ChemicalBook > CAS DataBase List > tert-Butyl (Mesitylsulfonyl)oxycarbaMate

tert-Butyl (Mesitylsulfonyl)oxycarbaMate

Product Name
tert-Butyl (Mesitylsulfonyl)oxycarbaMate
CAS No.
36016-39-4
Chemical Name
tert-Butyl (Mesitylsulfonyl)oxycarbaMate
Synonyms
tert-Butyl (Mesitylsulfonyl)oxycarbaMate;N-Boc-O-(mesitylsulfonyl)hydroxyamine;N-BOC-O-(MESITYLSULFONYL)HYDROXYLAMINE;N-Mesitylsulfonyloxy-tert-butylcarbaMat;BOC-Azanyl 2,4,6-trimethylbenzenesulfonate;_x000D_N-Boc-O-(mesitylsulfonyl)hydroxylamine;t-Butoxycarbonyl-O-mesitylenesulfonylhydroxylamine;N-Tert-butoxycarbonyl-O-(mesitylsulfonyl)hydroxylamine;tert-butyl N-[(2,4,6-trimethylbenzenesulfonyl)oxy]carbamate;1,1-dimethylethyl [[(2,4,6-trimethylphenyl)sulphonyl]oxy]car...
CBNumber
CB8909691
Molecular Formula
C14H21NO5S
Formula Weight
315.39
MOL File
36016-39-4.mol
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tert-Butyl (Mesitylsulfonyl)oxycarbaMate Property

Melting point:
104-105.5 °C
Density 
1.191±0.06 g/cm3(Predicted)
storage temp. 
Hygroscopic, Refrigerator, under inert atmosphere
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Solid
color 
White to Off-White
Stability:
Hygroscopic
InChI
InChI=1S/C14H21NO5S/c1-9-7-10(2)12(11(3)8-9)21(17,18)20-15-13(16)19-14(4,5)6/h7-8H,1-6H3,(H,15,16)
InChIKey
WVMDSNGINQNHLN-UHFFFAOYSA-N
SMILES
C1(S(ONC(OC(C)(C)C)=O)(=O)=O)=C(C)C=C(C)C=C1C
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Safety

HS Code 
2930909899
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H301Toxic if swalloed

H311Toxic in contact with skin

H331Toxic if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P310Immediately call a POISON CENTER or doctor/physician.

P330Rinse mouth.

P361Remove/Take off immediately all contaminated clothing.

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

AK Scientific
Product number
W5748
Product name
tert-Butyl(mesitylsulfonyl)oxycarbamate
Packaging
250mg
Price
$19
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB154038
Product name
tert-Butyl (mesitylsulfonyl)oxycarbamate
Packaging
250mg
Price
$50
Updated
2021/12/16
AK Scientific
Product number
J92785
Product name
tert-Butyl(mesitylsulfonyl)oxycarbamate
Packaging
5g
Price
$75
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB154038
Product name
tert-Butyl (mesitylsulfonyl)oxycarbamate
Packaging
500g
Price
$80
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB154038
Product name
tert-Butyl (mesitylsulfonyl)oxycarbamate
Packaging
1g
Price
$125
Updated
2021/12/16
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tert-Butyl (Mesitylsulfonyl)oxycarbaMate Chemical Properties,Usage,Production

Uses

Tert-Butyl (Mesitylsulfonyl)oxycarbaMate is a useful reagent for the enantioselective aziridination of α,β-unsaturated aldehydes.

Synthesis


2-Mesitylenesufonylchloride (2.00 g, 9.17 mmol) was added to a flame dried and argon purged round-bottom flask and dissolved in ether (18 mL), followed by the addition of N-Boc-hydroxylamine (1.47 g, 1100 mmol) The flask was cooled to 0° C and then TEA was added dropwise (1.3 mL). The reaction stirred for 2 hours at 0° C, at which all starting material had been converted as seen by TLC. The TEA-Cl, white solid, was filtered, and washed with ether. The filtrate was concentrated in vacuo, and purified via flash chromatography in 25/75 EtOAc/hexane gradient. Yield was quantitative, 2.16 g, white solid.

