3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose

Uses

Product Name: 3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose
CAS No.: 63593-03-3
Chemical Name: 3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose
Synonyms: ((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole-5,5-diyl)dimethanol;((3aR,6S,6aR);-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxole-5,5-diyl);Furo[2,3-d]-1,3-dio xole,a-D-erythro-pentofuranose deriv.;3-O-Benzyl-4-hydroxymethyl-1,2-O-isopropylidene-D-furanose;a-D-erythro-Pentofuranose,4-C-(hydroxymethyl)-1,2-O-(1-methy...;1,2-O-Isopropylidene-3-O-benzyl-4-hydroxymethyl-α-D-ribofuranose;3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-a-D-ribofuranose;3-O-benzyl-4-C-hydroxyMethyl-1,2-O-isopropylidene-α-D-ribofuranose;3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-α-D-ribofuranose
CBNumber: CB8839343
Molecular Formula: C16H22O6
Formula Weight: 310.34
MOL File: 63593-03-3.mol

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3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose Property

Boiling point:: 442.5±45.0 °C(Predicted)
Density: 1.29
storage temp.: 2-8°C
pka: 13.95±0.10(Predicted)
Appearance: White to off-white Solid
optical activity: Consistent with structure
InChI: InChI=1/C16H22O6/c1-15(2)20-12-13(19-8-11-6-4-3-5-7-11)16(9-17,10-18)22-14(12)21-15/h3-7,12-14,17-18H,8-10H2,1-2H3/t12-,13+,14+/s3
InChIKey: QVXXTLFHRGMIHD-AEMUBKJBNA-N
SMILES: [C@]12([H])OC(C)(C)O[C@@]1([H])OC(CO)(CO)[C@H]2OCC1C=CC=CC=1 |&1:0,7,15,r|

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Safety

HS Code: 2932990090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TRC

Product number: B297060
Product name: 3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-a-D-ribofuranose
Packaging: 25mg
Price: $45
Updated: 2021/12/16

TRC

Product number: B297060
Product name: 3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-a-D-ribofuranose
Packaging: 250mg
Price: $75
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MB05163
Product name: 3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-a-D-ribofuranose
Packaging: 2g
Price: $50
Updated: 2021/12/16

Apolloscientific

Product number: OR927884
Product name: 3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose
Purity: 97%
Packaging: 1g
Price: $66
Updated: 2021/12/16

Biosynth Carbosynth

Product number: MB05163
Product name: 3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-a-D-ribofuranose
Packaging: 5G
Price: $100
Updated: 2021/12/16

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3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose Chemical Properties,Usage,Production

Uses

3-O-benzyl-4-C-hydroxymethyl-1,2-O-isopropylidene-ALPHA-D-ribofuranoside is a useful research chemical.

Chemical Properties

White powder

Synthesis

50-00-0

63593-02-2

63593-03-3

The general procedure for the synthesis of ((3aR,6S,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxazole-5,5-diyl)dimethanol from formaldehyde and the compound (CAS: 63593-02-2) was as follows: to a 3000 mL round-bottomed flask at room temperature was added compound 269-4 (100 g 359.32 mmol, 1.00 equiv) to a solution of tetrahydrofuran (500 mL). Water (500 mL) was then added. After the mixture was cooled to 0 °C, sodium hydroxide solution (600 mL, 2N aqueous solution) was slowly added, followed by aqueous formaldehyde solution (240 mL, 37%). The reaction mixture was stirred at room temperature overnight. After the reaction was completed, the mixture was diluted with ethyl acetate (1500 mL) and washed with saturated aqueous sodium bicarbonate solution. Finally, the mixture was washed with aqueous sodium chloride solution (3 x 500 mL).

