Physical Form
ChemicalBook > CAS DataBase List > (2-Bromothien-3-yl)methanol

(2-Bromothien-3-yl)methanol

Physical Form
Product Name
(2-Bromothien-3-yl)methanol
CAS No.
70260-16-1
Chemical Name
(2-Bromothien-3-yl)methanol
Synonyms
2-Bromothiophene-3-methanol;(2-Bromo-3-thienyl)methanol;(2-BROMOTHIEN-3-YL)METHANOL;3-Thiophenemethanol, 2-bromo-;(2-bromothiophen-3-yl)methanol;2-BROMO-3-HYDROXYMETHYL-THIOPHENE
CBNumber
CB8854137
Molecular Formula
C5H5BrOS
Formula Weight
193.06
MOL File
70260-16-1.mol
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(2-Bromothien-3-yl)methanol Property

Boiling point:
142-145 °C(Press: 18 Torr)
Density 
1.772±0.06 g/cm3(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
pka
13.77±0.10(Predicted)
Appearance
Colorless to light yellow Liquid
InChI
InChI=1S/C5H5BrOS/c6-5-4(3-7)1-2-8-5/h1-2,7H,3H2
InChIKey
BOJYRNFSHPAZBL-UHFFFAOYSA-N
SMILES
C1(Br)SC=CC=1CO
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Safety

HS Code 
2934999090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

AK Scientific
Product number
5473BB
Product name
(2-Bromothiophen-3-YL)methanol
Packaging
100mg
Price
$101
Updated
2021/12/16
AK Scientific
Product number
5473BB
Product name
(2-Bromothiophen-3-YL)methanol
Packaging
250mg
Price
$119
Updated
2021/12/16
AK Scientific
Product number
5473BB
Product name
(2-Bromothiophen-3-YL)methanol
Packaging
1g
Price
$208
Updated
2021/12/16
Matrix Scientific
Product number
130413
Product name
(2-Bromo-thiophen-3-yl)-methanol
Purity
95%+
Packaging
1g
Price
$290
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
HCH0063356
Product name
2-BROMO-3-HYDROXYMETHYL-THIOPHENE
Purity
95.00%
Packaging
1G
Price
$800.42
Updated
2021/12/16
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(2-Bromothien-3-yl)methanol Chemical Properties,Usage,Production

Physical Form

Solid or liquid

Synthesis

71637-34-8

70260-16-1

General procedure for the synthesis of (2-bromo-3-thiophene) methanol from 3-thiophene methanol: 3-hydroxymethylthiophene (12, 4.06 g, 35.6 mmol) was dissolved in 18 mL of acetic acid at room temperature, followed by the addition of N-bromosuccinimide (6.34 g, 35.6 mmol), and the reaction was stirred for 45 min. After completion of the reaction, the reaction was quenched with 1 mL of water and the mixture was poured into 250 mL of ether and washed sequentially with 100 mL of water and 100 mL of 10% aqueous NaHCO3. The organic layer was separated, dried with anhydrous Na2SO4 and the solvent was concentrated. Finally, 6.25 g of crude product 13 was obtained in 91% yield, which was directly used in the next reaction without further purification.

References

[1] Organic Letters, 2008, vol. 10, # 17, p. 3665 - 3668
[2] Patent: WO2004/65384, 2004, A1. Location in patent: Page 36; 16/19
[3] Chemistry Letters, 2013, vol. 42, # 10, p. 1170 - 1172
[4] Patent: WO2008/17164, 2008, A1. Location in patent: Page/Page column 34
[5] Journal of Medicinal Chemistry, 2010, vol. 53, # 5, p. 2227 - 2238

(2-Bromothien-3-yl)methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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(2-Bromothien-3-yl)methanol Suppliers

Belgium 1 China 54 India 1 United States 5 Global 61
Alchem Pharmtech,Inc.
Tel
8485655694
Email
sales@alchempharmtech.com
Country
United States
ProdList
63687
Advantage
58
Synthonix Inc
Tel
--
Fax
--
Email
info@synthonix.com
Country
United States
ProdList
6872
Advantage
58
Advanced Chemical Intermediates Ltd.
Tel
--
Fax
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Email
enquiries@acints.com
Country
United States
ProdList
4893
Advantage
58
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
AstaTech, Inc
Tel
--
Fax
--
Email
sales@astatechinc.com
Country
United States
ProdList
6371
Advantage
58
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View Lastest Price from (2-Bromothien-3-yl)methanol manufacturers

Career Henan Chemical Co
Product
(2-Bromo-3-thienyl)methanol 70260-16-1
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1ton
Release date
2020-01-10

70260-16-1, (2-Bromothien-3-yl)methanolRelated Search:

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  • 70260-16-1