ChemicalBook > CAS DataBase List > 4-(HYDROXYMETHYL)CYCLOHEXANONE

4-(HYDROXYMETHYL)CYCLOHEXANONE

Product Name: 4-(HYDROXYMETHYL)CYCLOHEXANONE
CAS No.: 38580-68-6
Chemical Name: 4-(HYDROXYMETHYL)CYCLOHEXANONE
Synonyms: 4-(Hydroxymethyl)cyclohexan-1-one;101951;4-Methylolcyclohexan-1-one;4-(HYDROXYMETHYL)CYCLOHEXANONE;4-(HydroxyMethly)cyclohexanone;Cyclohexanone, 4-(hydroxyMethyl)-;4-(Hydroxymethyl)cyclohexan-1-one97%;4-(Hydroxymethyl)cyclohexan-1-one 97%;4-(hydroxymethyl)cyclohexanone - [H86643];(4-Oxocyclohex-1-yl)methanol, 1-(Hydroxymethyl)-4-oxocyclohexane
CBNumber: CB8698124
Molecular Formula: C7H12O2
Formula Weight: 128.17
MOL File: 38580-68-6.mol

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4-(HYDROXYMETHYL)CYCLOHEXANONE Property

Boiling point:: 239.8±13.0 °C(Predicted)
Density: 1.054±0.06 g/cm3(Predicted)
storage temp.: Inert atmosphere,Store in freezer, under -20°C
form: solid
pka: 14.85±0.10(Predicted)
InChI: InChI=1S/C7H12O2/c8-5-6-1-3-7(9)4-2-6/h6,8H,1-5H2
InChIKey: KHMBXNKCMNGLKG-UHFFFAOYSA-N
SMILES: C1(=O)CCC(CO)CC1

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Safety

Hazard Codes: Xi
Risk Statements: 37/38-41
Safety Statements: 26-39
HS Code: 2914500090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC

Product number: H946820
Product name: 4-(Hydroxymethyl)cyclohexanone
Packaging: 5G
Price: $525
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CHM0011132
Product name: 4-(HYDROXYMETHYL)CYCLOHEXANONE
Purity: 95.00%
Packaging: 250MG
Price: $650.27
Updated: 2021/12/16

Apolloscientific

Product number: OR6431
Product name: 4-(Hydroxymethyl)cyclohexan-1-one
Purity: 95%
Packaging: 5g
Price: $653
Updated: 2021/12/16

Matrix Scientific

Product number: 084270
Product name: 4-(Hydroxymethyl)cyclohexanone
Purity: 97%
Packaging: 1g
Price: $89
Updated: 2021/12/16

AK Scientific

Product number: Y8952
Product name: 4-(Hydroxymethyl)cyclohexanone
Packaging: 250mg
Price: $95
Updated: 2021/12/16

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4-(HYDROXYMETHYL)CYCLOHEXANONE Chemical Properties,Usage,Production

Uses

4-(Hydroxymethyl)cyclohexanone is a reagent used for the preparation of indazoles and benzisoxazoles containing cyclohexylazetidine moieties which are CCR2 antagonists with good hERG selectivity.

Synthesis Reference(s)

Tetrahedron Letters, 19, p. 2771, 1978 DOI: 10.1016/S0040-4039(01)94858-0

Synthesis

10596-05-1

33893-85-5

1653-30-1

38580-68-6

Example 5: Ce(IV)/PFCP (50 mg, 0.027 mmol) and NaBrO3 (200 mg) were dispersed and dissolved in acetic acid. Subsequently, 1,10-undecanediol (1.0 mmol) and 4-hydroxymethylcyclohexanol (1.0 mmol) were added, respectively. The reaction mixture was heated at 55°C for 3 hours. Upon completion of the reaction, the products were purified by column chromatography to afford 10-undecan-1-ol (154 mg, 82% yield) and 4-hydroxymethylcyclohexanone (93 mg, 73% yield).

References

[1] Patent: US4617153, 1986, A

4-(HYDROXYMETHYL)CYCLOHEXANONE Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-(HYDROXYMETHYL)CYCLOHEXANONE manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 4-(Hydroxymethyl)cyclohexanone 38580-68-6
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-24

Shanghai Yongzeng Technology Co.,Ltd

Product: 4-(hydroxymethyl)cyclohexanone 38580-68-6
Price: US $0.00/gm
Min. Order: 10gm
Purity: 96%min
Supply Ability: 1kgs
Release date: 2024-09-10

Shanghai Rlavie Technology Co ltd

Product: 4-(Hydroxymethyl)cyclohexan-1-one 38580-68-6
Price: US $0.00-0.00/kg
Min. Order: 0.0001kg
Purity: 98%min
Supply Ability: 100kgs/month
Release date: 2022-05-09

38580-68-6, 4-(HYDROXYMETHYL)CYCLOHEXANONERelated Search:

Limonin 4-Oxocyclohexanecarboxylic acid Ethyl 4-oxocyclohexanecarboxylate Methyl 4-ketocyclohexanecarboxylate SILYDIANIN Toosendanin Nomilin Cyclohexanone METHYLCYCLOHEXANONE DEACETYLNOMILIN DIETHYL 4-OXOCYCLOHEXANE-1,1-DICARBOXYLATE METHYL 2,2-DIMETHYL-4,6-DIOXOCYCLOHEXANECARBOXYLATE, 97 12-OXOCHENODEOXYCHOLIC ACID 5-BETA-CHOLANIC ACID-12-ALPHA-OL-3,7-DIONE ACETATE METHYL ESTER 5-BETA-CHOLANIC ACID-3-ALPHA, 7-ALPHA-DIOL-12-ONE METHYL ESTER AKOS BB-2936 12-DEHYDROCHOLIC ACID METHYL ESTER AURORA KA-6600

4-(HYDROXYMETHYL)CYCLOHEXANONE

4-(Hydroxymethyl)cyclohexan-1-one

101951

4-(Hydroxymethyl)cyclohexan-1-one 97%

(4-Oxocyclohex-1-yl)methanol, 1-(Hydroxymethyl)-4-oxocyclohexane

4-(HydroxyMethly)cyclohexanone

4-Methylolcyclohexan-1-one

Cyclohexanone, 4-(hydroxyMethyl)-

4-(Hydroxymethyl)cyclohexan-1-one97%

4-(hydroxymethyl)cyclohexanone - [H86643]

38580-68-6

Ring Systems

Hydroxymethyl's