ChemicalBook > CAS DataBase List > S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM

S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM

Product Name
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
CAS No.
133545-17-2
Chemical Name
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
Synonyms
SL-A101-2;)-(6,6′(S)-(-)-MeO-BIPHEP;97% (S)-MeO-BIPHEP;-diyl)bis(diphenylphosphine);S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM;(S)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(S)-(-)-2,3'-Bis(diphenylphosphino)-6-6'-dimethoxy-1,1'-biphenyl;(S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine);(S)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine)
CBNumber
CB8502823
Molecular Formula
C38H32O2P2
Formula Weight
582.61
MOL File
133545-17-2.mol
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S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Property

Melting point:
213-216 °C
alpha 
-101 º (C=0.3 IN TOLUENE)
Boiling point:
651.1±55.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
crystal
color 
white
optical activity
Consistent with structure
BRN 
4790083
InChIKey
KRJVQCZJJSUHHO-UHFFFAOYSA-N
SMILES
C1(C2=C(OC)C=CC=C2P(C2=CC=CC=C2)C2=CC=CC=C2)=C(OC)C=CC=C1P(C1=CC=CC=C1)C1=CC=CC=C1
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Safety

WGK Germany 
3
F 
8-10-23
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H303May be harmfulif swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
29511
Product name
(S)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
Purity
≥97%, optical purity ee: ≥99%
Packaging
1g
Price
$700
Updated
2023/06/20
Sigma-Aldrich
Product number
29511
Product name
(S)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
Purity
≥97%, optical purity ee: ≥99%
Packaging
5g
Price
$3350
Updated
2023/06/20
Strem Chemicals
Product number
15-0179
Product name
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (S)-MeO-BIPHEP
Packaging
100mg
Price
$96
Updated
2024/03/01
Strem Chemicals
Product number
15-0179
Product name
(S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (S)-MeO-BIPHEP
Packaging
500mg
Price
$355
Updated
2024/03/01
Sigma-Aldrich
Product number
29511
Product name
(S)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
Purity
≥97%, optical purity ee: ≥99%
Packaging
100g
Price
$19570
Updated
2024/03/01
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S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Chemical Properties,Usage,Production

Chemical Properties

White powder

Uses

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Preparation Products And Raw materials

Raw materials

Preparation Products

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S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM Suppliers

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View Lastest Price from S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM manufacturers

Career Henan Chemical Co
Product
S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM 133545-17-2
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1kg,5kg,100kg
Release date
2019-08-08

133545-17-2, S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIMRelated Search:


  • S(-)-2 2-BIS-(DIPHENYLPHOSPHINO)-6 6-DIM
  • (S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(S)-MeO-BIPHEP
  • (S)-(-)-MeO-BIPHEP, SL-A101-2, (S)-(-)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(S)-MeO-BIPHEP
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (S)-MeO-BIPHEP
  • (S)-(-)-2,3'-Bis(diphenylphosphino)-6-6'-dimethoxy-1,1'-biphenyl
  • (S)-(-)-MeO-BIPHEP
  • SL-A101-2
  • (S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99%
  • (R)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine)
  • -diyl)bis(diphenylphosphine)
  • 97% (S)-MeO-BIPHEP
  • 1,1'-[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine
  • Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl-
  • (S)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny
  • )-(6,6&#8242
  • (S)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
  • (S)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine)
  • (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • (<i>S</i>)-(?)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
  • (S)-(6,6'-dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphane)
  • (S)-MeO-BIPHEP, (S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
  • (S)-MeO-BIPHEP / (S)-(-)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
  • 133545-17-2
  • Chiral Phosphine
  • MeOBIPHEP Series