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DEUTERIUM

History Uses Preparation
Product Name
DEUTERIUM
CAS No.
7782-39-0
Chemical Name
DEUTERIUM
Synonyms
D2;Heavy hydrogen;(2)H2;diplogen;Deuteriu;DEUTERIUM;DEUTIRIUM;DEUTERRIUM;hydrogen-2;Dideuterium
CBNumber
CB8495776
Molecular Formula
D2
Formula Weight
4.03
MOL File
7782-39-0.mol
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DEUTERIUM Property

Melting point:
-254.43° (18.73 K) at 128.5 mm (triple point)
Boiling point:
-249.5 °C(lit.)
Density 
0.169 g/mL at 25 °C(lit.)
vapor density 
0.07 (vs air)
vapor pressure 
17.1-1665kPa at -254.43--234.8℃
form 
gas
color 
colorless
Merck 
13,2956
Dielectric constant
1.3(20℃)
Stability:
Stable. Extremely flammable. Readily forms explosive mixtures with air.
CAS DataBase Reference
7782-39-0(CAS DataBase Reference)
EPA Substance Registry System
Deuterium (7782-39-0)
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Safety

Hazard Codes 
F+
Risk Statements 
12
Safety Statements 
9-16-33
RIDADR 
UN 1957 2.1
WGK Germany 
1
HazardClass 
2.1
Hazardous Substances Data
7782-39-0(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H220Extremely flammable gas

H280Contains gas under pressure; may explode if heated

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P410+P403Protect from sunlight. Store in a well-ventilated place.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
361860
Product name
Deuterium
Purity
99.8 atom % D
Packaging
10l
Price
$206
Updated
2024/03/01
Sigma-Aldrich
Product number
361860
Product name
Deuterium
Purity
99.8 atom % D
Packaging
25l
Price
$365
Updated
2024/03/01
Sigma-Aldrich
Product number
617474
Product name
Deuterium
Purity
99.9 atom % D
Packaging
25l
Price
$429
Updated
2024/03/01
Sigma-Aldrich
Product number
617474
Product name
Deuterium
Purity
99.9 atom % D
Packaging
45l
Price
$706
Updated
2024/03/01
Sigma-Aldrich
Product number
368407
Product name
Deuterium
Purity
99.96 atom % D
Packaging
10l
Price
$356
Updated
2024/03/01
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DEUTERIUM Chemical Properties,Usage,Production

History

Rutherford predicted the existence of this heavy isotope of hydrogen in 1920. It was detected by Urey, Brickwedde and Murphy in 1932. It occurs in all natural compounds of hydrogen including water, as well as in free hydrogen molecules at the ratio of about one part per 6,000 parts hydrogen.

Uses

The principal application of deuterium is in tracer studies for measuring rates and kinetics of chemical reactions. It also is used in thermonuclear reactions; and as a projectile in cyclotrons for bombardment of atomic nuclei to synthesize isotopes of several transuranium elements. Deuterium oxide, D2O, or heavy water is used as a neutron moderator in nuclear reactors.

Preparation

Deuterium may be prepared by several methods. Urey’s first method of preparation involved fractional distillation of a very large amount of liquid hydrogen. It also may be produced by electrolysis of heavy water obtained by H2S/H2O exchange process. It may be obtained by continued, long-time electrolysis of ordinary water in which light water molecules are split first, thus concentrating deuterated oxygen in the residual liquid. Also, deuterium in high purity may be separated by thermally induced diffusion processes.

Chemical Properties

colourless gas

Uses

Used extensively in small amounts as tracer in the establishment of rates and kinetics of chemical reactions.

Definition

A naturally occurring stable isotope of hydrogen in which the nucleus contains one proton and one neutron. The atomic mass is thus approximately twice that of 1H; deuterium is known as ‘heavy hydrogen’. Chemically it behaves almost identically to hydrogen, forming analogous compounds, although reactions of deuterium compounds are often slower than those of the corresponding 1H compounds. This is made use of in kinetic studies where the rate of a reaction may depend on transfer of a hydrogen atom (i.e. a kinetic isotope effect).

