ChemicalBook > CAS DataBase List > 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- Product Name
- 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- CAS No.
- 7428-60-6
- Chemical Name
- 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- Synonyms
- DKFELEX0338;Tris(trimethylsilyl)silanol;Tris(trimethylsilyl)silanol >=95%;Hydroxy-tris(trimethylsilyl)silane;2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- CBNumber
- CB84805003
- Molecular Formula
- C9H28OSi4
- Formula Weight
- 264.66
- MOL File
- 7428-60-6.mol
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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Property
- Boiling point:
- 235.1±23.0 °C(Predicted)
- Density
- 0.833±0.06 g/cm3(Predicted)
- refractive index
- n/D 1.496
- form
- liquid
- pka
- 15.57±0.53(Predicted)
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 902489
- Product name
- Tris(trimethylsilyl)silanol
- Purity
- ≥95%
- Packaging
- 1G
- Price
- $260
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 902489
- Product name
- Tris(trimethylsilyl)silanol
- Purity
- ≥95%
- Packaging
- 5G
- Price
- $937
- Updated
- 2024/03/01
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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Chemical Properties,Usage,Production
Uses
Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
reaction suitability
reaction type: C-C Bond Formation
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Preparation Products And Raw materials
Raw materials
Preparation Products
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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Suppliers
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