(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&

Product Name: (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&
CAS No.: 171086-52-5
Chemical Name: (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&
Synonyms: (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&;(4S，5S)-2，2-Dimethyl-α，α，α'，α'-tetra(1-naphthyl)-1，3-dioxolane-4，5-dimethanol;((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-1-yl)methanol);(4S,5S)-2,2-dimethyl-α,α,α',α'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanol;(4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol;(4S,5S)-2,2-dimethyl-α,α,α',α'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanol;(4S,5S)-2,2-dimethyl-α,α,α',α'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanol;(4S-TRANS)-2,2-DIMETHYL-A,A,A',A'-TETRA( 1-NAPHTHYL)-1,3-DIOXOLANEDIMETHANOL, 99%;(4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-1-naphthalenyl-1,3-Dioxolane-4,5-dimethanol;(4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-1-naphthalenyl-1,3-Dioxolane-4,5-dimethanol
CBNumber: CB8499219
Molecular Formula: C47H38O4
Formula Weight: 666.8
MOL File: 171086-52-5.mol

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(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Property

Melting point:: 200 °C (dec.)(lit.)
Density: 1.269±0.06 g/cm3(Predicted)
pka: 12.00±0.29(Predicted)
optical activity: [α]20/D +280°, c = 1 in ethyl acetate

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 395242
Product name: (4S-trans)-2,2-Dimethyl-α,α,α′,α′-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol
Purity: 99%
Packaging: 1G
Price: $281
Updated: 2023/06/20

Ambeed

Product number: A1006006
Product name: ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-1-yl)methanol)
Purity: 95%99%ee
Packaging: 25g
Price: $655
Updated: 2021/12/16

Ambeed

Product number: A1006006
Product name: ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-1-yl)methanol)
Purity: 95%99%ee
Packaging: 100g
Price: $2300
Updated: 2021/12/16

Ambeed

Product number: A1006006
Product name: ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-1-yl)methanol)
Purity: 95%99%ee
Packaging: 250mg
Price: $20
Updated: 2021/12/16

Ambeed

Product number: A1006006
Product name: ((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-1-yl)methanol)
Purity: 95%99%ee
Packaging: 1g
Price: $65
Updated: 2021/12/16

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(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Chemical Properties,Usage,Production

Uses

(4S-trans)-2,2-Dimethyl-α,α,α′,α′-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol, also known as TADDOL, is a chiral auxiliary that can be used:

For the highly enantioselective addition of primary alkyl Grignards to ketones.
As an organocatalyst for the activation of carbonyl functionality in vinylogous addition reaction of an aldehyde.
As a chiral dopant in the preparation of cholesteric liquid crystal (CLC) having an aggregation-induced-emission dye.

(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Preparation Products And Raw materials

Raw materials

Preparation Products

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(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA& Suppliers

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171086-52-5, (4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&Related Search:

[(4S,5S)-5-[hydroxy(dinaphthalen-1-yl)methyl]-2,2-dimethyl-1,3-dioxolan-4-yl]-dinaphthalen-1-ylmethanol

(4S-TRANS)-2 2-DIMETHYL-A A A' A'-TETRA&

(4S-TRANS)-2,2-DIMETHYL-A,A,A',A'-TETRA( 1-NAPHTHYL)-1,3-DIOXOLANEDIMETHANOL, 99%

(4s-trans)-2,2-dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol

(4S,5S)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-nephthyl)-1,3-dioxolane-4,5-dimethanol

(4S-trans)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol 99%

(4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-1-naphthalenyl-1,3-Dioxolane-4,5-dimethanol

(4S,5S)-(-)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3-dioxolane-4,5-dimethanol,98%

(4S,5S)-2,2-Dimethyl-α,α,α',α'-tetra(1-naphthyl)-1,3- dioxolane-4,5-dimethanol,99%e.e.

(4S,5S)-2,2-dimethyl-α,α,α',α'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanol

1,3-Dioxolane-4,5-dimethanol, 2,2-dimethyl-α4,α4,α5,α5-tetra-1-naphthalenyl-, (4S,5S)-

(4S，5S)-2，2-Dimethyl-α，α，α'，α'-tetra(1-naphthyl)-1，3-dioxolane-4，5-dimethanol

((4S,5S)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(di(naphthalen-1-yl)methanol)

(4S,5S)-2,2-dimethyl-α,α,α',α'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanol

(4S,5S)-2,2-dimethyl-α4,α4,α5,α5-tetra-1-naphthalenyl-1,3-Dioxolane-4,5-dimethanol

(4S,5S)-2,2-dimethyl-α,α,α',α'-tetra-1-naphthalenyl-1,3-dioxolane-4,5-dimethanol

171086-52-5

Chiral Oxygen

TADDOL Series

Chiral Catalysts, Ligands, and Reagents

Privileged Ligands and Complexes

TADDOLs