ChemicalBook > CAS DataBase List > METHYL 4-CHLOROBENZOATE

METHYL 4-CHLOROBENZOATE

Product Name
METHYL 4-CHLOROBENZOATE
CAS No.
1126-46-1
Chemical Name
METHYL 4-CHLOROBENZOATE
Synonyms
NSC 8366;orobenzoate;Chlorophenyl Methyl;RARECHEM AL BF 0077;METHYL 4-CHLOROBENZO;Decitabine Impurity D;Decitabine Impurity 42;METHYL 4-CHLOROBENZOATE;METHYL P-CHLOROBENZOATE;Decitabine Impurity DCY
CBNumber
CB8687104
Molecular Formula
C8H7ClO2
Formula Weight
170.59
MOL File
1126-46-1.mol
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METHYL 4-CHLOROBENZOATE Property

Melting point:
42-44 °C (lit.)
Boiling point:
136-137°C 10mm
Density 
1,382 g/cm3
refractive index 
1.5800 (estimate)
Flash point:
224 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Solid
color 
Off-White
Merck 
14,2125
BRN 
1564310
LogP
2.870
CAS DataBase Reference
1126-46-1(CAS DataBase Reference)
EPA Substance Registry System
Benzoic acid, 4-chloro-, methyl ester (1126-46-1)
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Safety

Risk Statements 
36/37/38
Safety Statements 
24/25
WGK Germany 
3
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
216089
Product name
Methyl 4-chlorobenzoate
Purity
99%
Packaging
5g
Price
$37
Updated
2023/01/07
Sigma-Aldrich
Product number
216089
Product name
Methyl 4-chlorobenzoate
Purity
99%
Packaging
100g
Price
$132
Updated
2023/01/07
TCI Chemical
Product number
C1625
Product name
Methyl 4-Chlorobenzoate
Purity
>98.0%(GC)
Packaging
25g
Price
$34
Updated
2024/03/01
Alfa Aesar
Product number
A10109
Product name
Methyl 4-chlorobenzoate, 99%
Packaging
25g
Price
$30.65
Updated
2024/03/01
Alfa Aesar
Product number
A10109
Product name
Methyl 4-chlorobenzoate, 99%
Packaging
100g
Price
$87.65
Updated
2024/03/01
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METHYL 4-CHLOROBENZOATE Chemical Properties,Usage,Production

Chemical Properties

COLOURLESS TO WHITE CRYSTALS

Uses

Methyl 4-chlorobenzoate was used in quantitative determination of chlorophenoxyisobutyrate (CPIB) and salicylic acid, the metabolites of clofibrate and aspirin, by GC-MS method.

Synthesis Reference(s)

Synthesis, p. 790, 1981 DOI: 10.1055/s-1981-29595

General Description

Methyl 4-chlorobenzoate undergoes room temperature Pd-mediated hydrodehalogenation with KF and polymethylhydrosiloxane (PMHS) to yield methyl benzoate. It undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid in the presence of bis-carbene palladium complex catalyst to yield methyl-(4-phenyl)-benzoate.

METHYL 4-CHLOROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

1,2,3-BENZOTHIADIAZOLE-5-CARBOXYLIC ACID
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METHYL 4-CHLOROBENZOATE Suppliers

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View Lastest Price from METHYL 4-CHLOROBENZOATE manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
METHYL 4-CHLOROBENZOATE 1126-46-1
Price
US $40.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-05-17
airuikechemical co., ltd.
Product
Methyl 4-Chlorobenzoate 1126-46-1
Price
US $0.00-0.00/Kg
Min. Order
1Kg
Purity
99.9%
Supply Ability
200tons
Release date
2024-04-08
Shaanxi Dideu Medichem Co. Ltd
Product
METHYL 4-CHLOROBENZOATE 1126-46-1
Price
US $0.10/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10
Release date
2024-07-14

1126-46-1, METHYL 4-CHLOROBENZOATERelated Search:

2-AMINO-4-CHLOROBENZOIC ACID Methyl p-chlorophenylpyruvate METHYL 4-CHLOROCINNAMATE Methyl 4-chlorocarbonylbenzoate 2',4',5',7'-TETRABROMO-3,4,5,6-TETRACHLOROFLUORESCEIN 6-CHLOROISATIN METHYL 4-CHLOROBENZOATE METHYL 4-CHLORO-2-NITROBENZOATE METHYL 2,4-DICHLOROBENZOATE Tetrachlorophthalic anhydride 3,4,5,6-TETRACHLOROFLUORESCEIN ROSE BENGAL 4-Chloro-1,8-naphthalic anhydride DI-N-BUTYL TETRACHLOROPHTHALATE METHYL 3,4-DICHLOROBENZOATE METHYL 2-CHLOROBENZOATE,METHYL O-CHLOROBENZOATE,METHYL 2-CHLOROBENZOATE, 98+%,Methyl 2-chlorobenzoate 99+% METHYL 3-CHLOROBENZOATE,METHYL M-CHLOROBENZOATE Methyl4-Methyl-3-Chlorobenzoate

  • 4-Chlorobenzoic acid methyl
  • Methyl 4-chlorobenzoate,97%
  • METHYL 4-CHLOROBENZO
  • Chlorophenyl Methyl
  • 4-(Methoxycarbonyl)chlorobenzene
  • Benzoic acid, p-chloro-, Methyl ester (6CI,7CI,8CI)
  • NSC 8366
  • Methyl 4-chlorobenzoate 99%
  • 4-chloro-benzoicacimethylester
  • Benzoic acid, 4-chloro-, methyl ester
  • Benzoic acid, p-chloro-, methyl ester
  • Methyl ester of p-chlorobenzoic acid
  • METHYL 4-CHLOROBENZOATE
  • METHYL P-CHLOROBENZOATE
  • Decitabine Impurity D
  • Decitabine Related Compound D
  • Decitabine Impurity 42
  • 4-CHLOROBENZOIC ACID METHYL ESTER
  • P-CHLOROBENZOIC ACID METHYL ESTER
  • RARECHEM AL BF 0077
  • 1-Acetamidopropan-2-yl4-chlorobenzoate
  • Methyl 4-Chlorobenzoate &gt
  • Decitabine Impurity 42 (Methyl 4-Chlorobenzoate)
  • orobenzoate
  • Decitabine Impurity DCY
  • Lenalidomide ImpurityABCDEFGHI
  • Decitabine USP Related Compound D
  • 1126-46-1
  • ClC6H4CO2CH3
  • Esters
  • Organic Building Blocks
  • Building Blocks
  • C8 to C9
  • Carbonyl Compounds
  • blocks
  • Carboxes
  • Aromatic Esters
  • Benzoic acid
  • Acids & Esters
  • Chlorine Compounds
  • C8 to C9
  • Carbonyl Compounds
  • Esters