Purification Methods

Separation of 1,1-Dimethylethyl (((2,4,6-trimethylphenyl)sulphonyl)oxy)carbamate on Newcrom R1 HPLC column:1,1-Dimethylethyl (((2,4,6-trimethylphenyl)sulphonyl)oxy)carbamate can be analyzed by this reverse phase (RP) HPLC method with simple conditions. The mobile phase contains an acetonitrile (MeCN), water, and phosphoric acid. For Mass-Spec (MS) compatible applications the phosphoric acid needs to be replaced with formic acid. Smaller 3 μm particles columns available for fast UPLC applications. This liquid chromatography method is scalable and can be used for isolation impurities in preparative separation. It also suitable for pharmacokinetics.

tert-Butyl (Mesitylsulfonyl)oxycarbaMate Preparation Products And Raw materials

Raw materials

Preparation Products

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tert-Butyl (Mesitylsulfonyl)oxycarbaMate Suppliers

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View Lastest Price from tert-Butyl (Mesitylsulfonyl)oxycarbaMate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
tert-Butyl [(mesitylsulfonyl)oxy]carbamate 36016-39-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-04
Henan Aochuang Chemical Co.,Ltd.
Product
1,1-dimethylethyl [[(2,4,6-trimethylphenyl)sulphonyl]oxy]carbamate 36016-39-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-08
Henan Fengda Chemical Co., Ltd
Product
tert-Butyl (Mesitylsulfonyl)oxycarbaMate 36016-39-4
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
98%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-09

36016-39-4, tert-Butyl (Mesitylsulfonyl)oxycarbaMateRelated Search:

O-Mesitylenesulfonylhydroxylamine 2,4,6-Trimethylbenzenesulfonic acid 2,4-Dimethylbenzenesulfonic acid 2,4,6-TRIMETHYLTHIOPHENOL 2,4-Xylenesulfonic acid N-Hydroxyurethane 2,6-DIMETHYL-BENZENESULFONICACID tert-Butyl N-hydroxycarbamate Ammonium xylenesulfonate tert-Butyl (Mesitylsulfonyl)oxycarbaMate

  • tert-Butyl (Mesitylsulfonyl)oxycarbaMate
  • Benzenesulfonic acid,2,4,6-triMethyl-, [(1,1-diMethylethoxy)carbonyl]azanyl ester
  • 1,1-dimethylethyl [[(2,4,6-trimethylphenyl)sulphonyl]oxy]carbamate
  • N-[[(2,4,6-Trimethylphenyl)sulfonyl]oxy]carbamic acid tert-butyl ester
  • N-Tert-butoxycarbonyl-O-(mesitylsulfonyl)hydroxylamine
  • N-BOC-O-(MESITYLSULFONYL)HYDROXYLAMINE
  • [(2-methylpropan-2-yl)oxycarbonylamino] 2,4,6-trimethylbenzenesulfonate
  • tert-butyl N-[(2,4,6-trimethylbenzenesulfonyl)oxy]carbamate
  • N-Mesitylsulfonyloxy-tert-butylcarbaMat
  • N-Boc-O-(mesitylsulfonyl)hydroxyamine
  • _x000D_N-Boc-O-(mesitylsulfonyl)hydroxylamine
  • 1,1-dimethylethyl [[(2,4,6-trimethylphenyl)sulphonyl]oxy]car...
  • (1,1-Dimethylethoxy)carbonyl]azanyl 2,4,6-trimethylbenzenesulfonate
  • BOC-Azanyl 2,4,6-trimethylbenzenesulfonate
  • t-Butoxycarbonyl-O-mesitylenesulfonylhydroxylamine
  • 36016-39-4
  • 252-837-8