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PENTAAMMINECHLOROCOBALT(III) CHLORIDE

Product Name
PENTAAMMINECHLOROCOBALT(III) CHLORIDE
CAS No.
13859-51-3
Chemical Name
PENTAAMMINECHLOROCOBALT(III) CHLORIDE
Synonyms
CHLOROPENTAMMINO COBALTICHLORIDE;CHLOROPENTAMINO COBALTIC CHLORIDE;pentaaminechlorocobalt dichloride;Pentaamminechiororhodium(Ⅲ)Chloride;Cobalt(3) chloropentammine chloride;PENTAAMINECHLOROCOBALT(III)CHLORIDE;Cobalt(III) chloropentammine chloride;PENTAAMMINECHLOROCOBALT(III) CHLORIDE;pentaaminechlorocobalt(III) dichloride;CHLOROPENTAAMMINECOBALT (III) CHLORIDE
CBNumber
CB8757432
Molecular Formula
Cl3CoH15N5
Formula Weight
250.44
MOL File
13859-51-3.mol
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PENTAAMMINECHLOROCOBALT(III) CHLORIDE Property

Density 
1.819
form 
powder
Specific Gravity
1.819
Water Solubility 
Soluble in water.
Exposure limits
ACGIH: TWA 0.02 mg/m3
EPA Substance Registry System
Cobalt(2+), pentaamminechloro-, dichloride, (OC-6-22)- (13859-51-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
TSCA 
Yes
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H351Suspected of causing cancer

H413May cause long lasting harmful effects to aquatic life

Precautionary statements

P201Obtain special instructions before use.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
298301
Product name
Pentaamminechlorocobalt(III) chloride
Purity
98%
Packaging
10g
Price
$97.1
Updated
2024/03/01
Alfa Aesar
Product number
013765
Product name
Chloropentaamminecobalt(III) chloride
Packaging
10g
Price
$140
Updated
2024/03/01
Alfa Aesar
Product number
013765
Product name
Chloropentaamminecobalt(III) chloride
Packaging
2g
Price
$56.6
Updated
2023/06/20
Alfa Aesar
Product number
013765
Product name
Chloropentaamminecobalt(III) chloride
Packaging
50g
Price
$518
Updated
2023/06/20
American Custom Chemicals Corporation
Product number
ING0016037
Product name
PENTAAMMINECHLOROCOBALT(III) CHLORIDE
Purity
95.00%
Packaging
10G
Price
$1167.03
Updated
2021/12/16
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PENTAAMMINECHLOROCOBALT(III) CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

brick red crystal(s) [KIR79] [ALD94]

Uses

A nanocomposite of nanophotoadduct of pentaamminechlorocobalt(III) chloride with hexamine and polythiophene (PTh)may be used in high temperatures electrical appliances. It may be used along with potassium tris(oxalato)chromate(III) to synthesize heterometallic compound, [CoCl(NH3 )5 ] [KCr(C2 O4 )3 ]?0.5H2O.This heterometallic compound has several potential applications such as microporous hybrid material with organic π-donors.

Preparation

Chloropentaamminecobalt (III) Chloride is obtained by oxidation of an ammoniacal CoCl3 solution, and purified via [Co(NH3)sH2O]2(C2O4)3 ? 4H3O.
A solution of 20 g. of precipitated cobalt carbonate in some 1:1 HCl is prepared, filtered and cooled; a mixture of 250 ml. of cone, ammonia and 50 g. of (NH4)3CO3 dissolved in 250 ml. of H3O is then added. The mixture is oxidized for three hours by bubbling in a stream of air. After addition of 150 g. of NH4Cl the solution is evaporated to sirup consistency on the steam bath. Dilute HCl is added to drive off the CO 2 and produce a weakly acid reaction; then ammonia is added to give a weakly basic solution, followed by 10 ml. of additional cone, ammonia. The liquid, whose volume at this point is 400-500 ml., is heated on the steam bath until all the tetraammine salt disappears; it is then treated with 300 ml. of cone. HCl and heated for 30-45 minutes on the steam bath. The [Co(NH3)5- Cl]Cl2 precipitates on cooling. It is filtered off and washed with 1:1 HCl until free of NH4Cl, then with alcohol until free of acid. The salt still contains some [Co(NH3) 5]Cl3. Yield: 34.5 g.

PENTAAMMINECHLOROCOBALT(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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PENTAAMMINECHLOROCOBALT(III) CHLORIDE Suppliers

Alfa Aesar
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Shaanxi Dideu Medichem Co. Ltd
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13859-51-3, PENTAAMMINECHLOROCOBALT(III) CHLORIDERelated Search:


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