieves (4 ? , 100% wt) and copper(II) acetate (9.1 mg, 0.05 mmol). The reaction mixture was stirred at 120 °C for 10 to 24 h under an oxygen atmosphere (using an O2 balloon). After completion of the reaction, the reaction mixture was diluted with ethyl acetate, the organic layer was washed sequentially with water and brine, dried with anhydrous sodium sulfate, filtered, and the filtrate was concentrated under reduced pressure. The concentrated residue was purified by silica gel fast column chromatography to obtain the target product 4-carboxythiazole or 4-carboxyoxazole.

References

[1] Tetrahedron, 2011, vol. 67, # 38, p. 7406 - 7411

RARECHEM AL BI 1318 Preparation Products And Raw materials

Raw materials

Preparation Products

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RARECHEM AL BI 1318 Suppliers

Shanghai Ennopharm Co., Ltd.
Tel
+86 (21) 6435-5022
Country
China
ProdList
4267
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Chengdu Forest Science and Technology Development Co., Ltd.
Tel
18030648795
Fax
028-61777050
Email
sales@cdforestchem.com
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China
ProdList
1998
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58
Hangzhou Sage Chemical Co., Ltd.
Tel
+86057186818502 13588463833
Fax
Pls mail us for more information!
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info@sagechem.com
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China
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10266
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Nanjing Norris-Pharm Technology Co., Ltd
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18652989687
Fax
+86-25-52131256
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sales@norris-pharm.com
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China
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8878
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55
Beijing FYF Chemicals Co., Ltd
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010-57903446 15869909019
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010-57903446
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168931144@qq.com
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China
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2875
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Zhengzhou Guancheng Laboratory equipment Sales
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0371-88888888 272369594
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China
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Amadis Chemical Company Limited
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571-89925085
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0086-571-89925065
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China
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Sichuan BaiPeng Biotechnology Co., Ltd.
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028-65791793 18140026355
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China
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58
Capot Chemical Co.,Ltd.
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sales@capot.com
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China
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29735
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Aikon International Limited
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025-58859352 18068836627
Fax
(5)02557626880
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dt3@aikonchem.com
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China
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