CHEMBRDG-BB 4012533

Product Name: CHEMBRDG-BB 4012533
CAS No.: 265664-52-6
Chemical Name: CHEMBRDG-BB 4012533
Synonyms: CHEMBRDG-BB 4012533;UKRORGSYN-BB BBV-2090368;[4-(2-methoxyethoxy)phenyl]boranediol;4-(2-Methoxyethoxy)benzeneboronic acid;[4-(2-METHOXYETHOXY)PHENYL]BORONIC ACID;4-(2-Methoxyethoxy)benzeneboronicacid,95%;B-[4-(2-methoxyethoxy)phenyl]Boronic acid;4-(2-Methoxyethoxy)benzeneboronic acid, 95%;Boronic acid, B-[4-(2-methoxyethoxy)phenyl]-;[4-(2-methoxyethoxy)phenyl]boronic acid(SALTDATA: FREE)
CBNumber: CB8841254
Molecular Formula: C9H13BO4
Formula Weight: 196.01
MOL File: 265664-52-6.mol

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CHEMBRDG-BB 4012533 Property

Boiling point:: 361.1±52.0 °C(Predicted)
Density: 1.16±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
pka: 8.68±0.16(Predicted)
Appearance: White to off-white Solid

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Safety

Risk Statements: 41
Safety Statements: 26-39
HS Code: 2931900090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: M304328
Product name: 4-(2-Methoxyethoxy)phenylboronicacid
Packaging: 250mg
Price: $55
Updated: 2021/12/16

AK Scientific

Product number: J98448
Product name: 4-(2-Methoxyethoxy)phenylboronicacid
Packaging: 10g
Price: $180
Updated: 2021/12/16

Matrix Scientific

Product number: 077778
Product name: [4-(2-Methoxyethoxy)phenyl]boronic acid
Packaging: 1g
Price: $208
Updated: 2021/12/16

Matrix Scientific

Product number: 077778
Product name: [4-(2-Methoxyethoxy)phenyl]boronic acid
Packaging: 5g
Price: $678
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: BOR0003755
Product name: [4-(2-METHOXYETHOXY)PHENYL]BORONIC ACID
Purity: 97.00%
Packaging: 0.5G
Price: $770
Updated: 2021/12/16

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CHEMBRDG-BB 4012533 Chemical Properties,Usage,Production

Uses

4-(2-Methoxyethoxy)phenylboronic acid

Synthesis

959972-40-8

265664-52-6

General procedure for the synthesis of 4-(2-methoxyethoxy)phenylboronic acid (E34) from 2-(4-(2-methoxyethoxy)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (E33): Step 3: E33 (3.47 g, 12.50 mmol) was dissolved in acetone (75 mL) and a solution of ammonium acetate (4 equiv, 3.85 g, 49.9 mmol) in water (75 mL) was added with stirring. Sodium periodate (4 eq, 10.7 g, 49.9 mmol) was then added in batches. The reaction mixture was prepared as a yellow/white suspension and stirred vigorously for 36 hours at room temperature. After completion of the reaction, the mixture was filtered and the insoluble material was washed with ethyl acetate. The filtrates were combined, concentrated under reduced pressure and the residue was extracted several times with ethyl acetate. The organic phases were combined, dried with anhydrous magnesium sulfate and the solvent was evaporated under reduced pressure to give the crude product as a white solid. The crude product was purified by fast column chromatography (CombiFlash Rf, eluent: isohexane/ethyl acetate, gradient 0% to 70%) to give E34 as a white solid (875 mg). 1H NMR (CDCl3) δ: 8.14 (2H, d), 7.03 (2H, d), 4.20 (2H, t), 3.79 (2H, t), 3.48 (3H, s).

References

[1] Patent: WO2014/135654, 2014, A1. Location in patent: Page/Page column 39

CHEMBRDG-BB 4012533 Preparation Products And Raw materials

Raw materials

Preparation Products

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CHEMBRDG-BB 4012533 Suppliers

China 57 India 1 United States 9 Global 67

J & K SCIENTIFIC LTD.

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Shanghai Yolne Chemical Co., Ltd.

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View Lastest Price from CHEMBRDG-BB 4012533 manufacturers

Career Henan Chemical Co

Product: CHEMBRDG-BB 4012533 265664-52-6
Price: US $0.01/KG
Min. Order: 1KG
Purity: 98%; 99%
Supply Ability: 1kg; 5kg
Release date: 2020-02-03

265664-52-6, CHEMBRDG-BB 4012533Related Search:

Methyl 2-(4-boronophenoxy)acetate 2-[4-([1,3]DIOXOLAN-2-YLMETHOXY)-3-METHOXY-PHENYL]-4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLANE 4-(ETHOXYCARBONYL)METHOXYPHENYLBORONIC ACID 4-(2,2-DIMETHOXYETHOXY)PHENYLBORONIC ACID 4,4,5,5-TETRAMETHYL-2-(4-(OXIRAN-2-YLMETHOXY)PHENYL)-1,3,2-DIOXABOROLANE 1,2-Bis(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)ethane 2-[4-([1,3]DIOXOLAN-2-YLMETHOXY)-PHENYL]-4,4,5,5-TETRAMETHYL-[1,3,2]DIOXABOROLANE 4-(2-ETHOXY-2-OXOETHOXY)BENZENEBORONIC ACID 98 CHEMBRDG-BB 4012533 4-([1,3]Dioxolan-2-ylmethoxy)-phenylboronic acid

[4-(2-methoxyethoxy)phenyl]boronic acid(SALTDATA: FREE)

4-(2-Methoxyethoxy)benzeneboronic acid, 95%

[4-(2-methoxyethoxy)phenyl]boranediol

B-[4-(2-methoxyethoxy)phenyl]Boronic acid

CHEMBRDG-BB 4012533

UKRORGSYN-BB BBV-2090368

[4-(2-METHOXYETHOXY)PHENYL]BORONIC ACID

Boronic acid, B-[4-(2-methoxyethoxy)phenyl]-

4-(2-Methoxyethoxy)benzeneboronicacid,95%

4-(2-Methoxyethoxy)benzeneboronic acid

265664-52-6

Boronate Ester

Boronic Acid

Potassium Trifluoroborate