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(-)-CAMPHENE

Product Name
(-)-CAMPHENE
CAS No.
5794-04-7
Chemical Name
(-)-CAMPHENE
Synonyms
(1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE;2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane;Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-;[1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane;L-Camphene;(-)-Camphene;(-)-Camphene,95%;(+/-)-Camphene, sum of camphene + fenchene;(1S,4R)-2,2-Dimethyl-3-methylenenorbornane;2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
CBNumber
CB8468970
Molecular Formula
C10H16
Formula Weight
136.23
MOL File
5794-04-7.mol
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(-)-CAMPHENE Property

Melting point:
36-38 °C(lit.)
Boiling point:
157.5-158.5 °C(lit.)
Density 
0.84 g/mL at 25 °C(lit.)
refractive index 
1.4562 (estimate)
Flash point:
98 °F
solubility 
Benzene (Slightly), Chloroform (Sparingly)
form 
Solid
color 
White to Off-White Waxy
Odor
at 10.00 % in dipropylene glycol. fresh woody fir terpene
Odor Type
woody
Merck 
14,1730
Stability:
Volatile
LogP
4.239 (est)
EPA Substance Registry System
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1S,4R)- (5794-04-7)
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Safety

Hazard Codes 
F
Risk Statements 
11-10
Safety Statements 
16-33-29
RIDADR 
UN 1325 4.1/PG 2
WGK Germany 
3
RTECS 
EX1055000
HazardClass 
4.1
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC
Product number
C173135
Product name
(-)-Camphene
Packaging
100mg
Price
$145
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0004901
Product name
(-)-CAMPHENE
Purity
95.00%
Packaging
25G
Price
$1136.59
Updated
2021/12/16
AHH
Product number
MT-04349
Product name
(-)-Camphene
Purity
80%
Packaging
10000g
Price
$325
Updated
2021/12/16
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(-)-CAMPHENE Chemical Properties,Usage,Production

Uses

(-)-Camphene has been observed in the chemical composition of essential oils from different morphological parts of Pinus cembra L.

Definition

ChEBI: A camphene (2,2-dimethyl-3-methylenebicyclo[2.2.1]heptane) that has S configuration at position 1 and R configuration at position 4.

Purification Methods

Purify norbornane by fractionation through a Stedman column (see p. 11) at 100mm in a N2 atmosphere, crystallise it from EtOH and sublime it in a vacuum below its melting point. It is characterised by its camphenilone semicarbazone, m 217-218.5o, or camphor semicarbazone, m 236-238o. [NMR: Hana & Koch Chem Ber 111 2527 1978, Bartlett et al. Justus Liebigs Ann Chem 623 217 1959, Bain et al. J Am Chem Soc 72 3124 1950, Beilstein 5 IV 461.]

(-)-CAMPHENE Preparation Products And Raw materials

Raw materials

Preparation Products

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(-)-CAMPHENE Suppliers

SIGMA-RBI
Tel
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Fax
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Country
Switzerland
ProdList
6896
Advantage
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5794-04-7, (-)-CAMPHENERelated Search:


  • 2,2-dimethyl-3-methylene-,(1S)-Bicyclo[2.2.1]heptane
  • 2-dimethyl-3-methylene-(1s)-bicyclo[2.2.1]heptan
  • L-Camphene
  • (1S)-2,2-DIMETHYL-3-METHYLENEBICYCLO[2.2.1]HEPTANE
  • Bicyclo2.2.1heptane, 2,2-dimethyl-3-methylene-, (1S,4R)-
  • (1R,4S)-3,3-Dimethyl-2-methylenebicyclo[2.2.1]heptane
  • (1S,4R)-2,2-Dimethyl-3-methylenenorbornane
  • [1S,4R,(-)]-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
  • ()-Camphene,(1S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
  • (+/-)-Camphene, sum of camphene + fenchene
  • (-)-Camphene,95%
  • (-)-Camphene
  • (-)-CaMphene, tech. 80% (suM of caMphene + fenchene)
  • 5794-04-7
  • Alkenes
  • Asymmetric Synthesis
  • Chiral Building Blocks
  • Organic Building Blocks