ChemicalBook > CAS DataBase List > Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
- Product Name
- Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
- CAS No.
- 2030437-92-2
- Chemical Name
- Ir[dFFppy]2-(4,4'-dCF3bpy)PF6
- Synonyms
- Ir[dFFppy]?-(4,4′-dCF?bpy)PF?;Ir[dFFppy]2-(4,4'-dCF3bpy)PF6;IR [DFFPPY] 2-(4,4'- DCF3BPY)PF6;(5,5'-Difluoro-2,2'-bipyridine)bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl]phenyl]Iridium hexafluorophosphate;(5,5'-Difluoro-2,2'-bipyridine-κN1,κN1')bis[3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-κN]phenyl-κC]Iridium hexafluorophosphate
- CBNumber
- CB84846406
- Molecular Formula
- C34H16F18IrN4P
- Formula Weight
- 1045.69
- MOL File
- 2030437-92-2.mol
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Ir[dFFppy]2-(4,4'-dCF3bpy)PF6 Property
- Melting point:
- >300 °C
- form
- powder or crystals
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 902217
- Product name
- Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
- Purity
- ≥95%
- Packaging
- 100MG
- Price
- $130
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 902217
- Product name
- Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
- Purity
- ≥95%
- Packaging
- 500MG
- Price
- $619
- Updated
- 2024/03/01
Arctom
- Product number
- AS708764
- Product name
- Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
- Purity
- 98%
- Packaging
- 1g
- Price
- $651
- Updated
- 2021/12/16
Arctom
- Product number
- AS708764
- Product name
- Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
- Purity
- 98%
- Packaging
- 250mg
- Price
- $176
- Updated
- 2021/12/16
Arctom
- Product number
- AS708764
- Product name
- Ir[dFFppy]2-(4,4′-dCF3bpy)PF6
- Purity
- 98%
- Packaging
- 100mg
- Price
- $87
- Updated
- 2021/12/16
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Ir[dFFppy]2-(4,4'-dCF3bpy)PF6 Chemical Properties,Usage,Production
Uses
Under a dual catalytic copper/photoredox manifold, the Mes-Umemoto reagent has been demonstrated to be an excellent photocatalyst for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. For trifluoromethylation reactions, use with dMesSCF3 (901466) and supersilanol (902489).
reaction suitability
core: iridium
reagent type: catalyst
reaction type: Photocatalysis
Ir[dFFppy]2-(4,4'-dCF3bpy)PF6 Preparation Products And Raw materials
Raw materials
Preparation Products
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Ir[dFFppy]2-(4,4'-dCF3bpy)PF6 Suppliers
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