1-(Fluorosulfuryl)-2,3-
- Product Name
- 1-(Fluorosulfuryl)-2,3-
- CAS No.
- 2179072-33-2
- Chemical Name
- 1-(Fluorosulfuryl)-2,3-
- Synonyms
- 1-(fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate;1-(Fluorosulfuryl)-2,3-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate;185051;1-(Fluorosulfuryl)-2,3-;2,3-dimethylimidazol-3-ium-1-sulfonyl fluoride;2,3-dimethylimidazol-3-ium-1-sulfonyl fluoride trifluoromethanesulfonate;1-(Fluorosulfonyl)-2-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate;3-(Fluorosulfonyl)-1,2-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate;1-(fluorosulphonyl)-2,3-dimethyl-1H-imidazole-3-trifluoromethylsulfonic acidammonium;7-bromo-5-methyl-1,2,3,4-tetrahydroisoquinoline1-(Fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate
- CBNumber
- CB84662022
- Molecular Formula
- C6H8F4N2O5S2
- Formula Weight
- 328.25
- MOL File
- 2179072-33-2.mol
1-(Fluorosulfuryl)-2,3- Property
- Melting point:
- 64-65 °C
- storage temp.
- 2-8°C
- form
- Solid
Safety
- HS Code
- 2933299090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 903132
- Product name
- 1-(Fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate
- Purity
- ≥95%
- Packaging
- 1G
- Price
- $136
- Updated
- 2023/06/20
- Product number
- 903132
- Product name
- 1-(Fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate
- Purity
- ≥95%
- Packaging
- 5G
- Price
- $446
- Updated
- 2023/06/20
- Product number
- 903132
- Product name
- 1-(Fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-ium trifluoromethanesulfonate
- Purity
- ≥95%
- Packaging
- 25G
- Price
- $1530
- Updated
- 2023/06/20
- Product number
- PC32793
- Product name
- 1-(Fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-iumtrifluoromethanesulfonate
- Packaging
- 5g
- Price
- $240
- Updated
- 2021/12/16
- Product number
- PC32793
- Product name
- 1-(Fluorosulfonyl)-2,3-dimethyl-1H-imidazol-3-iumtrifluoromethanesulfonate
- Packaging
- 1g
- Price
- $60
- Updated
- 2021/12/16
1-(Fluorosulfuryl)-2,3- Chemical Properties,Usage,Production
Uses
This solid fluorosulfuryl imidazolium triflate salt, SuFEx-IT, is a convenient alternative to sulfuryl fluoride (SO2F2), which is a harmful fumigant gas with difficult handling procedures that make SO2F2 -- and the products it is capable of making -- difficult to access. However, this reagent possesses novel reactivity, selectivity, and scope and was demonstrated by the labs of K. Barry Sharpless and Jiajia Dong to convert phenols, primary amines, and secondary amines to fluorosulfates and sulfamoyl fluorides. Fluorosulfates are used widely in biological studies, medicinal chemistry, and work as a pseudohalide in Pd-catalysed cross-coupling reactions.
Store in dry environment (desiccator advised) at 4 °C.
1-(Fluorosulfuryl)-2,3- Preparation Products And Raw materials
Raw materials
Preparation Products
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