6,10-Dimethyl-5,9-undecadien-2-one
- Product Name
- 6,10-Dimethyl-5,9-undecadien-2-one
- CAS No.
- 689-67-8
- Chemical Name
- 6,10-Dimethyl-5,9-undecadien-2-one
- Synonyms
- Geranylacetone;5,9-Undecadien-2-one, 6,10-dimethyl-;Dihydropseudoionone;6,10-DIMETHYLUNDECA-5,9-DIEN-2-ONE;FEMA 3542;Nsc406679;CBI-BB ZERO/001230;Dihydropseudoionon;GERANYL-2-PROPANONE;Geranylacetone(Z/E)
- CBNumber
- CB8761079
- Molecular Formula
- C13H22O
- Formula Weight
- 194.31
- MOL File
- 689-67-8.mol
6,10-Dimethyl-5,9-undecadien-2-one Property
- Boiling point:
- 254-258 °C(lit.)
- Density
- 0.873 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.467(lit.)
- FEMA
- 3542 | 6,10-DIMETHYL-5,9-UNDECADIEN-2-ONE
- Flash point:
- >230 °F
- storage temp.
- Amber Vial, Refrigerator, Under inert atmosphere
- solubility
- Chloroform, Dichloromethane (Slightly)
- form
- Oil
- color
- Colourless
- Odor
- at 100.00 %. fresh rose leaf floral green magnolia aldehydic fruity
- Odor Type
- floral
- Water Solubility
- Not miscible or difficult to mix in water. Soluble in alcohol.
- JECFA Number
- 1122
- BRN
- 1722277
- Stability:
- Light Sensitive
- LogP
- 4.13
- CAS DataBase Reference
- 689-67-8(CAS DataBase Reference)
- NIST Chemistry Reference
- 5,9-Undecadien-2-one, 6,10-dimethyl-(689-67-8)
- EPA Substance Registry System
- 5,9-Undecadien-2-one, 6,10-dimethyl- (689-67-8)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-37/39-36
- WGK Germany
- 3
- RTECS
- YQ1190000
- TSCA
- Yes
- HS Code
- 2914199090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- W354201
- Product name
- 6,10-Dimethyl-5,9-undecadien-2-one
- Purity
- ≥97%, stabilized, FG
- Packaging
- sample-k
- Price
- $52
- Updated
- 2022/05/15
- Product number
- G0236
- Product name
- Geranylacetone [mixture of (E)- and (Z)- isomers, (3:2)]
- Purity
- >96.0%(GC)
- Packaging
- 25mL
- Price
- $50
- Updated
- 2024/03/01
- Product number
- A19184
- Product name
- Geranylacetone, (E)+(Z), 97%, (Z)-isomer (nerylacetone) ca 45%
- Packaging
- 25g
- Price
- $60.65
- Updated
- 2024/03/01
- Product number
- A19184
- Product name
- Geranylacetone, (E)+(Z), 97%, (Z)-isomer (nerylacetone) ca 45%
- Packaging
- 100g
- Price
- $142.65
- Updated
- 2024/03/01
- Product number
- G367778
- Product name
- (E/Z)-Geranylacetone
- Packaging
- 5g
- Price
- $50
- Updated
- 2021/12/16
6,10-Dimethyl-5,9-undecadien-2-one Chemical Properties,Usage,Production
Chemical Properties
Geranylacetone occurs in (5Z)-trans
as well as in (5E)-trans form and has been identified in fruits and in essential oils.
It is a colorless liquid with a fresh, green, slightly penetrating, rose-like odor.
Geranylacetone is an intermediate in the synthesis of other fragrance substances.
It is mainly produced from linalool. Another route starts from myrcene,
to which methyl acetoacetate is added under rhodium catalysis; geranylacetone is
subsequently obtained after saponification and decarboxylation. It is used
in perfumery in rose compositions, for example, in soap perfumes.
Chemical Properties
6,10-Dimethyl-5,9-undecadien-2-one has a green and rosy floral odor and fresh-floral, light, but rather penetrating sweet-rosy, slightly green, magnolia-like odor. It blends well in lavender and fruity notes, where it imparts a clean and natural character. It helps to round out floral bouquets
Occurrence
Reported found in oil of citronella, yellow passion fruit, peppermint, Scotch spearmint oil, Japanese seafood, scallop, tomato, tomato paste, citrus peel oils, carrots, papaya, melon, Parmesan cheese, milk powder, cognac, tea, starfruit, figs, mango, red sage, nectarines, clams, pork, anise, and hyssop
Uses
It is used as a flavoring agent and adjuvant. It is also employed as a substance, extract, or preparation for diffusing or imparting an agreeable or attractive smell.
Preparation
By reaction of linalool and ethyl acetoacetate with an alkaline catalyst and subsequent rearrangement and decarboxylation.
Application
Geranylacetone is an intermediate in nerolidol synthesis. It is used in perfumery in rose compositions, for example, in soap perfumes.
Definition
ChEBI: Geranyl acetone is a monoterpene ketone in which an (E)-geranyl group is bonded to one of the alpha-methyls of acetone. It is a component of essential oils from various plants including Nelumbo nucifera. It has a role as a flavouring agent, a fragrance, a volatile oil component and a plant metabolite. It contains a geranyl group.
Aroma threshold values
Detection: 60 ppb to 6.4 ppm
Taste threshold values
Taste characteristics at 12 ppm: floral, fruity, fatty, green, pear, apple and banana nuances
General Description
6,10-Dimethyl-5,9-undecadien-2-one is one of the key volatile flavor compounds of tomato and certain species of mushroom.
Safety Profile
A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
6,10-Dimethyl-5,9-undecadien-2-one Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 6,10-Dimethyl-5,9-undecadien-2-one manufacturers
- Product
- 6,10-Dimethyl-5,9-undecadien-2-one 689-67-8
- Price
- US $60.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2024-11-18
- Product
- 6-Methyl-5-hepten-2-one 689-67-8
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100 mt
- Release date
- 2024-11-06
- Product
- 6,10-Dimethyl-5,9-undecadien-2-one 689-67-8
- Price
- US $709.00/KG
- Min. Order
- 1KG
- Purity
- 98.0%
- Supply Ability
- 1T
- Release date
- 2020-07-06