ChemicalBook > CAS DataBase List > (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE

Product Name
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
CAS No.
65012-74-0
Chemical Name
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
Synonyms
(bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe;bicycloheptadiene(diphenylphosphino)butane rhodium ClO4;(BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04;(Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I);(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
CBNumber
CB8493732
Molecular Formula
C35H36ClO4P2Rh
Formula Weight
720.96
MOL File
65012-74-0.mol
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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Property

Melting point:
210 °C (dec.)(lit.)
solubility 
sol CH2Cl2, MeOH, THF/MeOH, and H2O/MeOH mixtures; sparingly sol THF; insol Et2O
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Safety

Hazard Codes 
O,Xi
Risk Statements 
8-36/37/38
Safety Statements 
17-26-36
RIDADR 
UN 1479 5.1/PG 2
WGK Germany 
3
HazardClass 
5.1
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P220Keep/Store away from clothing/…/combustible materials.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

American Custom Chemicals Corporation
Product number
OGM0000934
Product name
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) PERCHLORATE
Purity
95.00%
Packaging
25MG
Price
$670.66
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
OGM0000934
Product name
(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)BUTANE]RHODIUM(I) PERCHLORATE
Purity
95.00%
Packaging
100MG
Price
$924.12
Updated
2021/12/16
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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Chemical Properties,Usage,Production

Uses

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE is a catalyst precursor used in the asymmetric hydrogenation of amino acid precursors, as well as in transfer hydrogenation and hydrosilation reactions

Synthesis

Cationic rhodium-chiraphos complexes are usually prepared in situ or from the procedure given below. In reactions employing the various rhodium-chiraphos complexes, the diene ligand is frequently hydrogenated prior to catalysis to afford the active solvated catalyst precursors [RhS2(chiraphos)]+.

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE Suppliers

China 1 Switzerland 1 United Kingdom 1 United States 2 Global 5
Riedel-de Haen AG
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United States
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6773
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CARBONE SCIENTIFIC CO.,LTD
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sales@carbonesci.com
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United Kingdom
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6666
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SIGMA-RBI
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Switzerland
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Guangzhou WeiBo Chemical Co., Ltd.
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weibochem@163.com
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China
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6187
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3B Scientific Corporation
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6718
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65012-74-0, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATERelated Search:

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE 2,5-Norbornadiene 1,2-BIS(DIMETHYLPHOSPHINO)ETHANE diphenyl(2-phosphinoethyl)phosphine 1,2-BIS(PHENYLPHOSPHINO)ETHANE (S)-(-)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE 1,2-Bis-(diphenylphosphino)propane (2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE 1,2-Bis(diphenylphosphino)ethane

  • (BICYCLO[2.2.1]HEPTA-2,5-DIENE)[(2S,3S)-BIS(DIPHENYLPHOSPHINO)-BUTANE] RHODIUM(I) PERCHLORATE
  • (bicyclo(2.2.1)hepta-2,5-diene)((2S,3S)-bis(diphe
  • (BICYCLO(2.2.1)HEPTA-2,5-DIENE)((2S,3S)- BIS(DIPHENYLPHOSPHINO)BUTANE)RH(I)CL04
  • (Bicyclo[2.2.1]hepta-2,5-diene)[(2S,3S)-BIS(diphenylphosphino)-butane] rhodium(I)
  • bicycloheptadiene(diphenylphosphino)butane rhodium ClO4
  • 65012-74-0
  • C35H32ClO4P2Rh
  • C28H28P2C7H8ClO4Rh
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Hydrogenation