General Description

DEUTERIUM is an isotope of hydrogen but DEUTERIUM is chemically identical. DEUTERIUM is a colorless, odorless gas. DEUTERIUM is easily ignited. Once ignited DEUTERIUM burns with a pale blue, almost invisible flame. The vapors are lighter than air. DEUTERIUM is flammable over a wide range of vapor/air concentrations. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. DEUTERIUM is not toxic but is a simple asphyxiate by the displacement of oxygen in the air.

Air & Water Reactions

Highly flammable.

Reactivity Profile

DEUTERIUM, like hydrogen, is a reducing agent; reacts readily with oxidizing agents.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Some may be irritating if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases.

Fire Hazard

EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Vapors from liquefied gas are initially heavier than air and spread along ground. CAUTION: Hydrogen (UN1049), DEUTERIUM (UN1957), Hydrogen, refrigerated liquid (UN1966) and Methane (UN1971) are lighter than air and will rise. Hydrogen and DEUTERIUM fires are difficult to detect since they burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket.

Agricultural Uses

Deuterium is one of the three isotopes of hydrogen, the other two being hydrogen-1 and tritium. Hydrogen-1 and deuterium are naturally occurring stable isotopes, while the radioactive tritium is made artificially.
In nature, the ratio is one part of deuterium to 6500parts of normal hydrogen. Deuterium is present in water as the oxide HDO from which deuterium is usually obtained by electrolysis or fractional distillation. Its chemical behavior is similar to that of hydrogen, although deuterium compounds react slowly.

Purification Methods

Pass the gas over activated charcoal at -195o [MacIver & Tobin J Phys Chem 64 451 1960]. Purify it also by diffusion through nickel [Pratt & Rogers, J Chem Soc, Faraday Trans I 92 1589 1976]. Always check deuterium for radioactivity to determine the amount of tritium in it (see D2O below).

DEUTERIUM Preparation Products And Raw materials

Raw materials

Preparation Products

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DEUTERIUM Suppliers

PERIC Special Gases Co., Ltd.
Tel
0310-7182720-613 15620672519
Email
zhaoqingwei@pericsg.com
Country
China
ProdList
40
Advantage
58
Shanghai wechem chemical co., ltd
Tel
18824865657
Fax
021-6192 7501
Email
joey.lin@wechem.cn
Country
China
ProdList
506
Advantage
58
Wuhan NewRadar Special Gas Co., Ltd.
Tel
027-82652715 18986267605
Fax
027-82652715
Email
2850590615@qq.com
Country
China
ProdList
164
Advantage
58
Wuhan eastop Technology Co., ltd.6
Tel
027-027-87382885 18086641195
Fax
027-87382885
Email
service@isotopechina.com
Country
China
ProdList
155
Advantage
58
Isotope (Xiamen) Industry and Trade Co., Ltd
Tel
0510-051082803581 15903302207
Fax
051082803581
Email
zhongxin326@sohu.com
Country
China
ProdList
229
Advantage
58
Guangzhou Yuejia Gas Co., Ltd
Tel
400-6377517 19876107228
Email
linfeng@yigas.cn
Country
China
ProdList
39
Advantage
58
Shanghai isotope chemical co.,ltd
Tel
021-021-51600108 13062666369
Email
sales@chinaisotope.com
Country
China
ProdList
4272
Advantage
58
Central China Special Gas (CCSG) Co., Ltd
Tel
0734-8755555 15674722888
Fax
0734-8123618
Email
lyq@ccsg.cn
Country
China
ProdList
281
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
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View Lastest Price from DEUTERIUM manufacturers

Career Henan Chemical Co
Product
DEUTERIUM 7782-39-0
Price
US $6.68/KG
Min. Order
1KG
Purity
97%-99%
Supply Ability
1kg-1000kg
Release date
2020-01-10

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