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(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE

Product Name
(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE
CAS No.
180675-22-3
Chemical Name
(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE
Synonyms
2-methanidyl-1,3-dioxolane;Bromo(1,3-dioxolan-2-ylmethyl)magnesium;MagnesiuM,broMo(1,3-dioxolan-2-ylMethyl)-;(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE;magnesium,2-methanidyl-1,3-dioxolane,bromide;(1,3-dioxolan-2-ylmethyl)magnesium bromide solution;1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in THF;1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in 2-MeTHF;(1,3-Dioxolan-2-ylmethyl)magnesium bromide, 0.5M solution in THF;(1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide solution 0.5 M in THF
CBNumber
CB8685483
Molecular Formula
C4H7BrMgO2
Formula Weight
191.31
MOL File
180675-22-3.mol
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(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE Property

Boiling point:
65-67 °C
Density 
0.938 g/mL at 25 °C
Flash point:
−4 °F
form 
Powder
color 
White to off-white to pale brown
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Safety

Hazard Codes 
F,C,Xn
Risk Statements 
11-14-19-22-34-40-37-36/37/38
Safety Statements 
16-26-33-36-36/37/39-45-36/37
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
472611
Product name
(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution
Purity
0.5 M in THF
Packaging
100ml
Price
$184
Updated
2024/03/01
Sigma-Aldrich
Product number
472611
Product name
(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution
Purity
0.5 M in THF
Packaging
1l
Price
$862
Updated
2024/03/01
Rieke Metals
Product number
T0225
Product name
1,3-Dioxolan-2-ylmethylmagnesiumbromide
Packaging
50mL
Price
$153
Updated
2021/12/16
Rieke Metals
Product number
G0225
Product name
1,3-Dioxolan-2-ylmethylmagnesiumbromide
Packaging
50mL
Price
$153
Updated
2021/12/16
Matrix Scientific
Product number
121789
Product name
1,3-Dioxolan-2-ylmethylmagnesiumbromide
Purity
0.50MinTHF97%
Packaging
50ml
Price
$232
Updated
2021/12/16
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(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE Chemical Properties,Usage,Production

Uses

(1,3-Dioxolan-2-ylmethyl)magnesium bromide is a Grignard reagent that can be used to prepare:

  • 3-[11C]-Propionaldehyde, a key intermediate for the synthesis of radiolabeled compound [11C]SN-38, wherein SN-38 is 7-ethyl-10-hydroxy camptothecin.
  • 1-[(S)-2,2-Dimethyl-(1,3)-dioxolan-4-yl]-4-(1,3-dioxolan2-yl)-2-ol by reacting with D-glyceraldehyde, which is further used to synthesize unsaturated nucleosides.
  • A bicyclo carboxylate intermediate, which is employed in the total synthesis of spirovibsanin A.

reaction suitability

reaction type: Grignard Reaction

(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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(1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE Suppliers

Australia 1 Belgium 1 China 29 Germany 1 India 4 Switzerland 1 The Netherlands 1 United Kingdom 1 United States 15 Global 54
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View Lastest Price from (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 180675-22-3
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

180675-22-3, (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDERelated Search:

2-(1,3-Dioxolan-2-yl)ethylmagnesium bromide (1,3-Dioxolan-2-ylmethyl)triphenylphosphonium bromide Magnesium bromide (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE Ethylmagnesium bromide

  • (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMIDE
  • (1,3-DIOXOLAN-2-YLMETHYL)MAGNESIUM BROMI DE, 1.0M SOLUTION IN THF
  • (1,3-dioxolan-2-ylmethyl)magnesium bromide solution
  • (1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide, 0.5M solution in THF, AcroSeal
  • Bromo(1,3-dioxolan-2-ylmethyl)magnesium
  • MagnesiuM,broMo(1,3-dioxolan-2-ylMethyl)-
  • (1,3-Dioxolan-2-ylMethyl)MagnesiuM broMide solution 0.5 M in THF
  • 1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in THF
  • 1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in 2-MeTHF
  • (1,3-Dioxolan-2-ylmethyl)magnesium bromide, 0.5M solution in THF
  • 2-methanidyl-1,3-dioxolane
  • magnesium,2-methanidyl-1,3-dioxolane,bromide
  • 180675-22-3
  • C4H7BrMgO2
  • Alkyl
  • Organometallic Reagents
  • Grignard Reagents
  • Alkyl
  • Grignard Reagents
  • Organometallic Reagents