6-Bromobenzofuran

Product Name: 6-Bromobenzofuran
CAS No.: 128851-73-0
Chemical Name: 6-Bromobenzofuran
Synonyms: 6-Bromo-benzofuran;6-Bromobenzo[b]furan;6-Bromo-1-benzofuran;BENZOFURAN, 6-BROMO-
CBNumber: CB8798082
Molecular Formula: C8H5BrO
Formula Weight: 197.03
MOL File: 128851-73-0.mol

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6-Bromobenzofuran Property

Boiling point:: 234℃
Density: 1.608
Flash point:: 95℃
storage temp.: 2-8°C
solubility: Chloroform, Dichloromethane, Ethyl Acetate
form: Oil
color: Light Yellow
Stability:: Volatile
InChI: InChI=1S/C8H5BrO/c9-7-2-1-6-3-4-10-8(6)5-7/h1-5H
InChIKey: BBXQYOQXGGJUFK-UHFFFAOYSA-N
SMILES: O1C2=CC(Br)=CC=C2C=C1

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Safety

HS Code: 2932990090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B680180
Product name: 6-Bromo-benzofuran
Packaging: 1g
Price: $1135
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19200
Product name: 6-Bromobenzofuran
Packaging: 50mg
Price: $150.5
Updated: 2021/12/16

AK Scientific

Product number: X5968
Product name: 6-Bromo-1-benzofuran
Packaging: 1g
Price: $228
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2H10-9-68
Product name: 6-Bromobenzofuran
Packaging: 1g
Price: $256
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB19200
Product name: 6-Bromobenzofuran
Packaging: 100mg
Price: $273
Updated: 2021/12/16

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6-Bromobenzofuran Chemical Properties,Usage,Production

Chemical Properties

Light Yellow Oil

Synthesis

204452-94-8

128851-73-0

128868-60-0

Polyphosphoric acid (PPA, 0.743 g, 6.83 mmol) was added to a solution of compound 175 (0.656 g, 2.28 mmol) in toluene (4.6 mL) under an argon atmosphere and stirred at room temperature. The reaction mixture was heated to reflux and maintained for 4 hours. Upon completion of the reaction, it was cooled to room temperature and the reaction was quenched with ice water and subsequently extracted with ethyl acetate (EtOAc). The organic layers were combined, washed with saturated brine, dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated under reduced pressure. The crude products were purified by silica gel column chromatography (eluent: ethyl acetate/hexane, 2:98) to afford 6-bromobenzofuran (176, main product, 0.206 g, 1.05 mmol, 46% yield) and 4-bromobenzofuran (177, by-product, 0.183 g, 0.935 mmol, 41% yield, colorless oily substance), respectively. 1H-NMR (CDCl3, 400 MHz) data for 6-bromobenzofuran (176): δ 6.75 (d, J = 1.6 Hz, 1H, furan-H), 7.36 (dd, J = 1.2, 8.4 Hz, 1H, Ar-H), 7.46 (d, J = 8.4 Hz, 1H, Ar-H), 7.60 (d, J = 1.6 Hz 1H, furan-H), 7.69 (s, 1H, Ar-H). 1H-NMR (CDCl3, 400 MHz) data for 4-bromobenzofuran (177): δ 6.82 (d, J = 2.4 Hz, 1H, furan-H), 7.17 (dd, J = 7.6, 8.4 Hz, 1H, Ar-H), 7.40 (d, J = 7.6 Hz, 1H, Ar-H), 7.45 (d, J = 8.4 Hz 1H, Ar-H), 7.66 (d, J = 2.4 Hz, 1H, furan-H).

References

[1] Phytochemistry, 2013, vol. 96, p. 132 - 147
[2] Patent: US7045545, 2006, B1. Location in patent: Page/Page column 20
[3] Patent: EP1204659, 2003, B1. Location in patent: Page/Page column 15-16
[4] Journal of Medicinal Chemistry, 1997, vol. 40, # 3, p. 322 - 330
[5] Tetrahedron, 2015, vol. 71, # 29, p. 4835 - 4841

6-Bromobenzofuran Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Bromobenzofuran Suppliers

Canada 1 China 115 India 2 United Kingdom 2 United States 9 Global 129

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View Lastest Price from 6-Bromobenzofuran manufacturers

Career Henan Chemical Co

Product: 6-Bromobenzofuran 128851-73-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1kg; 2kg；10kg; 100kg
Release date: 2019-08-30

128851-73-0, 6-BromobenzofuranRelated Search:

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BENZOFURAN, 6-BROMO-

6-Bromo-1-benzofuran

6-Bromobenzo[b]furan

6-Bromo-benzofuran

128851-73-0

Aromatics

Heterocycles