References

[1] Tetrahedron, 2002, vol. 58, # 26, p. 5335 - 5345
[2] Patent: US2015/366888, 2015, A1. Location in patent: Paragraph 1083; 1087
[3] Patent: US2015/366887, 2015, A1. Location in patent: Paragraph 1015; 1019
[4] Patent: US2015/105341, 2015, A1. Location in patent: Paragraph 1148

3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose Preparation Products And Raw materials

Raw materials

Preparation Products

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3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose Suppliers

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View Lastest Price from 3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranose manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 3-O-Benzyl-4-C-hydroxymethyl-1,2-O-isopropylidene-alpha-D-ribofuranose 63593-03-3
Price: US $8.80-2.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2025-06-27

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 3-O-benzyl-4-C-(hydroxymethyl)-1,2-O-isopropylidene -a-D-ribofuranose 63593-03-3
Price: US $0.00-0.00/g
Min. Order: 50g
Purity: 98%min
Supply Ability: 20kg/month
Release date: 2021-06-03

Career Henan Chemical Co

Product: 3-O-BENZYL-4-(HYDROXYMETHYL-1,2-O-ISOPROPYLIDENE)-ALPHA-D-ERYTHROPENTOFURANOSE 63593-03-3
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1ton
Release date: 2018-08-06

63593-03-3, 3-O-Benzyl-4-(hydroxymethyl-1,2-O-isopropylidene)-alpha-D-erythropentofuranoseRelated Search:

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((3aR,6S,6aR)

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3-O-benzyl-4-C-(hydroxymethyl)-1,2-O-isopropylidene-a-D-ribofuranose

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3-O-benzyl-4-C-hydroxymethyl-1,2-O-isopropylidene-α-D-erythro-pentofuranose

4-C-(hydroxymethyl)-1,2-O-(1-methylethylidene)-3-O-(phenylmethyl)-alpha-D-erythro-pentofuranose

[(3aR,6S,6aR)-6-(benzyloxy)-5-(hydroxymethyl)-2,2-dimethyl-tetrahydro-2H-furo[2,3-d][1,3]dioxol-5-yl]methanol

a-D-erythro-Pentofuranose,4-C-(hydroxyMethyl)-1,2-O -(1-Methylethylidene)-3-O-(phenylMethyl)-

Furo[2,3-d]-1,3-dio xole,a-D-erythro-pentofuranose deriv.

3-O-benzyl-4-C-hydroxyMethyl-1,2-O-isopropylidene-α-D-ribofuranose

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3-O-BENZYL-4-(HYDROXYMETHYL-1,2-O-ISOPROPYLIDENE)-ALPHA-D-ERYTHROPENTOFURANOSE USP/EP/BP

[(3aR,6S,6aR)-5-(hydroxymethyl)-2,2-dimethyl-6-phenylmethoxy-6,6a-dihydro-3aH-furo[2,3-d][1,3]dioxol-5-yl]methanol

3-O-Benzyl-4-hydroxymethyl-1,2-O-isopropylidene-D-furanose

a-D-erythro-Pentofuranose,4-C-(hydroxymethyl)-1,2-O-(1-methy...

TIANFU-CHEM 3-O-BENZYL-4-(HYDROXYMETHYL-1,2-O-ISOPROPYLIDENE)-ALPHA-D-ERYTHROPENTOFURANOSE

1,2-O-Isopropylidene-3-O-benzyl-4-hydroxymethyl-α-D-ribofuranose

4-C-(Hydroxymethyl)-1,2-O-(1-methylethylidene)-3-O-(phenylmethyl)-α-D-erythro-pentofuranose

3-O-BENZYL-4-(HYDROXYMETHYL-1,2-O-ISOPROPYLIDENE)-α-D-ERYTHROPENTOFURANOSE

α-?D-?erythro-?Pentofuranose,4-?C-?(hydroxymethyl)?-?1,?2-?O-?(1-?methylethylidene)?-?3-?O-?(phenylmethyl)?-

3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-ALPHA-D-ribofuranose

3-O-Benzyl-4-(hydroxymethyl)-1,2-O-isopropylidene-α-D-ribofuranose

[(3aR,6S,6aR)-6-(benzyloxy)-5-(hydroxymethyl)-2,2-dimethyl-tetrahydro-2H-furo[2,3-d][1,3]dioxol-5-yl]methanol - [B87137]

4-C-(Hydroxymethyl)-1,2-o-(1-methylethylidene)-3-o-(benzyl)-alpha-D-erythro-pentofuranose

63593-03-3